IP Library Granted Patent US 10,760,034
Granted Patent B2
US 10,760,034 · App. 15/879,933 · Granted Sep 1, 2020

Stable unit dose compositions with high water content

Inventors: Casey Elphege Camire (Shelton, CT); Patrick Shane Akeem Harewood (Hamden, CT); Cynthia L. Moser (Wilton, CT); Daniel Thomas Piorkowski (Fairfield, CT); David S. Stott, II (Madison, CT)
Assignee: Henkel IP & Holding GmbH
C11D1/831C11D1/83C11D3/046C11D3/2075C11D3/2079C11D3/2086C11D3/221C11D3/43C11D17/0026C11D17/043C11D17/045C11D1/146C11D1/22C11D1/29C11D1/72
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Quick Facts
Patent No.
US 10,760,034
App. No.
15/879,933
Granted
Sep 1, 2020
Kind
B2
Abstract

Stable unit dose compositions with high water content are provided. Such unit dose compositions include an aqueous composition having a water activity of from about 0.65 to about 0.95 and a water-soluble container formed from a water-soluble or water-dispersible film material. In one embodiment, the aqueous composition includes water in an amount of 25% to 70% by weight, a surfactant system, and a water binding agent. The surfactant system may include: (1) a linear alkylbenzene sulfonate (LAS) and/or an alcohol ethoxylsulfate (AES), (2) a non-ionic surfactant, and (3) a fatty acid. The unit dose compositions can prevent the enclosed liquid detergent composition with a high level of water content from dissolving or pre-maturely dispersing the water-soluble container.

Claims (42)

1. A unit dose product comprising:

(a) a water-soluble container formed from a water-soluble or water-dispersible film material;

(b) an aqueous composition comprising:

(i) water present in an amount of about 25% to about 70% by weight;

(ii) a surfactant system present in an amount of about 0.1% to about 70% by weight; and

(iii) high fructose corn syrup water binding agent present in an amount of about 0.5% to about 50% by weight;

wherein the aqueous composition is enclosed in the water-soluble container and has a water activity of from 0.65 to 0.95.

2. The unit dose product of claim 1 , wherein the water binding agent is present in an amount of from about 4% to about 40% by weight.

3. The unit dose product of claim 1 , wherein the water binding agent is present in an amount of from about 20% to about 30% by weight.

4. The unit dose product of claim 1 , wherein the aqueous composition comprises from about 25% to about 55% by weight of water.

5. The unit dose product of claim 1 , wherein the aqueous composition is substantially free of a salt.

6. The unit dose product of claim 1 , wherein the aqueous composition is substantially free of a hygroscopic chelant.

7. The unit dose product of claim 1 , wherein the aqueous composition is substantially free of a polymer that stabilizes the water-soluble container.

8. The unit dose product of claim 1 , wherein the aqueous composition further comprises a salt in an amount of about 0.5% to about 25% by weight.

9. The unit dose product of claim 1 , wherein the surfactant system comprises:

(1) an anionic surfactant, and

(2) a non-ionic surfactant.

10. The unit dose product of claim 9 , wherein the surfactant system further comprises a zwitterionic surfactant or an amphoteric surfactant.

11. The unit dose product of claim 9 , wherein the anionic surfactant is linear alkylbenzene sulfonic acid or a salt thereof, alkyl ethoxylated sulphate, alkyl propoxy sulphate, alkyl sulphate, or a mixture thereof.

12. The unit dose product of claim 9 , wherein the nonionic surfactant is alcohol ethoxylate, alcohol propoxylate, or a mixture thereof.

13. The unit dose product of claim 1 , wherein the surfactant system comprises:

(1) a linear alkylbenzene sulfonate (LAS) and/or an alcohol ethoxylsulfate (AES),

(2) an alcohol ethoxylate (AE), and

(3) a fatty acid.

14. The unit dose product of claim 13 , wherein

the LAS is present in an amount of about 10% to about 20% by weight;

the AES is present in an amount of about 20% to about 40% by weight;

the AE is present in an amount of about 20% to about 50% by weight; and

the fatty acid is present in an amount of about 1% to about 15% by weight.

15. The unit dose product of claim 13 , wherein the weight ratio of LAS:AES:AE is about 1:2:3.

16. The unit dose composition of claim 1 , wherein the aqueous composition further comprises a fragrance composition comprising a neat oil, an encapsulated fragrance, an oil-in-water emulsion, or a combination thereof; wherein the fragrance composition is present in an amount from about 0.1% to about 15% by weight.

17. A unit dose product comprising:

(a) a water-soluble container formed from a water-soluble or water-dispersible film material;

(b) an aqueous composition comprising:

(i) water present in an amount of about 25% to about 40% by weight;

(ii) a surfactant system present in an amount of about 8% to about 60% by weight;

(iii) a fatty acid present in an amount of about 2% to about 4% by weight; and

(iv) high fructose corn syrup water binding agent present in an amount of about 0.5% to about 50% by weight;

wherein the aqueous composition is enclosed in the water-soluble container.

18. The unit dose product of claim 17 ,

wherein the aqueous composition has a water activity of from 0.65 to 0.95; and

wherein the aqueous composition is substantially free of a salt.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 9, 2022
From: HENKEL IP & HOLDING GMBH
To: HENKEL AG & CO. KGAA
Reel/Frame 059357/0267 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 27, 2018
From: CAMIRE, CASEY ELPHEGE; AKEEM, PATRICK SHANE; MOSER, CYNTHIA L.; PIORKOWSKI, DANIEL THOMAS; STOTT II, DAVID S.
To: HENKEL IP & HOLDING GMBH
Reel/Frame 045046/0746 →