Method for producing coated article
View Patent ↗To provide a production method for obtaining a coated article provided with a coating film having excellent weather resistance by using a powder coating material. A method for producing a coated article, which comprises applying a powder coating material comprising a fluororesin (A), a non-fluororesin (B) and a metallic pigment (C) to the surface of a substrate, and heating the substrate having the powder coating material applied, to a temperature of at least the glass transition temperature of the fluororesin (A) and the non-fluororesin (B), followed by cooling, to form a coating film on the substrate surface, and which is characterized in that the content of the metallic pigment (C) is from 0.7 to 23 mass % to the total amount of the powder coating material, the PCI value of the coating film is at least 6, and the flip-flop value is at least 1.2.
1. A method for producing a coated article, the method comprising:
applying a powder coating material comprising a fluororesin (A), a non-fluororesin (B) and a metallic pigment (C) to a surface of a substrate; then
heating the substrate having the powder coating material applied, at a temperature of at least a glass transition temperature of the fluororesin (A) and the non-fluororesin (B); and then
cooling to form a coating film on the substrate surface, to obtain the coated article,
wherein:
a content of the metallic pigment (C) is from 0.7 to 23 mass % relative to a total amount of the powder coating material;
the powder coating material further comprises a plasticizer (D) having a cyclic hydrocarbon group in the molecule;
a PCI value of the coating film is at least 6, where the PCI value is obtained based on smoothness of the coating film surface by comparison to smoothness visual judgement standard plates by Powder Coating Institute;
a flip-flop value of the coating film is at least 1.2, where the flip-flop value is obtained by a quotient:
“a brightness(25°) of light measured at an illumination angle of 25° and a light receiving angle of 0°, based on a direction (0°) perpendicular to the film surface”/
“a brightness(75°) of light measured at an illumination angle of 75° and a light receiving angle of 0°, based on a direction perpendicular to the film surface”.
2. The method for producing a coated article according to claim 1 , wherein a difference between an SP value of the fluororesin (A) and an SP value of the non-fluororesin (B) (SP value of the non-fluororesin (B)−SP value of the fluororesin (A)) is at least 0.4 (J/cm 3 ) 1/2 .
3. The method for producing a coated article according to claim 1 , wherein a mass ratio (AB) of the fluororesin (A) to the non-fluororesin (B) in the powder coating material is from 90/10 to 10/90.
4. The method for producing a coated article according to claim 1 , wherein the metallic pigment (C) comprises metal particles covered with a covering material.
5. The method for producing a coated article according to claim 4 , wherein an SP value of the covering material exceeds an SP value of the fluororesin (A), and an SP value of the covering material is less than an SP value of the non-fluororesin (B).
6. The method for producing a coated article according to claim 1 , wherein the plasticizer (D) has a melting point from 70 to 160° C.
7. The method for producing a coated article according to claim 1 , wherein an amount of the plasticizer (D) is from 0.1 to 40 parts by mass to 100 parts by mass relative to a total mass of the resin component contained in the powder coating material.
8. The method for producing a coated article according to claim 1 , wherein the powder coating material further comprises fine particles (E) of at least one selected from the group consisting of silica, alumina, titania and zinc oxide, said fine particles (E) having a specific surface area of from 10 to 500 m 2 /g and an average primary particle size of from 0.1 to 100 nm.
9. The method for producing a coated article according to claim 8 , wherein an amount of the fine particles (E) is from 0.01 to 10 parts by mass to 100 parts by mass relative to a total mass of resin component contained in the powder coating material.
10. The method for producing a coated article according to claim 1 , wherein the substrate having the powder coating material applied, is heated at from 120 to 300° C., and then, cooled by quenching or annealing to from 20 to 25° C.