CPE/CR blend co-cured by a thiadiazole or triazine cure system
View Patent ↗Fuel lines including an inner tube, a reinforcement layer disposed outwardly from the inner tube, and a cover layer disposed outwardly from the reinforcement layer. The cover layer and/or inner tube are formed from compositions including a blend of chlorinated polyethylene (CPE) and chloroprene rubber (CR), where the CPE and CR are blended in a CPE:CR weight ratio of from 20:1 to 1:1. The compositions also include a curing system containing tetrabutylammonium bromide (TBAB), magnesium oxide (MgO), and one of a thiadiazole or thiotriazine. In some aspects, the TBAB is incorporated in an amount of from 0.2 phr to 2.5 phr, the MgO incorporated in an amount of from 5 phr to 20 phr, and the one of a thiadiazole or thiotriazine incorporated in an amount of from 0.5 phr to 5 phr.
1. A composition comprising:
a) a blend of chlorinated polyethylene (CPE) and chloroprene rubber (CR), wherein the CPE and CR are blended in a CPE:CR weight ratio of from 20:1 to 1:1; and,
b) a curing system comprising tetrabutylammonium bromide (TBAB), magnesium oxide (MgO), and thiotriazine.
2. The composition according to claim 1 , wherein the TBAB is incorporated in an amount of from 0.2 phr to 2.5 phr, wherein the MgO is incorporated in an amount of from 5 phr to 20 phr, and wherein the thiotriazine is incorporated in an amount of from 0.5 phr to 5 phr, and wherein the composition is devoid of a conventional plasticizer.
3. The composition according to claim 1 , wherein the curing system devoid of free sulfur and peroxide.
4. The composition according to claim 1 , the composition further comprising antimony trioxide.
5. The composition according to claim 1 , wherein the TBAB is incorporated in an amount of from 0.3 phr to 2 phr.
6. The composition according to claim 1 , wherein the thiotriazine is incorporated in an amount of from 0.8 phr to 3 phr.
7. The composition according to claim 1 , wherein the CPE:CR weight ratio is of from 9:1 to 7:3.
8. The composition according to claim 1 as incorporated into a cover layer of a rubber article.
9. The composition according to claim 1 as incorporated into an inner tube layer of a rubber article.
10. The composition according to claim 1 as incorporated into one or more layers of a fuel line, a welding hose, a cold side return turbo charger hose, a conveyor belt, a power transmission belt, or an air spring.
11. A fuel line comprising an inner tube, a reinforcement layer disposed outwardly from the inner tube, and a cover layer disposed outwardly from the reinforcement layer;
wherein the cover layer comprises:
a) a blend of chlorinated polyethylene (CPE) and chloroprene rubber (CR), wherein the CPE and CR are blended in a CPE:CR weight ratio of from 20:1 to 1:1; and,
b) a curing system comprising tetrabutylammonium bromide (TBAB), magnesium oxide (MgO), and thiotriazine; and,
wherein the cover layer meets the specifications of SAE International Standard J30 201202.
12. The fuel line according to claim 11 , wherein the TBAB is incorporated in an amount of from 0.2 phr to 2.5 phr, wherein the MgO is incorporated in an amount of from 5 phr to 20 phr, and wherein the thiotriazine is incorporated in an amount of from 0.5 phr to 5 phr, and wherein the composition is devoid of a conventional plasticizer.
13. The fuel line according to claim 11 , wherein the curing system devoid of free sulfur and peroxide.
14. The fuel line according to claim 11 , the cover layer further comprising antimony trioxide.
15. The fuel line according to claim 11 , wherein the TBAB is incorporated in an amount of from 0.3 phr to 2 phr.
16. The fuel line according to claim 11 , wherein the thiotriazine is incorporated in an amount of from 0.8 phr to 3 phr.
17. The fuel line according to claim 11 , wherein the CPE:CR weight ratio is of from 9:1 to 7:3.
18. The fuel line according to claim 11 , wherein the inner tube comprises a blend of chlorinated polyethylene (CPE) and chloroprene rubber (CR), wherein the CPE and CR are blended in a CPE:CR weight ratio of from 20:1 to 1:1.
19. The fuel line according to claim 11 , wherein the inner tube comprises nitrile butadiene rubber (NBR).
20. A hose comprising an inner tube, a reinforcement layer disposed outwardly from the inner tube, and a cover layer disposed outwardly from the reinforcement layer;
wherein the inner tube comprises:
a) a blend of chlorinated polyethylene (CPE) and chloroprene rubber (CR), wherein the CPE and CR are blended in a CPE:CR weight ratio of from 20:1 to 1:1; and,
b) a curing system comprising tetrabutylammonium bromide (TBAB), magnesium oxide (MgO), and thiotriazine.