IP Library Granted Patent US 11,148,070
Granted Patent B2
US 11,148,070 · App. 15/914,993 · Granted Oct 19, 2021

Systems and methods of nanofiltration using graphene oxide

Inventors: David K. Biegelsen (Portola Valley, CA); Armin R. Volkel (Mountain View, CA)
Assignee: PALO ALTO RESEARCH CENTER INCORPORATED
B01D15/02B01D33/801B01D63/087B01D65/003B01D69/10B01D71/021B01D61/027B01D2239/1208B01D2251/602B82Y15/00
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Quick Facts
Patent No.
US 11,148,070
App. No.
15/914,993
Granted
Oct 19, 2021
Kind
B2
Abstract

Nanofiltration of aqueous solutions or other water-based fluids in various applications, such as desalination, dialysis, seawater purification, for example, may be enhanced through precisely controlling a filtration cutoff within graphene oxide nanofilters. By initially compressing and constraining the stacked thickness of multiple graphene oxide layers deposited between porous substrates, the interlayer gap size, and thus, the filtration cutoff may be adjusted and optimized.

Claims (32)

1. A nanofilter comprising:

a first porous support plate;

a second porous support plate;

graphene oxide layers deposited between the first and the second porous support plates, wherein the graphene oxide layers have pore sizes different than pore sizes in the first and second support plates;

an adjusting control to allow adjustment and to set at least one of pressure and distance between the first and second porous plates to compress and constrain the graphene oxide layers at a set position, the at least one of the pressure and the distance set based upon a desired filtration cutoff; and

a programmable controller connected to the adjusting control, the controller configured to provide the adjustment to the adjusting control based upon programmed filtration cutoff states mapped to a separate distance set by the adjusting control.

2. The nanofilter of claim 1 , further comprising:

a seal arranged between the first and second porous plates and surrounding the graphene oxide layers.

3. The nanofilter of claim 1 , further comprising:

a first porous substrate filter between the graphene oxide layers and the first porous plate; and

a second porous substrate filter between the graphene oxide and the second porous plate.

4. The nanofilter of claim 1 , further comprising:

a support frame;

a first flow channel arranged upstream of the first porous plate; and

a second flow channel arranged downstream of the second porous plate.

5. The nanofilter of claim 1 , wherein the adjusting control is remotely operable.

6. The nanofilter of claim 1 , wherein the distance between the first and second porous plates is mapped against an interlayer gap size of the graphene oxide layers.

7. A nanofiltration system comprising:

a filter including:

a first porous support plate;

a second porous support plate;

graphene oxide layers deposited between the first and the second porous support plates, wherein the graphene oxide layers have pore sizes different than the first and second support plates; and

an adjusting control to allow adjustment and to set at least one of pressure and distance between the first and second porous plates to compress and constrain the graphene oxide layers, the at least one of the pressure and the distance based upon a desired filtration cutoff;

a programmable controller connected to the adjusting control, the controller configured to provide the adjustment to the adjusting control based upon programmed filtration cutoff states mapped to a separate distance set by the adjusting control; and

a flow channel arranged tangentially to the filter.

8. The nanofiltration system of claim 7 , wherein the adjusting control includes a fine pitch screw.

9. The nanofiltration system of claim 7 , wherein the adjusting control includes an inch worm piezo element.

10. The nanofiltration system of claim 7 , wherein the adjusting control includes a spring mount.

11. The nanofiltration system of claim 7 , wherein the adjusting control includes a pneumatic element.

12. The nanofiltration system of claim 7 , further comprising:

a second filter; and

a second flow channel arranged tangentially to the second filter.

Assignments (10)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 6, 2025
From: XEROX CORPORATION
To: GENESEE VALLEY INNOVATIONS, LLC
Reel/Frame 073842/0479 →
SECOND LIEN NOTES PATENT SECURITY AGREEMENT Recorded Jul 2, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 071785/0550 →
FIRST LIEN NOTES PATENT SECURITY AGREEMENT Recorded Apr 11, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 070824/0001 →
SECURITY INTEREST Recorded Feb 13, 2024
From: XEROX CORPORATION
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 066741/0001 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENTS RECORDED AT RF 064760/0389 Recorded Feb 13, 2024
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: XEROX CORPORATION
Reel/Frame 068261/0001 →
SECURITY INTEREST Recorded Nov 20, 2023
From: XEROX CORPORATION
To: JEFFERIES FINANCE LLC, AS COLLATERAL AGENT
Reel/Frame 065628/0019 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVAL OF US PATENTS 9356603, 10026651, 10626048 AND INCLUSION OF US PATENT 7167871 PREVIOUSLY RECORDED ON REEL 064038 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Jun 28, 2023
From: PALO ALTO RESEARCH CENTER INCORPORATED
To: XEROX CORPORATION
Reel/Frame 064161/0001 →
SECURITY INTEREST Recorded Jun 22, 2023
From: XEROX CORPORATION
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 064760/0389 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 20, 2023
From: PALO ALTO RESEARCH CENTER INCORPORATED
To: XEROX CORPORATION
Reel/Frame 064038/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 8, 2018
From: BIEGELSEN, DAVID K.; VOLKEL, ARMIN R.
To: PALO ALTO RESEARCH CENTER INCORPORATED
Reel/Frame 045145/0983 →