IP Library Granted Patent US 11,913,099
Granted Patent B2
US 11,913,099 · App. 15/903,288 · Granted Feb 27, 2024

Press hardened steel with extremely high strength and method for production

Inventor: Erik James Pavlina (Lebanon, OH)
Assignee: Cleveland-Cliffs Steel Properties Inc.
C22C38/38B32B15/012B32B15/013C21D1/673C22C38/02C22C38/04C22C38/12C22C38/22C22C38/24C22C38/26C22C38/32C23C2/02C23C2/024C23C2/0224C23C2/06C23C2/12C23C2/28C21D9/46
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Quick Facts
Patent No.
US 11,913,099
App. No.
15/903,288
Granted
Feb 27, 2024
Kind
B2
Abstract

Press hardened steels exhibit increased strength in the press hardened steel parts without a corresponding decrease in elongation. Substitutional elements are included in the steel composition to increase the strength of martensite through a combination of substitutional solute strengthening and a reduction in softening that results from autotempering. Softening as a result of autotempering is minimized by suppression of the martensite start (Ms) temperature through the alloying. As a result of the increased hardenability in the proposed compositions that results from various additions of manganese, chromium, molybdenum, and niobium, the steel compositions permit a boron-free press hardening steel.

Claims (13)

1. A press hardenable steel comprising, by weight percent, 0.22-0.25% carbon, 2.0 to 3.0% manganese, 0.2-0.3% silicon, 0.2 to 6.0% chromium, no more than 0.004% aluminum, and at least one of 0.1 to 0.6% molybdenum, 0.01 to 0.1% niobium, or 0.01 to 0.15% vanadium, the balance comprising iron and incidental impurities, wherein the ultimate tensile strength of such steel is greater than 1800 MPa, and a total elongation of such steel is at least 6%.

2. The press hardenable steel of claim 1 comprising 0.4 to 0.6% molybdenum.

3. The press hardenable steel of claim 1 comprising 2.0 to 6.0% chromium.

4. The press hardenable steel of claim 1 having two outer surfaces, and further comprising an aluminum-based coating or a zinc-based coating applied to at least one outer surface.

5. The press hardenable steel of claim 1 , wherein the press hardenable steel can be fully austenitized at a PMT of less than 850° C.

6. The press hardenable steel of claim 1 comprising 0.4-6.0% chromium.

7. The press hardenable steel of claim 1 , without the intentional addition of titanium.

8. The press hardenable steel of claim 1 , without the intentional addition of antimony.

9. The press hardenable steel of claim 1 , wherein vanadium is 0.01 to 0.1%.

10. The press hardenable steel of claim 1 , without the intentional addition of boron.

11. The press hardenable steel of claim 1 , without the intentional addition of antimony and boron.

12. The press hardenable steel of claim 1 , without the intentional addition of antimony and boron, and where vanadium is 0.01 to 0.1%.

13. The press hardenable steel of claim 1 , wherein chromium is 0.2 to less than 3.0%.

Assignments (11)
RELEASE OF SECURITY INTEREST Recorded Apr 5, 2024
From: U.S. BANK NATIONAL ASSOCIATION
To: CLEVELAND-CLIFFS INC.; CLEVELAND-CLIFFS STEEL CORPORATION (F/K/A AK STEEL CORPORATION); CLEVELAND-CLIFFS STEEL PROPERTIES INC. (F/K/A AK STEEL PROPERTIES, INC.)
Reel/Frame 067025/0974 →
RELEASE OF SECURITY INTEREST Recorded May 11, 2022
From: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, SUCCESSOR IN INTEREST TO U.S. BANK NATIONAL ASSOCIATION
To: CLEVELAND-CLIFFS INC.; CLEVELAND-CLIFFS STEEL CORPORATION (F/K/A AK STEEL CORPORATION),; CLEVELAND-CLIFFS STEEL PROPERTIES, INC. (F/K/A AK STEEL PROPERTIES, INC.); IRONUNITS LLC
Reel/Frame 063272/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE RECEIVING PARTY DATA FROM CLEVELAND-CLIFFS STEEL PROPERTIES TO CLEVELAND-CLIFFS STEEL PROPERTIES INC. PREVIOUSLY RECORDED AT REEL: 056313 FRAME: 0443. ASSIGNOR(S) HEREBY CONFIRMS THE CHANGE OF NAME. Recorded Jul 2, 2021
From: AK STEEL PROPERTIES, INC.
To: CLEVELAND-CLIFFS STEEL PROPERTIES INC.
Reel/Frame 057941/0376 →
CORRECTIVE ASSIGNMENT TO CORRECT THE RECEIVING PARTY DATA PREVIOUSLY RECORDED AT REEL: 056228 FRAME: 0566. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded May 20, 2021
From: AK STEEL PROPERTIES, INC.
To: CLEVELAND-CLIFFS STEEL PROPERTIES
Reel/Frame 056313/0443 →
CHANGE OF NAME Recorded May 13, 2021
From: AK STEEL PROPERTIES, INC.
To: CLEVELAND-CLIFFS STEEL PROPERTIES INC.
Reel/Frame 056228/0566 →
RELEASE OF SECURITY INTEREST Recorded Mar 15, 2021
From: U.S. BANK NATIONAL ASSOCIATION
To: AK STEEL CORPORATION; AK STEEL PROPERTIES, INC.
Reel/Frame 055587/0118 →
PATENT SECURITY AGREEMENT Recorded Apr 17, 2020
From: CLEVELAND-CLIFFS INC.; AK STEEL CORPORATION; AK STEEL PROPERTIES, INC.
To: U.S. BANK NATIONAL ASSOCIATION, AS NOTES COLLATERAL AGENT
Reel/Frame 052432/0166 →
PATENT SECURITY AGREEMENT Recorded Mar 13, 2020
From: CLEVELAND-CLIFFS INC.; AK STEEL CORPORATION; AK STEEL PROPERTIES, INC.
To: U.S. BANK NATIONAL ASSOCIATION, AS NOTES COLLATERAL AGENT
Reel/Frame 052162/0865 →
PATENT SECURITY AGREEMENT Recorded Mar 13, 2020
From: CLEVELAND-CLIFFS INC.; AK STEEL CORPORATION; AK STEEL PROPERTIES, INC.
To: BANK OF AMERICA, N.A., AS AGENT
Reel/Frame 052162/0782 →
PATENT SECURITY AGREEMENT Recorded Mar 13, 2020
From: AK STEEL CORPORATION; AK STEEL PROPERTIES, INC.
To: U.S. BANK NATIONAL ASSOCIATION, AS NOTES COLLATERAL AGENT
Reel/Frame 052162/0691 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 8, 2018
From: PAVLINA, ERIK JAMES
To: AK STEEL PROPERTIES, INC.
Reel/Frame 045141/0951 →