IP Library Granted Patent US 10,283,725
Granted Patent B2
US 10,283,725 · App. 15/837,843 · Granted May 7, 2019

Organic Schottky diodes

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Quick Facts
Patent No.
US 10,283,725
App. No.
15/837,843
Granted
May 7, 2019
Kind
B2
Abstract

An organic diode has a substrate, a first conductor layer on the substrate, an organic semiconductor layer on the first conductor layer, and a second conductor layer on the organic substrate layer, wherein one of the conductor layers has an injection enhancement.

Claims (10)

1. A method of printing a diode, comprising:

printing a first conductor on a substrate from a first solution;

depositing an organic semiconductor layer onto the first conductor such that the organic semiconductor layer resides on, and is in contact with, the first conductor; and

printing a second conductor onto the organic semiconductor layer from a second solution, wherein at one least one of the first solution and the second solution has an injection enhancement material mixed into the solution.

2. The method of claim 1 , wherein printing the first conductor comprises printing one of silver, gold, copper, nickel, aluminum, indium-tin-oxide, conductive carbon materials, and silver nanowires.

3. The method of claim 1 , wherein forming the organic semiconductor layer comprises forming one of a pi conjugated polymer, poly(triarylamines), poly(phenylene vinylenes), poly(thiophenes), triarylamine containing polymers, ferrocene containing polymers, polysilanes, and triarylamine molecularly doped polymers.

4. The method of claim 1 , wherein the injection enhancement material is one of the group consisting of: tetracyanoquinodimethane, a derivative of tetracyanoquinodimethane, lithium fluoride, lithium carbonate, cesium fluoride, and cesium carbonate.

5. The method of claim 1 , wherein the first solution and the second solution are the same solution.

6. The method of claim 1 , wherein only one of the first solution and the second solution has the injection enhancement material.

7. The method of claim 1 , wherein both the first solution and the second solution have the injection enhancement material.

Assignments (10)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 6, 2025
From: XEROX CORPORATION
To: GENESEE VALLEY INNOVATIONS, LLC
Reel/Frame 073842/0479 →
SECOND LIEN NOTES PATENT SECURITY AGREEMENT Recorded Jul 2, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 071785/0550 →
FIRST LIEN NOTES PATENT SECURITY AGREEMENT Recorded Apr 11, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 070824/0001 →
SECURITY INTEREST Recorded Feb 13, 2024
From: XEROX CORPORATION
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 066741/0001 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENTS RECORDED AT RF 064760/0389 Recorded Feb 13, 2024
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: XEROX CORPORATION
Reel/Frame 068261/0001 →
SECURITY INTEREST Recorded Nov 20, 2023
From: XEROX CORPORATION
To: JEFFERIES FINANCE LLC, AS COLLATERAL AGENT
Reel/Frame 065628/0019 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVAL OF US PATENTS 9356603, 10026651, 10626048 AND INCLUSION OF US PATENT 7167871 PREVIOUSLY RECORDED ON REEL 064038 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Jun 28, 2023
From: PALO ALTO RESEARCH CENTER INCORPORATED
To: XEROX CORPORATION
Reel/Frame 064161/0001 →
SECURITY INTEREST Recorded Jun 22, 2023
From: XEROX CORPORATION
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 064760/0389 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 20, 2023
From: PALO ALTO RESEARCH CENTER INCORPORATED
To: XEROX CORPORATION
Reel/Frame 064038/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 11, 2017
From: HSIEH, BING R.; NG, TSE NGA; WHITING, GREGORY
To: PALO ALTO RESEARCH CENTER INCORPORATED
Reel/Frame 044356/0637 →