Separator for non-aqueous secondary battery and non-aqueous secondary battery
Provided is a separator for a non-aqueous secondary battery, including: a porous substrate, and a heat resistant porous layer that is provided on one side or both sides of the porous substrate, that is an aggregate of resin particles and an inorganic filler, and that satisfies the following expression (1). In expression (1), Vf is a volume proportion (% by volume) of the inorganic filler in the heat resistant porous layer, and CPVC is a critical pigment volume concentration (% by volume) of the inorganic filler. Also provided is a separator for a non-aqueous secondary battery, including: a porous substrate, a heat resistant porous layer that is provided on one side or both sides of the porous substrate, that includes a resin and an filler, and that satisfies the following expression (2), and an adhesive porous layer that is provided on both sides of a stacked body of the porous substrate and the heat resistant porous layer, and that includes an adhesive resin. In expression (2), Vf is a volume proportion (% by volume) of the filler in the heat resistant porous layer, and CPVC is a critical pigment volume concentration (% by volume) of the filler. 0.65≤ Vf /CPVC≤0.99 expression (1) 0.40≤ Vf /CPVC≤0.99 expression (2)
1. A separator for a non-aqueous secondary battery, comprising:
a porous substrate,
a heat resistant porous layer that is provided on both sides of the porous substrate, that includes a resin and a filler, and that satisfies the following expression (2), and
an adhesive porous layer that is provided on both sides of a stacked body of the porous substrate and the heat resistant porous layer, and that includes an adhesive resin:
0.40 ≤Vf /CPVC≤0.99 expression (2)
wherein, in expression (2), Vf is a volume proportion (% by volume) of the filler in the heat resistant porous layer, and CPVC is a critical pigment volume concentration (% by volume) of the filler.
2. The separator for a non-aqueous secondary battery according to claim 1 , wherein an average of a porosity of the heat resistant porous layer and a porosity of the adhesive porous layer is from 30% to 70%.
3. The separator for a non-aqueous secondary battery according to claim 1 , wherein, in the heat resistant porous layer, a proportion of the filler with respect to a total amount of the resin and the filler is from 50% by mass to 98% by mass.
4. The separator for a non-aqueous secondary battery according to claim 1 , wherein the critical pigment volume concentration of the filler is from 20% by volume to 80% by volume.
5. The separator for a non-aqueous secondary battery according to claim 1 , wherein a peel strength between the heat resistant porous layer and the adhesive porous layer is 0.05 N/cm or more.
6. The separator for a non-aqueous secondary battery according to claim 1 , wherein:
the resin in the heat resistant porous layer includes resin particles containing a polyvinylidene fluoride resin,
the filler is an inorganic filler, and
the heat resistant porous layer is an aggregate of the resin particles and the inorganic filler.
7. The separator for a non-aqueous secondary battery according to claim 1 , wherein the filler is magnesium hydroxide or magnesium oxide.
8. The separator for a non-aqueous secondary battery according to claim 1 , wherein the heat resistant porous layer further comprises a thickener.
9. A non-aqueous secondary battery comprising:
a positive electrode,
a negative electrode, and
the separator for a non-aqueous secondary battery according to claim 1 , which is disposed between the positive electrode and the negative electrode,
wherein, in the non-aqueous secondary battery, an electromotive force is obtained by lithium doping/dedoping.
10. The separator for a non-aqueous secondary battery according to claim 1 , wherein a Gurley value (JIS P8117 (2009)) of the separator is from 100 sec/100 cc to 500 sec/100 cc.
11. A separator for a non-aqueous secondary battery, comprising:
a porous substrate,
a heat resistant porous layer that is provided on one side or both sides of the porous substrate, that includes a resin and a filler, and that satisfies the following expression (2), and
an adhesive porous layer that is provided on both sides of a stacked body of the porous substrate and the heat resistant porous layer(s), and that includes an adhesive resin containing at least a polyvinylidene fluoride resin:
0.40 ≤Vf /CPVC≤0.99 expression (2)
wherein, in expression (2), Vf is a volume proportion (% by volume) of the filler in the heat resistant porous layer, and CPVC is a critical pigment volume concentration (% by volume) of the filler.
12. The separator for a non-aqueous secondary battery according to claim 11 , wherein an average of a porosity of the heat resistant porous layer and a porosity of the adhesive porous layer is from 30% to 70%.
13. The separator for a non-aqueous secondary battery according to claim 11 , wherein, in the heat resistant porous layer, a proportion of the filler with respect to a total amount of the resin and the filler is from 50% by mass to 98% by mass.
14. The separator for a non-aqueous secondary battery according to claim 11 , wherein the critical pigment volume concentration of the filler is from 20% by volume to 80% by volume.
15. The separator for a non-aqueous secondary battery according to claim 11 , wherein a peel strength between the heat resistant porous layer and the adhesive porous layer is 0.05 N/cm or more.
16. The separator for a non-aqueous secondary battery according to claim 11 , wherein:
the resin in the heat resistant porous layer includes resin particles containing a polyvinylidene fluoride resin,
the filler is an inorganic filler, and
the heat resistant porous layer is an aggregate of the resin particles and the inorganic filler.
17. The separator for a non-aqueous secondary battery according to claim 11 , wherein the filler is magnesium hydroxide or magnesium oxide.
18. The separator for a non-aqueous secondary battery according to claim 11 , wherein the heat resistant porous layer further comprises a thickener.
19. The separator for a non-aqueous secondary battery according to claim 11 , wherein a Gurley value (JIS P8117 (2009)) of the separator is from 100 sec/100 cc to 500 sec/100 cc.
20. A non-aqueous secondary battery comprising:
a positive electrode,
a negative electrode, and
the separator for a non-aqueous secondary battery according to claim 10 , which is disposed between the positive electrode and the negative electrode,
wherein, in the non-aqueous secondary battery, an electromotive force is obtained by lithium doping/dedoping.