System and method for adjusting carbon dioxide concentration in indoor atmospheres
An electrochemical device suited to modifying a carbon dioxide concentration in an interior space includes a cathode chamber with an inlet which receives a feed gas containing carbon dioxide. A reduction catalyst layer in the cathode chamber reduces carbon dioxide in the gas to form an ionic carrier species. An anode chamber with an outlet outputs a gas comprising carbon dioxide. A solid electrolyte membrane spaces the anode chamber from the cathode chamber and transports the ionic carrier species between the cathode chamber and the anode chamber. The membrane includes an ionic liquid. An oxidation catalyst layer in the anode chamber oxidizes the ionic carrier species to form carbon dioxide. A voltage source provides a voltage difference across the membrane.
1. An electrochemical device comprising:
a cathode chamber including an inlet which receives a feed gas comprising carbon dioxide;
a reduction catalyst layer in the cathode chamber which electrochemically reduces carbon dioxide in the gas to form an ionic carrier species;
an anode chamber;
an electrolyte membrane which spaces the anode chamber from the cathode chamber, the membrane transporting the ionic carrier species between the cathode chamber and the anode chamber;
an oxidation catalyst layer in the anode chamber which electrochemically oxidizes the ionic carrier species to form carbon dioxide; and
an energy source, electrically connected with at least one of the reduction catalyst layer and the oxidation catalyst layer, which provides energy for the reduction and oxidation;
wherein the electrochemical device changes the concentration of CO 2 in the feed gas; and
wherein the electrolyte membrane comprises a crosslinked polymerized ionic liquid.
2. The electrochemical device of claim 1 , wherein the reduction catalyst layer comprises indium, tin, lead, or glassy carbon.
3. The electrochemical device of claim 1 , wherein the crosslinked polymerized ionic liquid is a polyelectrolyte derived by polymerization of a monomer with a polymerizable group.
4. The electrochemical device of claim 3 , wherein the polymerizable group includes an alkenyl functional group.
5. The electrochemical device of claim 1 , wherein the crosslinked polymerized ionic liquid of the electrolyte membrane includes organic cations selected from nitrogen-containing cations, phosphorus-containing cations, sulfur-containing cations, and combinations thereof.
6. The electrochemical device of claim 5 , wherein the organic cations are selected from the group consisting of:
1,3-dimethylimidazolium, 1,3-diethylimidazolium, 1-ethyl-3-methylimidazolium, 1,2-dimethyl-3-propylimidazolium, 1,3-dipropylimidazolium, 1-ethyl-3-propylimidazolium, 1,2-dimethyl-3-N-butylimidazolium, 1-ethyl-3-butylimidazolium, 1-methyl-3-octylimidazolium, 1-ethyl-3-octylimidazolium, 1-n-propyl-3-methylimidazolium, 1-n-propyl-3-ethylimidazolium, 1-butyl-3-methylimidazolium, 1-butyl-3-ethylimidazolium, 1-butyl-2,3-dimethylimidazolium, 1-butyl-2,3-diethylimidazolium, 1-hexyl-3-methylimidazolium, 1-hexyl-3-ethylimidazolium, 1-octyl-3-methylimidazolium, and 1-octyl-3-ethylimidazolium, 1-vinylimidazolium, 1-propynylimidazolium, 1-vinyl-3-ethenylimidazolium, 1-ethenyl-3-propynylimidazolium, 1,3-dipropynylimidazolium, 2-methyl-1-vinylimidazolium;
1-(2-methoxyethyl)-1-methylpyridinium, N-(3-hydroxypropyl)pyridinium, N-hexylpyridinium, and 1-ethenyl-3-propenylpyridinium, 2-vinylpyridinium, and 4-vinylpyridinium;
1-butyl-1-methylpyrrolidinium, N-butyl-N-methylpyrrolidinium, and 1-hexyl-1-methylpyrrolidinium, and 1-ethenyl-3-propenylpyrrolidinium;
trimethylbutylammonium, N-ethyl-N,N-dimethyl-2-methoxyethylammonium, tetrabutylammonium, n-hexyltriethylammonium, trimethyl-n-hexylammonium, and triethylbutylammonium;
trihexyl (tetradecyl)phosphonium and tris(n-hexyl) tetradecylphosphonium;
mixtures thereof; and
polymers thereof.
