IP Library Granted Patent US 10,144,865
Granted Patent B2
US 10,144,865 · App. 15/907,226 · Granted Dec 4, 2018

Method of preparing and using drag-reducing dispersion polymer compositions

Inventors: Andrei Zelenev (Spring, TX); Lakia Champagne (The Woodlands, TX); David Philpot (Marlow, OK)
Assignee: Flotek Chemistry, LLC
C09K8/68C09K8/512C09K8/528C09K8/584C09K8/588C09K8/604C09K8/608C09K8/64C09K8/82E21B43/20C09K2208/28
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Quick Facts
Patent No.
US 10,144,865
App. No.
15/907,226
Granted
Dec 4, 2018
Kind
B2
Abstract

A method of preparing a drag-reducing composition that includes a dispersion polymer includes steps for preparing the dispersion polymer, steps for incorporating the dispersion polymer into a drag-reducing composition, and steps for using the drag-reducing composition. The step of preparing a dispersion polymer includes preparing an aqueous mixture by adding a water-soluble salt and at least one polymeric dispersant to water and polymerizing one or more water-soluble monomers in the aqueous mixture. Once the dispersion polymer has been combined with the drag-reducing additive, the combination is injected into a subterranean formation, a pipeline or a gathering line.

Claims (33)

1. A method comprising the steps of:

preparing a dispersion polymer, wherein the step of preparing the dispersion polymer comprises:

preparing an aqueous mixture by adding a water-soluble salt, at least one polymeric dispersant, and one or more water-soluble monomers to water; and

polymerizing the one or more water-soluble monomers in the aqueous mixture;

preparing a drag-reducing additive by mixing the dispersion polymer with a surfactant and a solvent;

forming a drag-reducing composition by combining the drag-reducing additive with an aqueous treatment fluid; and

injecting the drag-reducing composition into a subterranean formation, a pipeline or a gathering line.

2. The method of claim 1 , wherein the step of forming the drag-reducing composition with the aqueous treatment fluid further comprises the step of adding the drag-reducing additive into the aqueous treatment fluid on-the-fly as the aqueous treatment fluid is pumped into the subterranean formation, pipeline or gathering line.

3. The method of claim 1 , wherein the step of forming the drag-reducing composition further comprises the step of adding the drag-reducing additive to the aqueous treatment fluid before the drag-reducing composition is pumped into the subterranean formation, pipeline or gathering line.

4. The method of claim 1 , wherein the step of forming the drag-reducing composition further comprises adding from about 0.01 gallons to about 50 gallons of drag-reducing additive per 1,000 gallons of the aqueous treatment fluid.

5. The method of claim 1 , wherein the step of preparing the drag-reducing additive further comprises mixing 40-85% by weight of the dispersion polymer with 10-35% by weight of a surfactant with an HLB greater than 8 and 5-30% by weight of a solvent.

6. A method comprising the steps of:

preparing a dispersion polymer, wherein the step of preparing the dispersion polymer comprises:

preparing an aqueous mixture by adding a water-soluble salt, at least one polymeric dispersant, and one or more water-soluble monomers to water; and

polymerizing the one or more water-soluble monomers in the aqueous mixture;

preparing a drag-reducing additive by mixing 40-85% by weight of the dispersion polymer with 10-35% by weight of a surfactant with an HLB greater than 8 and 5-30% by weight of a solvent;

forming the drag-reducing composition by combining the drag-reducing additive with an aqueous treatment fluid; and

injecting the drag-reducing composition into a subterranean formation, a pipeline or a gathering line.

7. The method of claim 6 , wherein the step of forming the drag-reducing composition with the aqueous treatment fluid further comprises the step of adding the drag-reducing additive into the aqueous treatment fluid on-the-fly as the aqueous treatment fluid is pumped into the subterranean formation, pipeline or gathering line.

8. The method of claim 6 , wherein the step of forming the drag-reducing composition further comprises the step of adding the drag-reducing additive to the aqueous treatment fluid before the drag-reducing composition is pumped into the subterranean formation, pipeline or gathering line.

9. The method of claim 6 , wherein the step of forming the drag-reducing composition further comprises adding from about 0.01 gallons to about 50 gallons of drag-reducing additive per 1,000 gallons of the aqueous treatment fluid.

10. A method comprising the steps of:

preparing a dispersion polymer;

preparing a drag-reducing additive by mixing the dispersion polymer with a surfactant and a solvent;

forming a drag-reducing composition by combining the drag-reducing additive with an aqueous treatment fluid; and

injecting the drag-reducing composition into a subterranean formation, a pipeline or a gathering line.

11. The method of claim 10 , wherein the step of preparing the dispersion polymer comprises:

preparing an aqueous mixture by adding a water-soluble salt, at least one polymeric dispersant, and one or more water soluble monomers to water; and

polymerizing the one or more water-soluble monomers in the aqueous mixture.

12. The method of claim 10 , wherein the step of preparing the drag-reducing additive further comprises mixing 40-85% by weight of the dispersion polymer with 10-35% by weight of a surfactant with an HLB greater than 8 and 5-30% by weight of the solvent.

13. The method of claim 10 , wherein the step of forming the drag-reducing composition by combining the drag-reducing additive with the aqueous treatment fluid further comprises the step of adding the drag-reducing additive into the aqueous treatment fluid on-the-fly as the aqueous treatment fluid is pumped into the subterranean formation, pipeline or gathering line.

14. The method of claim 10 , wherein the step of forming the drag-reducing composition by combining the drag-reducing additive with the aqueous treatment fluid further comprises the step of adding the drag-reducing additive to the aqueous treatment fluid before the drag-reducing composition is pumped into the subterranean formation, pipeline or gathering line.

15. The method of claim 10 , wherein the step of forming the drag-reducing composition by combining the drag-reducing additive with the aqueous treatment fluid further comprises the step of adding from about 0.01 gallons to about 50 gallons of drag-reducing additive per 1,000 gallons of the aqueous treatment fluid.

Assignments (4)
CORRECTIVE ASSIGNMENT TO CORRECT THE THE FIF THE INVENTOR SIGNATURE BLOCK ON THE ASSIGNMENT PREVIOUSLY RECORDED AT REEL: 046509 FRAME: 0856. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Jan 18, 2023
From: PARNELL, EARL; SANNER, TODD; HOLTMYER, MARLIN; PHILPOT, DAVID; ZELENEV, ANDREI; GILZOW, GYDEON; CHAMPAGNE, LAKIA; SIFFERMAN, THOMAS
To: CESI CHEMICAL, INC.
Reel/Frame 063543/0550 →
CONFIRMATORY ASSIGNMENT Recorded Nov 16, 2022
From: ZELENEV, ANDREI
To: CESI CHEMICAL, INC.
Reel/Frame 061951/0025 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 31, 2018
From: PARNELL, EARL; SANNER, TODD; HOLTMYER, MARLIN; PHILPOT, DAVID; ZELENEV, ANDREI; GILZOW, GYDEON; CHAMPAGNE, LAKIA; SIFFERMAN, THOMAS
To: CESI CHEMICAL, INC.
Reel/Frame 046509/0856 →
CONVERSION Recorded Jul 31, 2018
From: CESI CHEMICAL, INC.
To: FLOTEK CHEMISTRY, LLC
Reel/Frame 046671/0317 →
Continuity (3)
Division 14323830 · Jul 3, 2014
Continuation 12268408 · Nov 10, 2008
Related Publication 20180187068A1 · Jul 5, 2018