Electrolyte and lithium-ion battery
The present disclosure provides an electrolyte and a lithium-ion battery. The electrolyte comprises: an organic solvent; a lithium salt dissolved in the organic solvent; and an additive. The additive comprises trifluoromethanesulfonate silyl compound, lithium fluorophosphate compound and cyclic phosphonitrile compound. The electrolyte of the present disclosure can significantly decrease the low temperature resistance of the lithium-ion battery, and improve the power performance of the lithium-ion battery, and the electrolyte of present disclosure can also significantly inhibit the gas generation during the cycle process and the storage process of the lithium-ion battery, and significantly improve the cycle performance, the high temperature storage performance and the safety performance of the lithium-ion battery.
1. An electrolyte, comprising:
an organic solvent;
a lithium salt dissolved in the organic solvent; and
an additive;
the additive comprising trifluoromethanesulfonate silyl compound, lithium fluorophosphate compound and cyclic phosphonitrile compound;
the trifluoromethanesulfonate silyl compound being one or more selected from a group consisting of trimethylsilyl trifluoromethanesulfonate, diethylmethylsilyl trifluoromethanesulfonate, triethylsilyl trifluoromethanesulfonate, trifluoromethyldimethylsilyl trifluoromethanesulfonate, tri(trifluoromethyl)silyl trifluoromethanesulfonate, dimethylethylsilyl trifluoromethanesulfonate, trivinylsilyl trifluoromethanesulfonate, triethynylsilyl trifluoromethanesulfonate and triethoxsilyl trifluoromethanesulfonate;
a content of the trifluoromethanesulfonate silyl compound being 0.1%-8% of a total weight of the electrolyte;
a content of the lithium fluorophosphate compound being 0.1%-5% of the total weight of the electrolyte;
a content of the cyclic phosphonitrile compound being 0.1%-8% of the total weight of the electrolyte; and
a content of the lithium salt being 6.25%-25% of the total weight of the electrolyte.
2. The electrolyte according to claim 1 , wherein the lithium fluorophosphate compound is one or two selected from a group consisting of LiPO 2 F 2 and LiPOF 4 .
3. The electrolyte according to claim 1 , wherein a structural formula of the cyclic phosphonitrile compound is represented by formula 2;
in formula 2, R 4 , R 5 , R 6 , R 7 , R 8 , R 9 each are independently one selected from a group consisting of H, halogen atom, C 1-20 alkyl, C 2-20 alkenyl, C 2-20 alkynyl, C 6-20 aryl, C 1-20 haloalkyl, C 2-20 haloalkenyl, C 2-20 haloalkynyl, C 6-20 haloaryl, C 1-20 alkoxy, C 2-20 alkenoxy, C 2-20 alkynoxy, C 6-20 aryloxy, C 1-20 haloalkoxy, C 2-20 haloalkenoxy, C 2-20 haloalkynoxy and C 6-20 haloaryloxy, and at least two of R 5 , R 7 and R 9 are a halogen atom.
4. The electrolyte according to claim 3 , wherein at least one of R 4 , R 6 , R 8 is one selected from a group consisting of C 1-20 alkoxy, C 2-20 alkenoxy, C 2-20 alkynoxy, C 6-20 aryloxy, C 1-20 haloalkoxy, C 2-20 haloalkenoxy, C 2-20 haloalkynoxy and C 6-20 haloaryloxy.
5. The electrolyte according to claim 3 , wherein the cyclic phosphonitrile compound is one or more selected from the group of compounds consisting of:
6. The electrolyte according to claim 1 , wherein
the content of the trifluoromethanesulfonate silyl compound is 0.3%-5% of the total weight of the electrolyte;
the content of the lithium fluorophosphate compound is 0.5%-3% of the total weight of the electrolyte;
the content of the cyclic phosphonitrile compound is 1%-5% of the total weight of the electrolyte.
