Flame retardant polyamide composition
Flame retardant polyamide compositions comprise (A) a semi-crystalline semi-aromatic polyamide having a melting temperature (TmA) and having a number average molecular weight in the range between 7,500 and 30,000 g/mol; (B) a semi-crystalline aliphatic polyamide having a melting temperature (TmB); and having a number average molecular weight in the range between 7,500 and 50,000 g/mol; and (C) a halogen free flame retardant system comprising a metal salt of a phosphinic acid and/or a diphosphinic acid, wherein TmA is higher than TmB and weight ratio of (A):(B) is in the range between 50:50 and 75:25. Process for moulding the flame retardant polyamide composition, and moulded parts made of the flame retardant polyamide composition are also provided.
1. An injection molded part made of a flame retardant polyamide composition consisting of:
(A)/(B) 30-90 wt. % of a polyamide (A) and a polyamide (B) in a weight ratio of the polyamide (A) to the polyamide (B) in a range between 55:45-72.5:27.5;
(C) 5-25 wt. % of a metal(di)phosphinate;
(D) 0-60 wt. % of inorganic fillers and/or fibrous reinforcing agents; and
(E) 0-40 wt. % of other components; wherein
the polyamide (A) is a semi-crystalline semi-aromatic polyamide having a melting temperature (TmA) in a range of 290-350° C. and a number average molecular weight (Mn-A) in a range between 10,000 and 30,000 g/mol; and
the polyamide (B) is a semi-crystalline aliphatic polyamide having a melting temperature (TmB) in a range of 250-300° C. and a number average molecular weight (Mn-B) in a range between 7,500 and 50,000 g/m, and wherein
the melting temperature TmA is higher than the melting temperature TmB.
2. The injection molded part according to claim 1 , wherein the flame retardant polyamide composition consists of:
(A)/(B) 30-87 wt. % of the polyamide (A) and the polyamide (B) in a weight ratio of the polyamide (A) to the polyamide (B) in the range between 55:45-72.5:27.5;
(C) 7.5-20 wt. % of the metal(di)phosphinate;
(D) 5-55 wt. % of the inorganic fillers and/or fibrous reinforcing agents; and
(E) 0.5-20 wt. % of the other components.
3. The injection molded part according to claim 1 , wherein Mn-A is in the range of 10,000-25,000 g/mol and/or wherein Mn-B in the range of 10,000-40,000 g/mol.
4. The injection molded part according to claim 1 , wherein the flame retardant system (C) comprises an aluminium (di)phosphinate.
5. The injection molded part according to claim 1 , wherein the composition comprises at most 1 wt. % ZnBorate.
6. The injection molded part according to claim 1 , wherein the composition comprises 5-25 wt. % of the metal(di)phosphinate (C), and 5-60 wt. % of the inorganic fillers and/or fibrous reinforcing agents (D), wherein the inorganic fillers and/or fibrous reinforcing agents (D) are glass or carbon reinforcement fibers, and wherein the wt. % is relative to total weight of the composition.
7. A plastic part for a connector which comprises the injection molded part according to claim 1 .
8. A housing or a stiffener frame for an electronic device which comprises the injection molded part according to claim 1 .
9. A process for producing injection moulded parts from a flame retardant polyamide composition comprising the steps of:
(a) providing the flame retardant polyamide composition according to claim 1 ;
(b) heating the flame retardant polyamide composition in an injection moulding machine to a temperature of at most 10° C. above TmA to form a polymer melt of the flame retardant polyamide composition; and
(c) injection moulding the polymer melt by injecting the polymer melt into a mould to form the injection moulded part.
10. The process according to claim 9 , wherein step (c) is practiced by injecting the polymer into the mould having a mould temperature of at least 100° C.
11. The process according to claim 10 , wherein step (c) is practiced by injecting the polymer melt into the mould having a mould temperature in a range of 110-150° C.