7. The electrochemical device of claim 5 , wherein the crosslinked polymerized ionic liquid of the electrolyte membrane includes nitrogen-containing organic cations selected from the group consisting of imidazolium, pyridinium, piperidinium, and pyrrolidinium-containing cations, organo-ammonium cations, polymers thereof, and mixtures thereof.
8. The electrochemical device of claim 1 , wherein the crosslinked polymerized ionic liquid of the electrolyte membrane includes nitrogen-containing organic cations of the general form:
where R 1 , R 2 , R 3 and R 4 are independently selected from H, C 1 -C 12 alkyl groups, C 1 -C 12 alkenyl groups, C 1 -C 12 alkoxy groups, C 1 -C 12 hydroxyalkyl groups, C 1 - C 12 hydroxyalkenyl groups, and combinations thereof, and wherein at least one of R 1 , R 2 , R 3 and R 4 is not H;
X is C or N; and
n is 0 or 1.
9. The electrochemical device of claim 1 , wherein the crosslinked polymerized ionic liquid includes anions selected from the group consisting of oxalate, formate, hydroxide, sulfonates, acetates, phosphates, carboxylates, borates, imide anions, amide anions, halides, sulfates, and mixtures thereof.
10. The electrochemical device of claim 1 , wherein the crosslinked polymerized ionic liquid is selected from the group consisting of:
1-(3-methoxypropyl)-1-methylpiperidinium bis (trifluoromethylsulfonyl) imide, 1-(2-methoxyethyl)-1-methylpiperidinium tris-(pentafluoroethyl) trifluorophosphate,
trihexyl (tetradecyl)phosphonium tris (pentafluoroethyl)trifluorophosphate, trihexyl (tetradecyl)phosphonium chloride, tris(n-hexyl) tetradecylphosphonium trifluorotris (pentafluoroethyl)phosphate, tris(n-hexyl)tetradecylphosphonium bis (trifluoromethylsulfonyl)imide, trihexyl(tetradecyl)phosphonium dicyanamide, N-allylphosphonium formate,
1-(2-methoxyethyl)-1-methylpyridinium tris (pentafluoroethyl)trifluorophosphate, N-(3-hydroxypropyl)pyridinium bis (trifluoromethylsulfonyl)imide, N-hexylpyridinium bis(trifluoromethylsulfonyl) imide,
1-butyl-1-methylpyrrolidinium trifluoromethanesulfonate, N-butyl-N-methylpyrrolidinium bis (trifluoromethanesulfonyl)imide, 1-hexyl-1-methyl-pyrrolidinium bis (trifluoromethylsulfonyl)imide, 1-butyl-1-methylpyrrolidinium trifluoroacetate,
1-ethyl-3-methylimidazolium tetracyanoborate, 1-methyl-3-octylimidazolium bis(trifluoromethylsulfonyl)imide, 1,2-dimethyl-3-N-butylimidazolium hexafluorophosphate, 1,2-dimethyl-3-propylimidazolium bis (trifluoromethylsulfonyl)imide, 1,3-dimethylimidazolium diphosphate, 1,3-dimethylimidazolium trifluoromethanesulfonate, 1-ethyl-3-methylimidazolium bis (trifluoromethylsulfonyl)imide, 1-ethyl-3-methylimidazolium ethylsulfate, 1-ethyl-3-methylimidazolium tetrafluoroborate, 1-n-propyl-3-methylimidazolium tetrafluoroborate, 1-butyl-3-methylimidazolium tetracyanoborate, 1-butyl-2,3-dimethylimidazolium trifluoromethanesulfonate, 1-butyl-2,3-methylimidazolium bis (trifluoromethanesulfonyl)imide, 1-butyl-3-methylimidazolium bis (trifluoromethylsulfonyl)imide, 1-butyl-3-methylimidazolium hexafluorophosphate, 1-butyl-3-methylimidazolium tetrafluoroborate, 1-n-butyl-3-methylimidazolium tetrafluoroborate, 1-hexyl-3-methylimidazolium chloride, 1-hexyl-3-methylimidazolium trifluorotris (pentafluoroethyl)phosphate, 1-hexyl-3-methylimidazolium bis (trifluoromethylsulfonyl)imide, 1-hexyl-3-methylimidazolium tetracyanoborate, 1-octyl-3-methylimidazolium chloride, N-vinyl imidazolium formate, 1-ethyl, 3-methyl imidazolium hydroxide,
trimethylbutylammonium bis (trifluoromethylsulfonyl)imide, N-ethyl-N,N-dimethyl- 2 -methoxyethylammonium bis(trifluoromethylsulfonyl)imide, n-hexyltriethylammonium bis (trifluoromethylsulfonyl)imide, trimethyl-n-hexylammonium bis (trifluoromethylsulfonyl)imide, triethylbutylammonium bis (trifluoromethylsulfonyl)imide, tetrabutylammonium hexafluorophosphate,
polymerizable unsaturated equivalents thereof,
mixtures thereof, and
polymers thereof.
