BORON-CONTAINING OIL WELL FRACTURING FLUID
A water source comprising a boron containing compound. The water source can have a boron concentration of not greater than 0.05 moles per liter. The water source further comprising a polyol. The polyol having a concentration of at least N times 0.05 moles per liter, wherein the water source is free of any boron-containing solid and has a dynamic viscosity of less than 100 cp.
1 . A method of preparing a fracturing fluid, comprising in the following order:
providing water from a water source, the water comprising a boron containing compound;
adding a polyol to the water; and
adding a polysaccharide-based polymer to the water and hydrating the polysaccharide-based polymer to form a hydrated polysaccharide-based polymer comprising fluid.
2 . The method according to claim 1 , further comprising determining a concentration of the boron containing compound.
3 . The method according to claim 2 , wherein determining the concentration of the boron containing compound is conducted before adding the polyol to the water.
4 . The method according to claim 1 , further comprising crosslinking the hydrated polysaccharide-based polymer by adding a cross-linking agent to form the fracturing fluid.
5 . The method according to claim 4 , wherein the cross-linking agent includes a borate compound.
6 . The method according to claim 5 , wherein the cross-linking agent is a delayed release borate.
7 . The method according to claim 4 , wherein a viscosity of the hydrated polysaccharide-based polymer comprising fluid is less than 100 cP.
8 . The method according to claim 7 , wherein the viscosity of the hydrated polysaccharide-based polymer comprising fluid is less than 50 cP.
9 . The method according to claim 1 , wherein a molar ratio of the boron containing compound to the polyol is not greater than 1:1.
10 . The method according to claim 9 , wherein the molar ratio of the boron containing compound to the polyol is not greater than 1:2.
11 . The method according to claim 10 , wherein the molar ratio of the boron containing compound to the polyol is not greater than 1:4.
12 . The method according to claim 1 , wherein an amount of the boron containing compound is not greater than 0.05 mol/liter.
13 . The method according to claim 12 , wherein an amount of the boron containing compound is not greater than 0.0046 mol/liter.
14 . The method according to claim 1 , wherein the polyol includes a C 2 -C 6 polyol, a C 2 -C 6 sugar alcohols, a C 2 -C 6 monosaccharides, a disaccharides made from C 2 -C 6 monosaccharides, a trisaccharides made from C 2 -C 6 monosaccharides, a C 2 -C 6 sugar acids, a C 2 -C 6 amino sugars, or any combination thereof.
15 . The method according to claim 1 , wherein the polyol includes a glycol, glycerin, glucose, sorbitol, dextrose, mannose, mannitol, or any combination thereof.
16 . The method according to claim 1 , wherein the polysaccharide-based polymer includes guar, methylcellulose, a derivative of methylcellulose, xantham gum, or any combination thereof.
17 . The method according to claim 1 , wherein a concentration of the boron-containing compound is at least 9.25×10 −8 mol/liter.
18 . The method according to claim 1 , further comprising adjusting the pH to at least 8.5 after hydrating the polysaccharide-based polymer.
19 . The method according to claim 1 , wherein the water source includes a well water source, a riparian water source, an aquifer water source, a lake water source, an ocean water source, a surface water source, a subterranean water source, an industrial water source, a waste water source, production water, flowback water, or any combination thereof.
20 . A method of forming a fracturing fluid, comprising in the following order:
providing water from a water source, the water comprising a boron containing compound;
adding a polyol to the water; and
adding a polysaccharide-based polymer to the water and hydrating the polysaccharide-based polymer to form a hydrated polysaccharide-based polymer comprising fluid; and
crosslinking the hydrated polysaccharide-based polymer with a cross-linking agent to form the fracturing fluid,
wherein a viscosity of the hydrated polysaccharide-based polymer comprising fluid before crosslinking is not greater than 100 cP.