COATING COMPOSITION INCLUDING ALDYL OXIMES
A coating composition including at least one solvent, at least one resin, at least one drier, and an anti-skinning agent is provided, an anti-skinning composition, wherein the anti-skinning composition comprises at least 92 wt. %, or more particularly at least 98 wt. %, of an alkyl oxime having five carbon atoms selected from 2-pentanone oxime and 3-methyl-2-butanone oxime. In some embodiments, the high-purity 2-pentanone oxime includes less than 0.5 wt. % methyl isobutyl ketoxime. In some embodiments, the composition includes less than 0.006 wt. % methyl isobutyl ketoxime. A method for the preparation of a purified 2-pentanone stream suitable for oximation to a high-purity 2-pentanone oxime is also provided.
1 . A coating composition comprising:
at least one solvent;
at least one resin;
at least one drier; and
an anti-skinning composition capable of preventing oxidative crosslinking of the resin to form a skin, the anti-skinning composition comprising at least 92 wt. % of an alkyl oxime based on the total weight of the anti-skinning composition, wherein the alkyl oxime is selected from 2-pentanone oxime and 3-methyl-2-butanone oxime.
2 . The coating composition of claim 1 , wherein the alkyl oxime comprises 2-pentanone oxime.
3 . The coating composition of claim 2 , wherein the anti-skinning composition comprises at least 98 wt. % 2-pentanone oxime, based on the total weight of the anti-skinning composition.
4 . The coating composition of claim 2 , wherein the wherein the anti-skinning composition comprises less than 0.5 wt. % methyl isobutyl ketoxime, based on the total weight of the anti-skinning composition.
5 . The coating composition of claim 2 , wherein the wherein the anti-skinning composition comprises less than 0.3 wt. % methyl isobutyl ketoxime, based on the total weight of the anti-skinning composition.
6 . The coating composition of claim 2 , wherein the coating composition comprises less than 0.06 wt. % methyl isobutyl ketoxime, based on the total weight of the coating composition.
7 . The coating composition of claim 2 , wherein the at least one resin comprises one or more alkyd resins.
8 . The coating composition of claim 2 , wherein the at least one drier comprises at least one transition metal salt.
9 . The coating composition of claim 1 , wherein the alkyl oxime comprises 3-methyl-2-butanone oxime.
10 . A coating composition comprising:
at least one solvent;
at least one resin;
at least one drier; and
an anti-skinning composition capable of preventing oxidative crosslinking of the resin to form a skin, wherein the anti-skinning comprises 2-pentanone oxime, the anti-skinning composition comprising less than 0.5 wt. % methyl isobutyl ketoxime based on the total weight of the anti-skinning composition.
11 . The coating composition of claim 10 , wherein the anti-skinning composition further comprises methyl ethyl ketoxime, wherein the ratio of 2-pentanone oxime to methyl ethyl ketoxime is from 60:40 to 80:20.
12 . The coating composition of claim 10 , wherein the anti-skinning composition comprises at least 92 wt. % 2-pentanone oxime, based on the total weight of the anti-skinning composition.
13 . The coating composition of claim 10 , wherein the anti-skinning composition comprises at least 98 wt. % 2-pentanone oxime, based on the total weight of the anti-skinning composition.
14 . A method for preparation of a purified 2-pentanone product, the method comprising:
conveying an input stream including 2-pentanone to a distillation apparatus, the input stream further including methyl isobutyl ketone; and
distilling the input stream in the distillation apparatus to produce an overheads stream including less methyl isobutyl ketone than the input stream and a bottoms stream including more methyl isobutyl ketone than the input stream.
15 . The method of claim 14 , wherein the overheads stream comprises at least 98 wt. % 2-pentanone.
16 . The method of claim 14 , wherein the distillation apparatus includes a first distillation column and a second distillation column, wherein the first distillation column includes an overheads stream divided between a first reflux stream returned to the first distillation column and a takeoff stream provided as a feed stream to the second distillation column.
17 . The method of claim 16 , wherein a first reflux ratio is defined as a ratio of a flow rate of the first reflux stream to the takeoff stream, and wherein the first reflux ratio is from 1:2 to 5:1.
18 . The method of claim 16 , wherein the second distillation column includes an overheads stream divided between a second reflux stream returned to the second distillation column and a recycle stream provided as a second input stream to the first distillation column.
19 . The method of claim 18 , wherein a second reflux ratio is defined as a ratio of a flow rate of the second reflux stream to the recycle stream, and wherein the second reflux ratio is from 2:1 to 20:1.
20 . The method of claim 19 , wherein a first reflux ratio is defined as a ratio of a flow rate of the first reflux stream to the takeoff stream, and wherein the second ratio is at least 2 times greater than the first reflux ratio.