Battery separator with improved oxidation stability
The invention relates to a thermoplastic polymer-based battery separator, which contains a compound of formula R (OR 1 ) n (COOM x+ 1/x ) m . In said formula, R represents a non-aromatic hydrocarbon group comprising between 10 and 4,200 carbon atoms, which can be interrupted by oxygen atoms, R 1 represents H, —(CH 2 ) k COOM x+ 1/x or —(CH 2 ) k —SO 3 M x+ 1/x , whereby k stands for 1 or 2, M represents an alkali or earth alkaline metal ion, H + or NH 4 + , whereby not all variables of M are defined simultaneously as H + , n stands for 0 or 1, m stands for 0 or a whole number from 10 to 1,400 and x stands for 1 or 2. The ratio of oxygen atoms to carbon atoms in the compound according to the aforementioned formula ranges between 1:1.5 and 1:30 and n and m cannot simultaneously represent zero.
1. A non-fibrous extruded and extracted porous battery separator sheet comprising:
an ultra-high molecular-weight polyolefin with an average molecular weight by weight of at least 300,000;
a filler; and
an oxidation stability enhancing compound according to the Formula (I) in the non-fibrous extruded and extracted porous battery separator sheet, on a surface of the non-fibrous extruded and extracted porous battery separator sheet, or both in and on a surface of non-fibrous extruded and extracted porous battery separator sheet,
ROH (I)
in which R is a non-aromatic hydrocarbon radical with 10 to 4200 carbon atoms, which can be interrupted by oxygen atoms, the ratio of oxygen atoms to carbon atoms in the compound according to Formula (I) lying in the range between 1:1.5 and 1:30, and wherein the compound of Formula (I) is not, or is only difficultly, soluble in each of water and sulphuric acid;
said non-fibrous extruded and extracted battery separator sheet comprising, relative to the sum of the weights of the filler and the polyolefin, 10 to 90 wt.-% polyolefin and a filler to polyolefin weight ratio of 1.0 to 5.7, and, relative to the weight of the non-fibrous extruded and extracted battery separator sheet, 5 to 35 wt.-% residual oil after extraction to achieve the porosity of said porous battery separator and 0.5 to 5.0 wt.-% of the compound according to Formula (I).
2. The non-fibrous extruded and extracted porous battery separator sheet of claim 1 , wherein in said Formula (I), R is a hydrocarbon radical with 10 to 180 carbon atoms, which can be interrupted by 1 to 60 oxygen atoms.
3. The non-fibrous extruded and extracted porous battery separator sheet of claim 1 , wherein R is a hydrocarbon radical of the formula R 2 —[(OC 2 H 4 ) p ](OC 3 H 6 ) q ]—, in which
R 2 is an alkyl radical with 10 to 30 carbon atoms,
p is an integer from 0 to 30, and/or
q is an integer from 0 to 30.
4. The non-fibrous extruded and extracted porous battery separator sheet of claim 3 , wherein
p is an integer from 0 to 10 and
q is an integer from 0 to 10.
5. The non-fibrous extruded and extracted porous battery separator sheet of claim 1 , wherein the compound according to Formula (I) is not soluble in each of water and sulphuric acid.
6. The non-fibrous extruded and extracted porous battery separator sheet of claim 1 , wherein said filler is present in an amount of from 50 to 85 wt. %.
7. The non-fibrous extruded and extracted porous battery separator sheet of claim 1 , wherein said filler comprises silica.
8. The non-fibrous extruded and extracted porous battery separator sheet of claim 6 , wherein said filler comprises silica.
9. The non-fibrous extruded and extracted porous battery separator sheet of claim 1 , wherein said polyolefin is polyethylene.
10. The non-fibrous extruded and extracted porous battery separator sheet of claim 1 , wherein the compound according to Formula (I) is in the non-fibrous extruded and extracted porous battery separator sheet.
11. The non-fibrous extruded and extracted porous battery separator sheet of claim 1 , wherein the compound according to Formula (I) is on a surface of the non-fibrous extruded and extracted porous battery separator sheet.
12. The non-fibrous extruded and extracted porous battery separator sheet of claim 1 , wherein the compound according to Formula (I) is in and on a surface of the non-fibrous extruded and extracted porous battery separator sheet.