Composite electrolyte structure and lithium metal battery including the same
A composite electrolyte structure includes: a protective layer having a Young's modulus of about 10 6 pascals or greater and including a first particle, the first particle including an organic particle, an inorganic particle, an organic-inorganic particle, or a combination thereof, wherein the particle in the protective layer has a particle size of greater than 1 micrometer to about 100 micrometers, and a solid electrolyte layer including a second particle including an organic particle, an inorganic particle, an organic-inorganic particle, or a combination thereof, wherein the second particle has a particle size of greater than 1 micrometer to about 100 micrometers, wherein the first particle and the second particle are the same or different, and wherein the protective layer is on the solid electrolyte layer.
1. A composite electrolyte structure comprising:
a protective layer having a Young's modulus of about 10 6 pascals to about 10 11 pascals and comprising a crosslinked polymer and a first particle, the first particle comprising an organic particle,
wherein the first particle has a particle size of greater than 1 micrometer to about 100 micrometers,
wherein the crosslinked polymer is a crosslinked material of a polymerizable compound and the crosslinked polymer is between first particles of the protective layer, and
wherein an amount of the crosslinked polymerizable compound is in a range of about 10 parts by weight to about 50 parts by weight, based on 100 parts by weight of the first particle in the protective layer; and
a solid electrolyte layer comprising a polymer, a lithium salt, and a second particle, the second particle comprising an organic particle, wherein the second particle has an average particle size of greater than 1 micrometer to about 100 micrometers,
wherein the protective layer is on the solid electrolyte layer,
wherein the first particle and the second particle are the same or different, and
wherein the first particle of the protective layer and the second particle of the solid electrolyte layer each independently comprise a homopolystyrene, a copolymer comprising a styrene repeating unit, or a combination thereof.
2. The composite electrolyte structure of claim 1 , wherein the first particle and the second particle are each a porous hollow particle.
3. The composite electrolyte structure of claim 1 , wherein the first particle or the second particle comprises a porous particle having an average pore diameter of about 10 nanometers to about 50 nanometers.
4. The composite electrolyte structure of claim 1 , wherein the first particle or the second particle comprises a microsphere having an average diameter of about 1.1 micrometer to about 50 micrometers.
5. The composite electrolyte structure of claim 1 , wherein the polymerizable compound in the protective layer comprises diethylene glycol diacrylate, triethylene glycol diacrylate, tetraethylene glycol diacrylate, polyethylene glycol diacrylate, dipropylene glycol diacrylate, tripropylene glycol diacrylate), ethoxylated trimethylolpropane triacrylate, acrylate-functionalized ethylene oxide, 1,6-hexanediol diacrylate, ethoxylated neopentyl glycol diacrylate, propoxylated neopentyl glycol diacrylate, allyl methacrylate, trimethylolpropane triacrylate, trimethylolpropane trimethacrylate, pentaerythritol triacrylate, ethoxylated propoxylated trimethylolpropane triacrylate, glyceryl/propoxylated triacrylate, tris(2-hydroxyethyl) isocyanurate triacrylate, pentaerythritol tetraacrylate, dipentaerythritol pentaacrylate, dipentaerythritol pentaacrylate, or a combination thereof.
6. A lithium metal battery comprising:
an anode comprising a lithium metal electrode comprising lithium metal or a lithium metal alloy;
the composite electrolyte structure of claim 1 between the anode and the cathode, wherein the protective layer of the composite electrolyte is on at least a portion of the lithium metal electrode; and
a cathode.
7. A method of manufacturing a composite electrolyte structure, the method comprising:
providing a first composition for forming a protective layer, the first composition comprising a polymerizable compound and a first particle comprising an organic particle;
disposing the first composition on a substrate and crosslinking and polymerizing the polymerizable compound to form a protective layer having a Young's modulus of about 10 6 pascals to about 10 11 pascals and comprising a crosslinked polymer and the first particle,
wherein the first particle has a particle size of greater than 1 micrometer to about 100 micrometers,
wherein the crosslinked polymer is a crosslinked material of the polymerizable compound and is between first particles of the protective layer, and
wherein an amount of the crosslinked polymerizable compound is in a range of about 10 parts by weight to about 50 parts by weight, based on 100 parts by weight of the first particle in the protective layer;
providing a second composition for forming a solid electrolyte, the second composition comprising a polymer, a first lithium salt, and a second particle comprising an organic particle, wherein the second particle has an average particle size of greater than 1 micrometer to about 100 micrometers; and
disposing the second composition on the protective layer to form a solid electrolyte layer on the protective layer,
wherein the first particle and the second particle are the same or different, and
wherein the first particle in the protective layer and the second particle of the solid electrolyte layer each independently comprises a homopolystyrene, a copolymer comprising a styrene repeating unit, or a combination thereof.