Relief image-forming method and assembly
A relief image is prepared by: A) imaging an imageable material to form a mask element; B) exposing a relief-forming precursor through the mask element; C) removing the mask element; and D) developing the imaged relief-forming precursor. The imageable material has, in order: (a) a transparent polymeric carrier sheet; (b) a non-ablatable light-to-heat converting having an average dry thickness of 1-5 μm and comprising: (i) an infrared radiation absorbing material at 0.1-5 weight %; (ii) a thermally crosslinked organic polymeric binder material; and (iii) non-thermally ablatable particles having an average particle size of 0.1-20 μm in an amount of 0.2-10 weight %; and (c) a non-silver halide thermally-ablatable imaging layer (IL) disposed on the LTHC layer, the IL comprising a second infrared radiation absorbing material and a UV-light absorbing material dispersed within one or more thermally-ablatable polymeric binder materials. The imageable material can be included in a relief image-forming assembly.
1. A method for making a relief image in a relief image element, the method comprising, in order:
A) imaging an imageable material with infrared radiation to form a mask element;
B) exposing a relief-forming precursor comprising a UV-sensitive layer with curing UV radiation through the mask element, to form an imaged relief-forming precursor with exposed hardened regions and non-exposed regions in the UV-sensitive layer,
C) removing the mask element; and
D) developing the imaged relief-forming precursor by removing the non-exposed regions in the UV-sensitive layer, thereby forming a relief image element having a relief image,
wherein the imageable material consisting essentially of, in order:
(a) a transparent polymeric carrier sheet;
(b) a non-ablatable light-to-heat converting (LTHC) layer disposed directly on the transparent polymeric carrier sheet, the LTHC layer having an average dry thickness of at least 1 um and up to and including 5 μm, and comprising: (i) a first infrared radiation absorbing material in an amount of at least 0.1 weight % and up to and including 5 weight %; (ii) a thermally crosslinked organic polymeric binder material; and (iii) non-thermally ablatable particles having an average particle size of at least 0.1 μm and up to and including 20 μm and that are present in an amount of at least 0.2 weight % and up to and including 10 weight %, all weight percentages being based on the total dry weight of the LTHC layer;
all weight percentages being based on the total dry weight of the LTHC layer;
(c) a non-silver halide thermally-ablatable imaging layer (IL) disposed directly on the LTHC layer, the IL comprising a second infrared radiation absorbing material and a UV-light absorbing material dispersed within one or more thermally-ablatable polymeric binder materials; and
the imageable material optionally further comprising (d) a transparent polymeric overcoat layer disposed directly on the IL.
2. The method of claim 1 , wherein in B), the mask element is in complete optical contact with the relief-forming precursor.
3. The method of claim 1 , wherein B) further includes vacuum drawdown of the mask element onto the relief-forming precursor.
4. The method of claim 1 , wherein the one or more thermally-ablatable polymeric binder materials in the IL are nitrocellulose, a poly(cyanoacrylate), or a combination thereof.
5. The method of claim 1 , wherein the second infrared radiation absorbing material is present in the IL in an amount of at least 3 weight % and up to and including 20 weight %, based on the total dry weight of the IL.
6. The method of claim 1 , wherein the UV-light absorbing material is present in the IL in an amount of at least 10 weight % and up to and including 40 weight %, based on the total dry weight of the IL.
7. The method of claim 1 , wherein the transparent polymeric carrier sheet is composed of one or more polyesters, polyethylene-polypropylene copolymers, polybutadienes, polycarbonates, polyacrylates, vinyl chloride polymers, hydrolyzed or non-hydrolyzed cellulose acetates, or a combination of two or more of these materials.
8. The method of claim 1 , wherein the non-thermally ablatable particles in the LTHC layer are composed of particles of silica, titanium dioxide, zinc oxide, or a combination of two or more types of such particles.
9. The method of claim 1 , wherein the non-thermally ablatable particles are present in the LTHC layer in an amount of at least 1 weight % and up to and including 7 weight %, based on the total dry weight of the LTHC layer.
10. The method of claim 1 , wherein the thermally crosslinked organic polymeric binder material in the LTHC layer is composed of crosslinked nitrocellulose, a crosslinked polyester, or a combination of two or more of such crosslinked organic polymeric materials.
11. The method of claim 1 , wherein the first and second infrared radiation absorbing materials are the same materials.
12. The method of claim 1 , wherein the LTHC layer has an average dry thickness of at least 1 μm and up to and including 3 μm.
13. The method of claim 1 , wherein the IL has an average dry thickness of at least 0.5 μm and up to and including 5 μm.
14. The method of claim 1 , wherein developing is carried out using a processing solution comprising a) a fatty acid composition consisting of one or more saturated or unsaturated fatty acids or alkali metal salts thereof, each saturated or unsaturated fatty acid or alkali metal salts thereof independently having 12 to 20 carbon atoms, the fatty acid composition being present in an amount of at least 0.25 weight % and up to and including 2.0 weight %, and at least 85 weight % of the fatty acid composition is composed of one or more C18 mono- or poly-unsaturated fatty acids or alkali metal salts thereof; b) an aminopolycarboxylic acid or alkali metal salt thereof in an amount of at least 0.05 weight % and up to and including 0.30 weight %; c) a buffer compound in an amount of at least 05 weight % and up to and including 0.60 weight %; and d) water.
15. The method of claim 1 , comprising laminating the mask element to the relief-forming precursor prior to B).
16. The method of claim 1 , wherein the relief-forming precursor further comprises an anti-tack layer disposed on the UV-sensitive layer.
17. A relief image-forming assembly, consisting essentially of:
a mask element in complete optical contact with a relief-forming precursor comprising a UV-sensitive layer,
the mask element having a mask image, the mask element consisting essentially of, in order:
(a) a transparent polymeric carrier sheet;
(b) a non-ablatable light-to-heat converting (LTHC) layer disposed directly on the transparent polymeric carrier sheet, the LTHC layer having an average dry thickness of at least 1 μm and up to and including 5 nm, and comprising: (i) a first infrared radiation absorbing material in an amount of at least 0.1 weight % and up to and including 5 weight percent; (ii) a thermally crosslinked organic polymeric binder material; and (iii) non-thermally ablatable particles having an average particle size of at least 0.1 nm and up to and including 20 nm and that are present in an amount of at least 0.2 weight % and up to and including 10 weight %, all weight percentages being based on the total dry weight of the LTHC layer;
(c) a non-silver halide thermally-ablatable imaging layer (IL) disposed directly on the LTHC layer, a non-ablated portion of the IL comprising a second infrared radiation absorbing material and a UV-light absorbing material dispersed within one or more thermally-ablatable polymeric binder materials, wherein at least a portion of the IL layer is an ablated portion and at least a portion of the IL layer is the non-ablated portion; and
the imageable material optionally further comprising (d) a transparent polymeric overcoat layer disposed directly on the IL.
18. The assembly of claim 17 , wherein the mask element and relief-forming precursor are held in complete optical contact with a laminator.
19. The assembly of claim 18 , wherein the mask element and relief-forming precursor are held in complete optical contact with a laminator that provides a balanced, non-distorting, optimized laminating force.
20. The assembly of claim 17 , wherein the mask element and relief-forming precursor are held in complete optical contact using vacuum drawdown.
21. The method of claim 1 , wherein the non-thermally ablatable particles are not thermally ablated by the imaging of step A).
22. The method of claim 1 , wherein the non-thermally ablatable particles are not ablated by imaging with an infrared imaging wavelength and imaging intensity.