IP Library Granted Patent US 10,815,583
Granted Patent B2
US 10,815,583 · App. 15/914,173 · Granted Oct 27, 2020

Composite graphene structures

Inventors: Jeff Bullington (Orlando, FL); Richard A. Stoltz (Plano, TX)
Assignee: GARMOR INC.
C25D15/00B82Y30/00C08L63/00C09D7/20C09D155/02C25D13/04D01F11/12D01F11/16D06M11/73D06M11/83Y10T428/292Y10T428/2944
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Quick Facts
Patent No.
US 10,815,583
App. No.
15/914,173
Granted
Oct 27, 2020
Kind
B2
Abstract

Graphene has been used in nanocomposites as constituents/doping in plastics or epoxy providing dramatic enhancement of the mechanical properties but have not progressed past the laboratory level novelty. This invention can provide a graphene based composite structure with a density less that 1.9 g/cm 3 for a fiber, yarn, rope or cable and a density less that 1.5 g/cm 3 for a sheet both structure have tensile and shear strength greater than either Aluminum or Steel; thus providing a graphene material that is both much lighter and stronger.

Claims (18)

1. A high-strength composite fiber comprising:

flat graphene flakes, each graphene flake comprising a plurality of graphene sheets stacked together, disposed on an electroplated metal layer formed on a substrate; and

a polymer chemically bonded at least one of in, about, or to the graphene flakes;

wherein the composite is formed into the fiber, or a yarn, a rope, or a cable that comprises a density less than 1.9 g/cm 3 .

2. A high-strength composite fiber comprising:

flat graphene flakes, each graphene flake comprising a plurality of graphene sheets stacked together, disposed on an electroplated layer formed on a substrate; and

a polymer chemically bonded at least one of in, about, or to the graphene flakes;

wherein the composite fiber is formed into a sheet or layer having a density less than 1.5 g/cm 3 .

3. The fiber of claim 1 , wherein the substrate is at least one of a plastic, a wood, a metal, a glass, or a grass.

4. The fiber of claim 1 , wherein the polymer is at least one of an epoxy, a thermoplastic, or a thermosetting polymer.

5. The fiber of claim 1 , wherein said flat graphene flakes are 5 to 50 micron across.

6. The fiber of claim 1 , wherein said flat graphene flakes are 5 to 20 micron across.

7. The fiber of claim 1 , wherein said flat graphene flakes are 5 to 14 micron across.

8. The fiber of claim 2 , wherein the substrate is at least one of a plastic, a wood, a metal, a glass, or a grass.

9. The fiber of claim 2 , wherein the polymer is at least one of an epoxy, a thermoplastic, or a thermosetting polymer.

10. The fiber of claim 2 , wherein said flat graphene flakes are 5 to 50 micron across.

11. The fiber of claim 2 , wherein said flat graphene flakes are 5 to 20 micron across.

12. The fiber of claim 2 , wherein said flat graphene flakes are 5 to 14 micron across.

Assignments (6)
SECURITY AGREEMENT Recorded Mar 27, 2023
From: ASBURY GRAPHITE OF NORTH CAROLINA, INC.; ASBURY CARBONS, INC.; PEC FRICTION FIGHTERS CORPORATION
To: PNC BANK, NATIONAL ASSOCIATION, AS AGENT
Reel/Frame 063169/0025 →
CORRECTIVE ASSIGNMENT TO CORRECT THE DELETE PATENT APPLICATIONS 15554974, 62899396, & 17012913 (974 ONLY LICENSED & 396 & 913 JIONLY OWNED WITH ANOTHER). PREVIOUSLY RECORDED AT REEL: 057306 FRAME: 0139. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Dec 15, 2022
From: GARMOR, INC.
To: ASBURY GRAPHITE OF NORTH CAROLINA, INC.
Reel/Frame 062248/0807 →
RELEASE OF SECURITY INTEREST Recorded Oct 12, 2021
From: ASBURY CARBONS, INC.
To: GARMOR, INC.
Reel/Frame 057763/0871 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 27, 2021
From: GARMOR, INC.
To: ASBURY GRAPHITE OF NORTH CAROLINA, INC.
Reel/Frame 057306/0139 →
SECURITY INTEREST Recorded Mar 29, 2021
From: GARMOR, INC.
To: ASBURY CARBONS, INC.
Reel/Frame 055757/0308 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 16, 2018
From: BULLINGTON, JEFF; STOLTZ, RICHARD
To: GARMOR INC.
Reel/Frame 045257/0483 →
Continuity (3)
Continuation 14353760
Provisional Application 61551983 · Oct 27, 2011
Related Publication 20180195198A1 · Jul 12, 2018