Rubber composition, crosslinked rubber molded product and golf ball
An object of the present invention is to provide a rubber composition from which a crosslinked rubber molded product excellent in the resilience performance can be obtained. The present invention provides a rubber composition containing (a) a base rubber, (b) a co-crosslinking agent and (c) a crosslinking initiator, wherein (b) the co-crosslinking agent contains a complex represented by a general formula (1). ((RCOO) 8 M 5 (OH) 2 ) n (1) [In the formula (1), M is a metal atom, R is a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, an alkenyl group having 2 to 18 carbon atoms or an alkynyl group having 2 to 18 carbon atoms, and n is an integer of 1 or more. A plurality of R and M may be identical to or different from each other. At least one of R is the alkenyl group having 2 to 18 carbon atoms or the alkynyl group having 2 to 18 carbon atoms.]
1. A rubber composition containing (a) a base rubber, (b) a co-crosslinking agent and (c) a crosslinking initiator, wherein (b) the co-crosslinking agent contains a complex represented by a general formula (1):
((RCOO) 8 M 5 (OH) 2 ) n (1)
in the formula (1), M is a metal atom, R is a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, an alkenyl group having 2 to 18 carbon atoms or an alkynyl group having 2 to 18 carbon atoms, n is an integer of 1 or more, a plurality of R and M may be identical to or different from each other, and at least one of R is the alkenyl group having 2 to 18 carbon atoms or the alkynyl group having 2 to 18 carbon atoms.
2. The rubber composition according to claim 1 , wherein (b) the co-crosslinking agent contains the complex represented by the general formula (1) in an amount of 5 mass % or more.
3. The rubber composition according to claim 1 , wherein in the general formula (1), at least one of R is an alkenyl group having 2 to 8 carbon atoms and a carbon-carbon double bond at a terminal thereof, or an alkynyl group having 2 to 8 carbon atoms and a carbon-carbon triple bond at a terminal thereof.
4. The rubber composition according to claim 1 , wherein the complex represented by the general formula (1) is a complex represented by a structural formula (2):
in the formula (2), M 1 to M 5 are identical to or different from each other and represent a metal atom, R 1 to R 8 are identical to or different from each other and represent a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, an alkenyl group having 2 to 18 carbon atoms or an alkynyl group having 2 to 18 carbon atoms, n is an integer of 1 or more, and at least one of R 1 to R 8 is the alkenyl group having 2 to 18 carbon atoms or the alkynyl group having 2 to 18 carbon atoms.
5. The rubber composition according to claim 4 , wherein n in the formula (2) is 1, and the complex represented by the structural formula (2) has a structure represented by a structural formula (3):
in the formula (3), M 1 to M 5 are identical to or different from each other and represent a metal atom, R 1 to R 8 are identical to or different from each other and represent a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, an alkenyl group having 2 to 18 carbon atoms or an alkynyl group having 2 to 18 carbon atoms, and at least one of R 1 to R 8 is the alkenyl group having 2 to 18 carbon atoms or the alkynyl group having 2 to 18 carbon atoms.
6. The rubber composition according to claim 1 , wherein (a) the base rubber contains a diene rubber or a natural rubber.
7. The rubber composition according to claim 1 , wherein the rubber composition contains (b) the co-crosslinking agent in an amount ranging from 1 part by mass to 50 parts by mass with respect to 100 parts by mass of (a) the base rubber.
8. The rubber composition according to claim 1 , wherein the metal atom of the complex represented by the general formula (1) has oxidation number of +2.
9. The rubber composition according to claim 1 , wherein the rubber composition further contains (d) a metal compound.
10. The rubber composition according to claim 9 , wherein (d) the metal compound is at least one metal oxide selected from the group consisting of calcium oxide, zinc oxide and magnesium oxide.
11. The rubber composition according to claim 9 , wherein the rubber composition contains (d) the metal compound in an amount ranging from 0.5 part by mass to 20 parts by mass with respect to 100 parts by mass of (a) the base rubber.
12. The rubber composition according to claim 9 , wherein (a) the base rubber contains a diene rubber or a natural rubber, (b) the co-crosslinking agent contains the complex represented by the general formula (1) in an amount of 5 mass % or more, and in the general formula (1), at least two of R are an alkenyl group having 2 to 8 carbon atoms and a carbon-carbon double bond at a terminal thereof, or an alkynyl group having 2 to 8 carbon atoms and a carbon-carbon triple bond at a terminal thereof.
13. A crosslinked rubber molded product formed from the rubber composition according to claim 12 and having a slab hardness in a range from 20 to 98 in Shore C hardness.
14. A crosslinked rubber molded product formed from the rubber composition according to claim 12 and having a Lupke type rebound resilience (JIS K6255) in a range from 55% to 98%.
15. A crosslinked rubber molded product formed from the rubber composition according to claim 12 and having a storage modulus E′ (Pa) in a range from 3.0×10 7 Pa to 40×10 7 Pa, wherein the storage modulus E′ (Pa) is measured with a dynamic viscoelasticity measuring apparatus under conditions of: tensile mode, measuring temperature of 24° C., oscillation frequency of 10 Hz and measuring strain of 0.05%.
16. A crosslinked rubber molded product formed from the rubber composition according to claim 12 and having a loss modulus E″ (Pa) in a range from 0.001×10 7 Pa to 3.0×10 7 Pa, wherein the loss modulus E″ (Pa) is measured with a dynamic viscoelasticity measuring apparatus under conditions of: tensile mode, measuring temperature of 24° C., oscillation frequency of 10 Hz and measuring strain of 0.05%.
17. A crosslinked rubber molded product formed from the rubber composition according to claim 12 and having a slab hardness (Shore C) X and a Lupke type rebound resilience (JIS K6255) (%) Y satisfying a relationship of Y≥87−0.283X.
18. A crosslinked rubber molded product formed from the rubber composition according to claim 12 and having a storage modulus E′ (Pa), a loss modulus E″ (Pa) and a slab hardness (Shore C) X satisfying a relationship of |log(E′/E″ 2 )|/X×100≤5.7, wherein the storage modulus E′ (Pa) and the loss modulus E″ (Pa) are measured with a dynamic viscoelasticity measuring apparatus under conditions of: tensile mode, measuring temperature of 24° C., oscillation frequency of 10 Hz and measuring strain of 0.05%.
19. A crosslinked rubber molded product formed from the rubber composition according to claim 1 .
20. A golf ball comprising a constituent member formed from the rubber composition according to claim 1 .