Methods and systems for processing a sucrose crop and sugar mixtures
A method comprising: (a) providing a partially processed sucrose crop product containing at least 2% optionally at least 5% of the sucrose content of said crop at harvest on a dry solids basis, cellulose and lignin; (b) hydrolyzing said partially processed crop product with HCl to produce an acid hydrolyzate stream and a lignin stream; and (c) de-acidifying said hydrolyzate stream to produce a de-acidified sugar solution and an HCl recovery stream. Additional, methods, systems and sugar mixtures are also disclosed.
1. A method comprising:
(a) processing a crop containing a content of sucrose at harvest to produce a partially processed sucrose crop product containing at least 2% of the sucrose content of said crop at harvest on a dry solids basis, cellulose and lignin;
(b) hydrolyzing said partially processed crop product with acid to produce an acid hydrolyzate stream and a lignin stream; and
(c) de-acidifying said hydrolyzate stream to produce a de-acidified sugar solution, the de-acidifying comprising extracting said hydrolyzate stream with a first extractant comprising a first solvent to produce an acid-carrying first extract and the de-acidified sugar solution.
2. A method according to claim 1 , wherein said partially processed crop product comprises sugar cane leaves, sugar cane tops, or a combination thereof.
3. A method according to claim 1 , wherein said de-acidified sugar solution comprises at least 90% of sugars from said at least 2% of said sucrose content.
4. A method according to claim 1 , wherein a ratio of hydroxymethylfurfural to sugars in said hydrolyzate stream is less than 0.01 weight/weight.
5. A method according to claim 1 , wherein a ratio of hydroxymethylfurfural to sugars in said de-acidified sugar solution is less than 0.002 weight/weight.
6. A method according to claim 1 , wherein a ratio of furfural to sugars in said hydrolyzate stream is less than 0.01 weight/weight.
7. A method according to claim 1 , wherein a ratio of furfural to sugars in said de-acidified sugar solution is less than 0.002 weight/weight.
8. A method according to claim 1 , wherein said hydrolyzing comprises contacting said partially processed crop product with said acid in a counter-current mode of operation.
9. A method according to claim 1 , comprising chromatographically separating said acid-depleted sugar solution to produce a monosaccharide: enriched monomer cut.
10. A method according to claim 1 , wherein said first solvent is selected from the group consisting of an alcohol, a ketone having at least 5 carbon atoms, and an aldehyde having at least 5 carbon atoms, and combinations thereof.
11. A method according to claim 1 , wherein said de-acidifying said hydrolyzate stream reduces a concentration of at least one non-saccharide impurity in said hydrolyzate stream by at least 30% on a weight basis relative to the sugar in said solution.
12. A method according to claim 1 , further comprising de-acidifying said lignin stream to form-de-acidified lignin.
13. A method according to claim 1 , wherein said partially processed crop product is produced from an unburned sucrose crop.
14. A method according to claim 1 , further comprising:
providing a culture medium comprising the de-acidified sugar solution; and
growing an organism in said medium to produce a fermentation product.
15. A method according to claim 14 , wherein said fermentation product includes at least one member selected from the group consisting of alcohols, carboxylic acids, amino acids, polymer monomers and proteins.
16. A method according to claim 1 , wherein a ratio of acid to sugars in said de-acidified sugar solution is less than 0.03 weight/weight.
17. A method according to claim 1 , further comprising, prior to (a):
providing a harvested crop containing the amount of sucrose; and
processing said harvested crop to produce a sugar juice containing sucrose and said partially processed crop product.
18. A method according to claim 17 , wherein said sugar juice containing sucrose further comprises an invert sugar.
19. A method according to claim 1 , wherein said partially processed crop product contains at least 5% of the sucrose content of said crop on a dry solids basis.
20. A method according to claim 1 , wherein said first solvent is hexanol, 2-ethylhexanol, or a combination thereof.
21. A method according to claim 1 , wherein the acid is HCl or sulfuric acid.
22. A method according to claim 1 , wherein the de-acidifying further comprises extracting said acid-depleted sugar solution with a second extractant comprising a second solvent to produce an acid-carrying second extract and the de-acidified sugar solution.
23. A method according to claim 22 , wherein the second extractant is characterized by a polarity related component of Hoy's cohesion parameter (delta-P) greater than the delta-P of the first extractant by at least 0.2 MPa 1/2 or a hydrogen-bond related component of Hoy's cohesion parameter (delta-H) greater than the delta-H of the first extractant by at least 0.2 MPa 1/2 .