IP Library Granted Patent US 10,133,203
Granted Patent B2
US 10,133,203 · App. 15/873,351 · Granted Nov 20, 2018

Toner formulation having a silane surface treated on its outer surface and method of preparing the same

Inventors: Danielle Renee Ashley (Longmont, CO); Ligia Aura Bejat (Lexington, KY); Michael James Bensing (Lexington, KY); Ashley Schafer Grant (Lexington, KY); Cory Nathan Hammond (Winchester, KY); Rick Owen Jones (Berthoud, CO); John Joseph Kraseski (Lexington, KY); Jing X Sun (Lexington, KY)
Assignee: LEXMARK INTERNATIONAL, INC.
G03G9/09392G03G9/0812G03G9/0827G03G9/08755G03G9/09307G03G9/09321G03G9/09328G03G9/09335G03G9/09342G03G9/09364G03G9/09371
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Quick Facts
Patent No.
US 10,133,203
App. No.
15/873,351
Granted
Nov 20, 2018
Kind
B2
Abstract

A method for producing core shell toner for electrophotography according to one embodiment, includes surface treating the outer surface of a core shell toner particle with a alkoxysilane hydrocarbon or combination of different alkoxysilane hydrocarbons using a hydrolytic deposition process after the core shell toner particle is fully formed. This method results in the bonding of the alkoxysilane hydrocarbon or combination of different alkoxysilane hydrocarbons to the outer surface of the core shell toner particle. In an alternative method, the outer surface of the toner is surface treated with the alkoxysilane hydrocarbon solution and then fused to form toner particles. The alkoxysilane hydrocarbon surface treated core shell toner also can be mixed with magnetic carrier beads to form a developer mix to be used in a dual component development electrophotographic printer.

Claims (10)

1. A method for producing toner comprising:

combining and agglomerating a first polymer emulsion with a pigment dispersion and a wax dispersion to form toner cores;

combining and agglomerating a second polymer emulsion with the toner cores to form toner shells around the toner cores;

fusing the aggregated toner cores and toner shells to form toner particles; and

treating the surface of the formed toner particles with 1,3-di-n-octyltetramethyldisiloxane and diethoxydimethylsilane, wherein alkoxy groups in the 1,3-di-n-octyltetramethyldisiloxane and diethoxydimethylsilane covalently bond to functional groups located on the outer surface of the toner particle.

2. A method for producing toner comprising:

combining and agglomerating a first polymer emulsion with a pigment dispersion and a wax dispersion to form toner cores;

combining and agglomerating a second polymer emulsion with the toner cores to form toner shells around the toner cores;

fusing the aggregated toner cores and toner shells to form toner particles; and

treating the surface of the formed toner particles with n-octadecyltrimethoxysilane, wherein alkoxy groups in the n-octadecyltrimethoxysilane covalently bond to functional groups located on the outer surface of the toner particle.

Assignments (5)
SECURITY INTEREST Recorded Jan 5, 2026
From: LEXMARK INTERNATIONAL, INC.
To: BANK TRUST COMPANY, NATIONAL ASSOCIATION
Reel/Frame 074202/0192 →
SECURITY INTEREST Recorded Jan 5, 2026
From: LEXMARK INTERNATIONAL, INC.
To: BANK TRUST COMPANY, NATIONAL ASSOCIATION
Reel/Frame 074202/0293 →
SECURITY INTEREST Recorded Sep 23, 2025
From: LEXMARK INTERNATIONAL, INC.
To: CITIBANK, N.A.
Reel/Frame 073007/0118 →
SECURITY INTEREST Recorded Sep 23, 2025
From: LEXMARK INTERNATIONAL, INC.
To: JEFFERIES FINANCE LLC
Reel/Frame 073007/0346 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 17, 2018
From: BEJAT, LIGIA AURA; BENSING, MICHAEL JAMES; GRANT, ASHLEY SCHAFER; DAHLKE, AARON MICHAEL; HAMMOND, CORY NATHAN; SUN, JING X; ASHLEY, DANIELLE RENEE; JONES, RICK OWEN; KRASESKI, JOHN JOSEPH
To: LEXMARK INTERNATIONAL, INC.
Reel/Frame 044641/0794 →
Continuity (2)
Continuation 15355698 · Nov 18, 2016
Related Publication 20180143556A1 · May 24, 2018