Lithium ion battery and electrolyte thereof
The present invention provides a lithium ion battery and an electrolyte thereof. The electrolyte for the lithium ion battery includes a non-aqueous organic solvent, a lithium salt and additives, wherein the additives include additive A cyclophosphazene compound, additive B lithium fluorophosphate compound, and additive C selected from at least one of silane phosphate compound, silane phosphite compound and silane borate compound. Compared with conventional technologies, the nickel-rich positive electrode lithium ion battery using the electrolyte of the present invention has a desirable cyclic capacity retention rate, a desirable storage capacity retention rate and a low gas production at high temperature, and has a low DC internal resistance at low temperature, which can remarkably improve the thermal stability of lithium ion battery.
1. A lithium ion battery, comprising: a positive electrode plate, a negative electrode plate, a separator interposed between the positive electrode plate and the negative electrode plate, and an electrolyte, the positive electrode plate comprising a positive electrode current collector and a positive electrode active material formed thereon, the negative electrode plate comprising a negative electrode current collector and a negative electrode active material formed thereon, wherein the electrolyte comprises a non-aqueous organic solvent, a lithium salt, and additives, the additives comprise additive A cyclophosphazene compound, additive B lithium fluorophosphate compound, and additive C selected from at least one of silane phosphate compound, silane phosphite compound and silane borate compound, wherein the positive electrode active material is LiNi 1-x-y Co x M y O 2 , M is Mn or Al, 0≤x≤0.5, 0≤y≤0.5, 0≤x+y≤0.5, and a weight content of the additive A in the electrolyte is no less than a weight content of the additive B in the electrolyte, and no less than a weight content of the additive C in the electrolyte, and wherein the additive A is selected from at least one of the compounds represented by formula I;
wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 are each independently selected from F, Cl, Br, I, an alkyl group having 1 to 20 carbon atoms, a halogenated alkyl group having 1 to 20 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, a halogenated alkenyl group having 2 to 20 carbon atoms, an aryl group having 6 to 26 carbon atoms, a halogenated aryl group having 6 to 26 carbon atoms, a halogenated alkoxy group having 1 to 20 carbon atoms, an aryloxy group having 6 to 26 carbon atoms, a halogenated aryloxy group having 6 to 26 carbon atoms, at least one of R 1 , R 3 and R 5 represents an alkyl group having 1 to 20 carbon atoms, a halogenated alkyl group having 1 to 20 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, a halogenated alkenyl group having 2 to 20 carbon atoms, an aryl group having 6 to 26 carbon atoms, a halogenated aryl group having 6 to 26 carbon atoms, a halogenated alkoxy group having 1 to 20 carbon atoms, an aryloxy group having 6 to 26 carbon atoms, a halogenated aryloxy group having 6 to 26 carbon atoms, at least two of R 2 , R 4 , R 6 are selected from F, Cl, Br, I.
2. The lithium ion battery according to claim 1 , wherein the weight content of the additive A in the electrolyte is 0.1 wt % to 10 wt %.
3. The lithium ion battery according to claim 1 , wherein the weight content of the additive B in the electrolyte is 0.1 wt % to 3 wt %.
4. The lithium ion battery according to claim 1 , wherein the additive C is selected from at least one of the compounds represented by formulas II, III and IV;
wherein R 7 , R 8 , R 9 , R 10 , R 11 , R 12 , R 13 , R 14 , R 15 are each independently selected from an alkyl group or a halogenated alkyl having 1 to 6 carbon atoms.
5. The lithium ion battery according to claim 4 , wherein the weight content of the additive C in the electrolyte is 0.1 wt % to 2 wt %.
6. The lithium ion battery according to claim 1 , wherein the organic solvent is selected from at least two of the group consisting of ethylene carbonate, propylene carbonate, butylene carbonate, fluoroethylene carbonate, methyl ethyl carbonate, dimethyl carbonate, diethyl carbonate, dipropyl carbonate, methyl propyl carbonate, ethyl propyl carbonate, 1,4-butyrolactone, γ-butyrolactone, methyl propionate, methyl butyrate, ethyl acetate, ethyl propionate, and ethyl butyrate.
7. The lithium ion battery according to claim 1 , wherein the lithium salt is selected from at least one of LiPF 6 , LiClO 4 , LiAsF 6 , LiTFSI, LiFSI, LiDFOB, LiDFOP, LiBOB, and a mole concentration of the lithium salt is 0.5M to 1.5M.
8. The lithium ion battery according to claim 1 , wherein the electrolyte further comprises at least one of vinylene carbonate (VC), vinyl ethylene carbonate (VEC), fluoroethylene carbonate (FEC), succinonitrile (SN), adiponitrile (ADN), ethylene sulfate (DTD), 1,3-propane sultone (1,3-PS), 1,3-propene sultone (PST).
9. The lithium ion battery according to claim 1 , wherein the lithium salt is selected from at least one of LiPF 6 , LiClO 4 , LiAsF 6 , LiTFSI, LiFSI, LiDFOB, LiDFOP, LiBOB, and a mole concentration of the lithium salt is 0.8M to 1.2M.