IP Library Granted Patent US 11,001,918
Granted Patent B2
US 11,001,918 · App. 15/852,629 · Granted May 11, 2021

High-strength hot-dip galvanized steel sheet having excellent plating surface quality and adhesion, and method of manufacturing the same

Inventors: Myung-Soo Kim (Gwangyang-si, KR); Jong-Sang Kim (Gwangyang-si, KR); Young-Ha Kim (Gwangyang-si, KR); Joong-Chul Park (Gwangyang-si, KR)
Assignee: POSCO
C23C2/02B32B15/011B32B15/013C21D9/46C22C38/02C22C38/04C22C38/06C23C2/06C23C2/28C23C2/40C23C28/322C23C28/3225C23C28/345C23C28/36C25D5/48C25D7/0614C25D3/20Y10T428/12799
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Quick Facts
Patent No.
US 11,001,918
App. No.
15/852,629
Granted
May 11, 2021
Kind
B2
Abstract

Provided is a method of manufacturing a hot-dip galvanized steel sheet. According to an aspect of the present invention, the method may include preparing a base steel sheet, forming a iron (Fe)-plated layer on the prepared base steel sheet, oxidation heating the steel sheet having the Fe-plated layer formed thereon at a temperature ranging from 600° C. to 800° C., maintaining the heated steel sheet at a temperature ranging from 750° C. to 900° C. for 5 seconds or more in a reducing atmosphere with a dew point of between −30° C. to 5° C. including 20 ppm or less of oxygen, 1 vol % to 20 vol % of H 2 , and N 2 as well as unavoidable gases as a remainder, cooling the maintained steel sheet, and plating the cooled steel sheet by dipping in a hot-dip galvanizing bath.

Claims (16)

1. A method of manufacturing a hot-dip galvanized steel sheet, the method comprising:

preparing a base steel sheet;

forming an iron-plated layer on the base steel sheet to form an iron-plated steel sheet;

oxidation heating the iron-plated steel sheet at a temperature ranging from 600° C. to 800° C. to form a heated steel sheet;

maintaining the heated steel sheet at a temperature ranging from 750° C. to 900° C. for 5 seconds or more in a reducing atmosphere with a dew point of between −30° C. to 5° C. to form a maintained steel sheet, the reducing atmosphere including 20 ppm or less of oxygen, 1 vol % to 20 vol % of H 2 , and N 2 and unavoidable gases as a remainder, respectively based on a total volume of atmospheric gas;

cooling the maintained steel sheet to form a cooled steel sheet; and

dipping the cooled steel sheet in a hot-dip galvanizing bath to form the hot-dip galvanized steel sheet,

wherein the oxidation heating is performed in a direct flame furnace by controlling an air-fuel ratio; and the air-fuel ratio is controlled as follows: (1100/(C 0.09 ×T))+(100/T)≤air-fuel ratio≤(1450/(C 0.09 ×T))+(100/T) where C is a coating weight (mg/m 2 ) of the iron-plated layer and T is a temperature (° C.) of the direct flame furnace, or

wherein the oxidation heating is performed in a radiant tube flame furnace in an atmosphere having 5 vol % or less of H 2 , 20 ppm or less of O 2 and N 2 as a remainder, respectively based on a total volume of atmospheric gas; and an oxygen content in an oxidation region in the radiant tube flame furnace is controlled as follows:

(4000/(C 0.2 ×T 0.08 ))+(3500/T)≤oxygen content (ppm)≤(5800/(C 0.2 ×T 0.08 ))+(3850/T) where C is a coating weight (mg/m 2 ) of the iron-plated layer and Tis a temperature (° C.) of the radiant tube flame furnace.

2. The method of claim 1 , wherein the base steel sheet comprises: 0.3 wt % or less of carbon (C); and 1.0 wt % to 6.0 wt % of one or more of silicon (Si), manganese (Mn), and aluminum (Al).

3. The method of claim 1 , wherein the base steel sheet comprises: one or more of chromium (Cr), nickel (Ni), copper (Cu), molybdenum (Mo), phosphorous (P), sulfur (S), antimony (Sb), titanium (Ti), niobium (Nb), and nitrogen (N), wherein each of the one or more is contained in an amount of 0.5 wt % or less.

4. The method of claim 1 , wherein the coating weight is in a range of 0.2 g/m 2 to 2 g/m 2 .

5. The method of claim 1 , wherein the forming of the iron-plated layer is performed by using an electroplating method.

6. The method of claim 1 , wherein a temperature of the hot-dip galvanizing bath is in a range of 440° C. to 480° C.

7. The method of claim 1 , further comprising: heating the hot-dip galvanized steel sheet to a temperature ranging from 480° C. to 650° C.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 26, 2022
From: POSCO HOLDINGS INC.
To: POSCO CO., LTD
Reel/Frame 061778/0785 →
CHANGE OF NAME Recorded Sep 28, 2022
From: POSCO
To: POSCO HOLDINGS INC.
Reel/Frame 061561/0923 →
Priority Claims (1)
KR 10-2011-0145233 · Dec 28, 2011 · national
Continuity (2)
Division 14369577
Related Publication 20180119263A1 · May 3, 2018