11. The electrochemical device of claim 1 , wherein the membrane is substantially impermeable to at least one gas, the at least one gas including oxygen.
12. The electrochemical device of claim 1 , further comprising at least one of:
a gas diffusion layer in the cathode chamber adjacent the reduction catalyst layer;
a gas diffusion layer in the anode chamber adjacent the oxidation catalyst layer; and
a carbon dioxide capture layer in the anode chamber, the carbon dioxide capture layer being spaced from the membrane by the oxidation catalyst layer.
13. The electrochemical device of claim 1 , wherein the cathode chamber comprises an outlet which outputs the feed gas with a lower concentration of carbon dioxide than the feed gas received by the cathode chamber inlet.
14. The electrochemical device of claim 1 , further comprising at least one of:
a controller which controls a voltage across the membrane; and
a carbon dioxide sensor which senses a carbon dioxide concentration in the electrochemical device.
15. An electrolytic carbon dioxide removal apparatus comprising the electrochemical device of claim 1 and conduits which connect the cathode chamber inlet and a cathode chamber outlet with an associated interior space, the electrochemical device reducing a partial pressure of carbon dioxide in the interior space.
16. An electrolytic carbon dioxide pumping apparatus comprising the electrochemical device of claim 1 and conduits which connect an anode chamber inlet and the anode chamber outlet with an associated interior space, the electrochemical device increasing a partial pressure of carbon dioxide in the interior space.
17. An electrochemical device comprising:
a cathode chamber including an inlet which receives a feed gas comprising carbon dioxide;
a reduction catalyst layer in the cathode chamber which electrochemically reduces carbon dioxide in the gas to form an ionic carrier species;
a gas diffusion layer in the cathode chamber adjacent the reduction catalyst layer;
an anode chamber;
an electrolyte membrane which spaces the anode chamber from the cathode chamber, the membrane transporting the ionic carrier species between the cathode chamber and the anode chamber;
an oxidation catalyst layer in the anode chamber which electrochemically oxidizes the ionic carrier species to form carbon dioxide;
a gas diffusion layer in the anode chamber adjacent the oxidation catalyst layer;
a carbon dioxide capture layer in the anode chamber, the carbon dioxide capture layer being spaced from the membrane by the oxidation catalyst layer; and
an energy source, electrically connected with at least one of the reduction catalyst layer and the oxidation catalyst layer, which provides energy for the reduction and oxidation;
wherein the electrochemical device changes the concentration of CO 2 in the feed gas.
18. A method for modifying carbon dioxide concentration in an interior space, comprising:
providing the electrochemical device of claim 1 ;
electrochemically reducing carbon dioxide to an ionic carrier species in the cathode chamber;
ionically transporting the ionic carrier species through the membrane;
electrochemically oxidizing the ionic carrier species to carbon dioxide in the anode chamber; and
supplying gas from one of the cathode chamber and the anode chamber to the interior space to modify the carbon dioxide concentration in an interior space;
wherein the ionic carrier species is selected from the group consisting of peroxydicarbonate anions, formate anions, oxalate anions, and mixtures thereof.
19. The method of claim 18 , wherein a partial pressure of carbon dioxide in a product gas is within the range 0.001 to 0.01 bar, and wherein the method is used for carbon dioxide removal.