Peel strength between dissimilar fabrics
Hybrid fibrous composite materials incorporating at least two different fabric components and a multicomponent adhesive system for adhering the fabric components together. The adhesive system enhances the bond strength between the fabric components, which would otherwise easily delaminate from each other and peel apart. The components of the adhesive system bond strongly to each other as well as to the fabric elements.
1. A ballistic resistant composite comprising:
a) a first fibrous layer comprising one or more fibrous plies, said first fibrous layer comprising a plurality of multifilament fibers;
b) a second fibrous layer bonded to the first fibrous layer, said second fibrous layer comprising one or more fibrous plies, said second fibrous layer comprising a plurality of multifilament fibers; and
c) an intermediate multi-component adhesive system positioned between and attached to each of said first fibrous layer and second fibrous layer, said multi-component adhesive system bonding the first fibrous layer and the second fibrous layer to each other, wherein said multi-component adhesive system comprises at least a first polymer layer, a second polymer layer and an adhesion promoter applied between said first polymer layer and said second polymer layer, wherein the first polymer layer is positioned in contact with the first fibrous layer and the second polymer layer is positioned in contact with the second fibrous layer, wherein the first polymer layer comprises a first polymer and the second polymer layer comprises a second polymer, wherein the first polymer and second polymer are different, and wherein the adhesion promoter aids in adhering the first polymer layer and the second polymer layer to each other.
2. The ballistic resistant composite of claim 1 wherein said adhesion promoter is an adhesive film, and wherein at least one of the first fibrous layer and the second fibrous layer is a non-woven fibrous layer comprising unidirectionally oriented multifilament fibers having a tenacity of at least 20 g/denier.
3. The ballistic resistant composite of claim 1 wherein said adhesion promoter comprises one or more adhesive deposits, and wherein at least one of the first fibrous layer and the second fibrous layer comprises multifilament fibers having a tenacity of at least 27 g/denier.
4. The ballistic resistant composite of claim 1 wherein the adhesion promoter comprises a polyethylene, an ethylene copolymer, ethylene vinyl acetate (EVA), polypropylene, a propylene copolymer, polybutadiene, polyisoprene, natural rubber, an ethylene-propylene copolymers, an ethylene-propylene-diene terpolymer, a polysulfide polymer, a polyurethane elastomer, polychloroprene, plasticized polyvinylchloride, a butadiene acrylonitrile elastomer, poly(isobutylene-co-isoprene), a polyacrylate, a polyester, a polyether, a fluoroelastomer, a silicone elastomer, a phenolic, a polybutyral, an epoxy polymer, a styrenic block copolymer or a poly(ester-urethane) copolymer.