7. The electrolyte according to claim 1 , wherein the additive further comprises one or more selected from a group consisting of fluoro-cyclic carbonate ester, 1,3-propylene sulfite and vinylene carbonate;
a content of the fluoro-cyclic carbonate ester is 1%-5% of the total weight of the electrolyte;
a content of 1,3-propylene sulfite is 1%-5% of the total weight of the electrolyte; and
a content of vinylene carbonate is 1%-5% of the total weight of the electrolyte.
8. A lithium-ion battery comprising an electrolyte, the electrolyte comprising:
an organic solvent;
a lithium salt dissolved in the organic solvent; and
an additive;
the additive comprising trifluoromethanesulfonate silyl compound, lithium fluorophosphate compound and cyclic phosphonitrile compound;
the trifluoromethanesulfonate silyl compound being one or more selected from a group consisting of trimethylsilyl trifluoromethanesulfonate, diethylmethylsilyl trifluoromethanesulfonate, triethylsilyl trifluoromethanesulfonate, trifluoromethyldimethylsilyl trifluoromethanesulfonate, tri(trifluoromethyl)silyl trifluoromethanesulfonate, dimethylethylsilyl trifluoromethanesulfonate, trivinylsilyl trifluoromethanesulfonate, triethynylsilyl trifluoromethanesulfonate and triethoxsilyl trifluoromethanesulfonate;
a content of the trifluoromethanesulfonate silyl compound being 0.1%-8% of a total weight of the electrolyte;
a content of the lithium fluorophosphate compound being 0.1%-5% of the total weight of the electrolyte;
a content of the cyclic phosphonitrile compound being 0.1%-8% of the total weight of the electrolyte;
a content of the lithium salt being 6.25%-25% of the total weight of the electrolyte.
9. The lithium-ion battery according to claim 8 , wherein the lithium fluorophosphate compound is one or two selected from a group consisting of LiPO 2 F 2 and LiPOF 4 .
10. The lithium-ion battery according to claim 8 , wherein a structural formula of the cyclic phosphonitrile compound is represented by formula 2;
in formula 2, R 4 , R 5 , R 6 , R 7 , R 8 , R 9 each are independently one selected from a group consisting of H, halogen atom, C 1-20 alkyl, C 2-20 alkenyl, C 2-20 alkynyl, C 6-20 aryl, C 1-20 haloalkyl, C 2-20 haloalkenyl, C 2-20 haloalkynyl, C 6-20 haloaryl, C 1-20 alkoxy, C 2-20 alkenoxy, C 2-20 alkynoxy, C 6-20 aryloxy, C 1-20 haloalkoxy, C 2-20 haloalkenoxy, C 2-20 haloalkynoxy and C 6-20 haloaryloxy, and at least two of R 5 , R 7 and R 9 are a halogen atom.
11. The electrolyte lithium-ion battery according to claim 10 , wherein at least one of R 4 , R 6 , R 8 is one selected from a group consisting of C 1-20 alkoxy, C 2-20 alkenoxy, C 2-20 alkynoxy, C 6-20 aryloxy, C 1-20 haloalkoxy, C 2-20 haloalkenoxy, C 2-20 haloalkynoxy and C 6-20 haloaryloxy.
12. The lithium-ion battery according to claim 10 , wherein the cyclic phosphonitrile compound is one or more selected from the group of compounds consisting of:
13. The lithium-ion battery according to claim 8 , wherein
the content of the trifluoromethanesulfonate silyl compound is 0.3%-5% of the total weight of the electrolyte;
the content of the lithium fluorophosphate compound is 0.5%-3% of the total weight of the electrolyte;
the content of the cyclic phosphonitrile compound is 1%-5% of the total weight of the electrolyte.
14. The lithium-ion battery according to claim 8 , wherein the additive further comprises one or more selected from a group consisting of fluoro-cyclic carbonate ester, 1,3-propylene sulfite and vinylene carbonate;
a content of the fluoro-cyclic carbonate ester is 1%-5% of the total weight of the electrolyte;
a content of 1,3-propylene sulfite is 1%-5% of the total weight of the electrolyte;
a content of vinylene carbonate is 1%-5% of the total weight of the electrolyte.