Photo-thermally induced polymerization inhibitors for electrophoretic media
View Patent ↗An electrophoretic medium that may be incorporated into an electrophoretic display includes a dispersion that may be contained in a plurality of microcapsules or microcells or a polymeric continuous phase. The dispersion may include a non-polar fluid, a plurality of first charged particles; and an inhibitor of photo-thermally induced polymerization that inhibits potential cross-linking between the particles and/or the microcells or polymeric continuous phase. The inhibitor may be a compound having an unsaturated hydrocarbon ring and at least one of a hydroxyl group, a carbonyl group, and a nitroso group. The plurality of microcells or polymeric continuous phase and a coating of the particles may include a polymeric material that includes (meth)acrylates.
1. An electrophoretic medium comprising a dispersion, the dispersion comprising:
(a) a non-polar fluid;
(b) a plurality of first charged particles; and
(c) an inhibitor of photo-thermally induced polymerization, wherein the inhibitor is selected from the group consisting of 2, 6-di-tert-butyl-p-cresol, tris (N-nitroso-N-phenylhydroxylamine) aluminum salt, 4,4′,4″-(1-methylpropanyl-3-ylidene)tris[6-tert-butyl-m-cresol], and 4,4′-butylidenebis(6-tert-butyl-m-cresol).
2. The electrophoretic medium of claim 1 , wherein the first charged particles comprise a polymeric coating containing (meth)acrylate groups.
3. The electrophoretic medium of claim 2 , wherein the dispersion is encapsulated within a plurality of microcells or polymeric continuous phase comprising a polymeric material containing (meth)acrylate groups.
4. The electrophoretic medium of claim 1 , wherein the dispersion is encapsulated.
5. The electrophoretic medium of claim 4 , wherein the dispersion is encapsulated within a plurality of microcells or polymeric continuous phase comprising a polymeric material containing (meth)acrylate groups.
6. The electrophoretic medium of claim 1 , further comprising a plurality of second charged particles dispersed in the non-polar fluid, wherein the first and second charged particles have opposite charges, and at least one of the first and second charged particles comprises a polymeric coating containing (meth)acrylate groups.
7. The electrophoretic medium of claim 6 , wherein the dispersion is encapsulated within a plurality of microcells or polymeric continuous phase comprising a polymeric material containing (meth)acrylate groups.
8. The electrophoretic medium of claim 1 , wherein the first charged particles comprise titania, carbon black, or copper chromite.
9. The electrophoretic medium of claim 1 , wherein the weight percent of the inhibitor is 0.01 to 10% based on the total weight of the dispersion.
10. The electrophoretic medium of claim 1 , wherein the weight percent of the inhibitor is 0.1 to 5% based on the total weight of the dispersion.
11. The electrophoretic medium of claim 1 further comprising a plurality of second charged particles and a plurality of third charged particles dispersed in the non-polar fluid, wherein each of the first, second, or third charged particles are a different color selected from red, green, blue, cyan, yellow, and magenta.