Golf ball resin composition and golf ball
An object of the present invention is to provide a material from which a golf ball having excellent resilience and durability can be obtained. The present invention provides a golf ball resin composition containing: (A) at least one member selected from the group consisting of a polyamide, an ethylene-vinyl alcohol copolymer, a partially saponified product of an ethylene-vinyl acetate copolymer, and a polyvinyl alcohol, (B) at least one resin component selected from the group consisting of (b-1) a binary copolymer composed of an olefin and an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms, (b-2) a metal ion-neutralized product of a binary copolymer composed of an olefin and an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms, (b-3) a ternary copolymer composed of an olefin, an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms and an α,β-unsaturated carboxylic acid ester, and (b-4) a metal ion-neutralized product of a ternary copolymer composed of an olefin, an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms and an α,β-unsaturated carboxylic acid ester, and (C) a fatty acid metal salt having 18 or less carbon atoms.
1. A golf ball resin composition containing a resin component and (C) a fatty acid metal salt having 18 or less carbon atoms,
wherein the resin component of the golf ball resin composition consists of
a resin component consisting of components (A) and (B),
(A) at least one member selected from the group consisting of a polyamide, an ethylene-vinyl alcohol copolymer, a partially saponified product of an ethylene-vinyl acetate copolymer, and a polyvinyl alcohol, and
(B) at least one resin component selected from the group consisting of
(b-1) a binary copolymer composed of an olefin and an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms,
(b-2) a metal ion-neutralized product of a binary copolymer composed of an olefin and an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms,
(b-3) a ternary copolymer composed of an olefin, an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms and an α,β-unsaturated carboxylic acid ester, and
(b-4) a metal ion-neutralized product of a ternary copolymer composed of an olefin, an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms and an α,β-unsaturated carboxylic acid ester,
(C) the fatty acid metal salt having 18 or less carbon atoms has at least one substituent group selected from the group consisting of a hydroxyl group, a halogen and a dialkylamino group, and
the golf ball resin composition contains the component (C) in an amount of 0.1 parts by mass or more and 4.5 parts by mass or less with respective to 100 parts by mass of a total amount of the component (A) and the component (B).
2. The golf ball resin composition according to claim 1 , wherein a metal ion constituting (C) the fatty acid metal salt having 18 or less carbon atoms is at least one metal ion selected from the group consisting of aluminum ion, sodium ion, zinc ion, calcium ion and magnesium ion.
3. The golf ball resin composition according to claim 1 , wherein a mass ratio ((A)/(B)) of the component (A) to the component (B) ranges from 5/95 to 95/5.
4. The golf ball resin composition according to claim 1 , wherein the component (A) consists of the polyamide or consists of the polyamide and at least one member selected from the group consisting of the ethylene-vinyl alcohol copolymer, the partially saponified product of the ethylene-vinyl acetate copolymer, and the polyvinyl alcohol.
5. The golf ball resin composition according to claim 1 , wherein (C) the fatty acid metal salt having 18 or less carbon atoms is at least one member selected from the group consisting of aluminum 12-hydroxystearate, sodium 12-hydroxystearate, zinc 12-hydroxystearate, and zinc ricinoleate.
6. The golf ball resin composition according to claim 1 , wherein the golf ball resin composition has a melt flow rate (240° C., 2.16 kgf) ranging from 5 g/10 min to 100 g/10 min.
7. The golf ball resin composition according to claim 1 , wherein the golf ball resin composition has a slab hardness ranging from 50 to 80 in Shore D hardness.
8. The golf ball resin composition according to claim 1 , wherein
component (A) includes the polyamide and at least one member selected from the group consisting of the ethylene-vinyl alcohol copolymer, the partially saponified product of the ethylene-vinyl acetate copolymer and the polyvinyl alcohol; and
a mass ratio of the polyamide to the at least one member selected from the group consisting of the ethylene-vinyl alcohol copolymer, the partially saponified product of the ethylene-vinyl acetate copolymer and the polyvinyl alcohol (the polyamide/the at least one member selected from the group consisting of the ethylene-vinyl alcohol copolymer, the partially saponified product of the ethylene-vinyl acetate copolymer and the polyvinyl alcohol) ranges from 2 to 20.
9. A golf ball comprising a core, one or more intermediate layers covering the core, and a cover covering the one or more intermediate layers, wherein at least one layer of the intermediate layers is formed from a golf ball resin composition containing a resin component and (C) a fatty acid metal salt having 18 or less carbon atoms,
wherein the resin component of the golf ball resin composition consists of
a resin component consisting of components (A) and (B),
(A) at least one member selected from the group consisting of a polyamide, an ethylene-vinyl alcohol copolymer, a partially saponified product of an ethylene-vinyl acetate copolymer, and a polyvinyl alcohol, and
(B) at least one resin component selected from the group consisting of
(b-1) a binary copolymer composed of an olefin and an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms,
(b-2) a metal ion-neutralized product of a binary copolymer composed of an olefin and an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms,
(b-3) a ternary copolymer composed of an olefin, an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms and an α,β-unsaturated carboxylic acid ester, and
(b-4) a metal ion-neutralized product of a ternary copolymer composed of an olefin, an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms and an α,β-unsaturated carboxylic acid ester,
(C) the fatty acid metal salt having 18 or less carbon atoms has at least one substituent group selected from the group consisting of a hydroxyl group, a halogen and a dialkylamino group, and
the golf ball resin composition contains the component (C) in an amount of 0.1 parts by mass or more and 4.5 parts by mass or less with respective to 100 parts by mass of a total amount of the component (A) and the component (B).
10. The golf ball according to claim 9 , wherein a metal ion constituting (C) the fatty acid metal salt having 18 or less carbon atoms is at least one metal ion selected from the group consisting of aluminum ion, sodium ion, zinc ion, calcium ion and magnesium ion.
11. The golf ball according to claim 9 , wherein a mass ratio ((A)/(B)) of the component (A) to the component (B) ranges from 5/95 to 95/5.
12. The golf ball according to claim 9 , wherein the component (A) consists of the polyamide or consists of the polyamide and at least one member selected from the group consisting of the ethylene-vinyl alcohol copolymer, the partially saponified product of the ethylene-vinyl acetate copolymer, and the polyvinyl alcohol.
13. The golf ball according to claim 9 , wherein (C) the fatty acid metal salt having 18 or less carbon atoms is at least one member selected from the group consisting of aluminum 12-hydroxystearate, sodium 12-hydroxystearate, zinc 12-hydroxystearate, and zinc ricinoleate.
14. The golf ball according to claim 9 , wherein the golf ball resin composition has a melt flow rate (240° C., 2.16 kgf) ranging from 5 g/10 min to 100 g/10 min.
15. The golf ball according to claim 9 , wherein the golf ball resin composition has a slab hardness ranging from 50 to 80 in Shore D hardness.
16. The golf ball according to claim 9 , wherein
if component (A) includes the polyamide and at least one member selected from the group consisting of the ethylene-vinyl alcohol copolymer, the partially saponified product of the ethylene-vinyl acetate copolymer and the polyvinyl alcohol;
then a mass ratio of the polyamide to the at least one member selected from the group consisting of the ethylene-vinyl alcohol copolymer, the partially saponified product of the ethylene-vinyl acetate copolymer and the polyvinyl alcohol (the polyamide/the at least one member selected from the group consisting of the ethylene-vinyl alcohol copolymer, the partially saponified product of the ethylene-vinyl acetate copolymer and the polyvinyl alcohol) ranges from 2 to 20.