VES fluids having improved rheology at high temperature and high salinity
View Patent ↗A viscoelastic surfactant treatment fluid comprises an aqueous base fluid an inorganic salt, the inorganic salt being present in an amount of greater than about 5 wt. % based on the total weight of the treatment fluid; a viscoelastic surfactant gelling agent effective to gel the aqueous base fluid by forming a plurality of micelles; and a cationic polymer additive associated with the micelles via electrostatic interactions.
1. A method of improving a rheological property of a viscoelastic surfactant treatment fluid, the method comprising:
gelling an aqueous base fluid having greater than about 5 wt. % of an inorganic salt with a viscoelastic surfactant gelling agent to form a plurality of micelles, the viscoelastic surfactant gelling agent comprising one or more of erucamidopropyl hydroxypropyl sulfobetaine, erucamidopropyl hydroxyethyl sulfobetaine, or erucamidopropyl hydroxymethyl sulfobetaine; and
contacting the plurality of micelles with a cationic polymer additive, which comprises polydiallyldialkylammonium salt, to form a viscoelastic surfactant treatment fluid having an improved rheological property at a temperature of greater than about 200° F. as compared to an otherwise identical reference viscoelastic surfactant treatment fluid that does not contain the cationic polymer additive,
wherein the cationic polymer is present in an amount of about 0.1 wt. % to about 10 wt. % based on a total weight of the viscoelastic surfactant treatment fluid; and
the viscoelastic gelling agent is present in an amount of about 1 volume % to about 20 volume %, based on the total volume of the aqueous base fluid wherein a viscosity of the viscoelastic surfactant treatment fluid changes less than 10% after exposing to an environment having a temperature of about 250° F. to about 350° F. for two hours when tested under the same conditions.
2. The method of claim 1 , wherein gelling the aqueous base fluid comprises mixing the aqueous base fluid with the viscoelastic surfactant gelling agent at a temperature of about 20° F. to about 350° F.
3. The method of claim 1 , wherein the improved rheological property is viscosity.
4. The method of claim 1 , wherein the cationic polymer additive by itself does not gel the aqueous based fluid by forming micelles.
5. The method of claim 1 , wherein the cationic polymer additive is polydiallyldimethylammonium chloride.
6. The method of claim 1 , wherein the aqueous base fluid is a brine comprising about 15 wt. % to about 50 wt. % of the inorganic salt based on the total weight of the viscoelastic surfactant treatment fluid.
7. The method of claim 1 , wherein the viscoelastic surfactant treatment fluid has a viscosity of about 50 to about 350 cP at 300° F. and 100 s −1 using Chandler 5550 HPHT viscometer in accordance with API RP 13M.
8. The method of claim 1 , wherein the viscoelastic surfactant treatment fluid has a viscosity of about 250 to about 350 cP at 300° F. and 100 s −1 using Chandler 5550 HPHT viscometer in accordance with API RP 13M.
9. The method of claim 1 , wherein the plurality of micelles have negative charges on a surface of the micelles.
10. The method of claim 1 , wherein:
the inorganic salt comprises calcium chloride and is present in an amount of about 15 wt. % to about 40 wt. % based on the total weight of the viscoelastic surfactant treatment fluid;
the viscoelastic surfactant gelling agent is present in an amount of about 5 volume % to about 10 volume % based on the total volume of the aqueous base fluid; and
the cationic polymer additive comprises polydiallyldialkylammonium salt and is present in an amount of about 0.1 wt. % to about 5 wt. %, based on the total weight of the viscoelastic surfactant treatment fluid.
11. The method of claim 10 , wherein the viscoelastic surfactant comprises erucamidopropyl hydroxypropyl sulfobetaine.
12. The method of claim 10 , wherein the cationic polymer additive is present in an amount of about 0.1 wt. % to about 3 wt. %, based on the total weight of the viscoelastic surfactant treatment fluid.
13. The method of claim 10 , wherein the inorganic salt comprises calcium chloride and is present in an amount of about 20 wt. % to about 40 wt. % based on the total weight of the viscoelastic surfactant treatment fluid.
14. The method of claim 1 , wherein:
the inorganic salt comprises calcium chloride and is present in an amount of about 20 wt. % to about 40 wt. % based on the total weight of the viscoelastic surfactant treatment fluid;
the viscoelastic surfactant gelling agent comprises erucamidopropyl hydroxypropyl sulfobetaine and is present in an amount of about 5 volume % to about 10 volume % based on the total volume of the aqueous base fluid; and
the cationic polymer additive comprises polydiallyldialkylammonium salt and is present in an amount of about 0.1 wt. % to about 3 wt. %, based on the total weight of the viscoelastic surfactant treatment fluid.