IP Library Granted Patent US 11,217,846
Granted Patent B2
US 11,217,846 · App. 15/924,158 · Granted Jan 4, 2022

Electrochemical cell

Inventors: Dong Zhang (Webb City, MO); Jason A Mudge (Joplin, MO); David Timothy Andrew Darch (Neosho, MO); Destephen Mario (Joplin, MO); Ernest Ndzebet (Carl Junction, MO); Umamaheswari Janakiraman (Webb City, MO)
Assignee: EAGLEPICHER TECHNOLOGIES, LLC
H01M50/147H01M4/06H01M4/364H01M4/382H01M4/5835H01M4/623H01M4/625H01M4/80H01M6/16H01M6/166H01M50/172H01M50/183H01M50/636H01M4/663H01M4/667H01M2004/027H01M2004/028H01M2220/30H01M2300/0037
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Quick Facts
Patent No.
US 11,217,846
App. No.
15/924,158
Granted
Jan 4, 2022
Kind
B2
Abstract

An electrochemical cell that converts chemical energy to electrical energy includes a cathode with an active material of fluorinated carbon on a perforated metal cathode current collector, a lithium anode on a perforated metal anode current collector, a stepped header, a stable electrolyte, and a separator. In various embodiments, an anode current collector design, a cathode current collector design, a stepped header design, a cathode formulation, an electrolyte formulation, a separator, and a battery incorporating the electrochemical cell are provided.

Claims (39)

1. An electrochemical cell comprising:

a cathode, wherein the cathode comprises a cathode formulation comprising a cathode active material, a conductive carbon filler, and a binder, wherein the cathode formulation is disposed on a cathode current collector;

an anode, wherein the anode comprises at least one lithium metal foil disposed on an anode current collector;

a header comprising a stepped header comprising a first step and a second step, and a first opening, a second opening, and a third opening, wherein

an upper surface of the first step is disposed directly on a lower surface of the header and an upper surface of the second step is disposed directly on a lower surface of the first step,

the first opening has a length extending from an upper surface of the header, through a thickness of the header and a thickness of the first step, and to a bottom surface of the first step,

the first opening in the first step is configured for a ball seal,

the second opening and the third opening each have a length extending from an upper surface of the header, through the thickness of the header, the thickness of the first step, and a thickness of the second step, and to a bottom surface of the second step, wherein a first terminal pin for connection to a cathode tab portion extends through the length of the second opening and a second terminal pin for connection to an anode tab portion extends through the length of the third opening, and

the second opening and the third opening in the second step are configured for a glass seal; and

an electrolyte, wherein the electrolyte comprises a lithium salt in a mixed solvent;

wherein the electrochemical cell has an internal volume including an electrode, a separator, an electrolyte volume, and a void volume, and the electrolyte volume is in the range of 38 percent to 46 percent of the internal volume, and

wherein the electrochemical cell has a swelling percentage of less than or equal to about 2 percent.

2. The electrochemical cell of claim 1 , wherein the cathode active material is CF x , conductive carbon filler is carbon black, and binder is polytetrafluoroethylene in a ratio of about 90:6:4.

3. The electrochemical cell of claim 1 , wherein the cathode active material is blended with the binder and the conductive carbon filler to form a pellet, and the pellet is disposed on the cathode current collector.

4. The electrochemical cell of claim 1 , wherein the cathode current collector comprises perforations.

5. The electrochemical cell of claim 4 , wherein the perforations comprise large circles and small circles and wherein the average diameter for the large circles is about 2.4 mm and the average diameter for the small circles is about 1.9 mm.

6. The electrochemical cell of claim 4 , wherein a ratio of area comprising the perforations to a whole area of the cathode current collector is about 0.6.

7. The electrochemical cell of claim 1 , wherein the cathode current collector has a thickness of about 0.6 to 0.8 mm.

8. The electrochemical cell of claim 1 , wherein the cathode current collector is coated with conductive carbon.

9. The electrochemical cell of claim 8 , wherein the conductive carbon coating has a thickness of about 0.080 mm.

10. The electrochemical cell of claim 1 , wherein the anode current collector comprises perforations, wherein the perforations comprise a diamond shape, a circle, an oval, a rectangle, a star, a triangle, and combinations thereof.

11. The electrochemical cell of claim 10 , wherein ratio of a perforated area to a total area of the anode current collector is about 0.6.

12. The electrochemical cell of claim 1 , wherein the anode current collector has a thickness of about 0.050 mm.

13. The electrochemical cell of claim 1 , wherein a ratio of an amount of electrolyte to an amount of cathode active material is in a range of about 0.7 to 1.1.

14. The electrochemical cell of claim 1 , wherein a ratio of an amount of electrolyte to an amount of cathode active material is 0.93.

15. The electrochemical cell of claim 1 , wherein the first step has a thickness of about 1.1 mm and the second step has a thickness of about 1.5 mm.

16. The electrochemical cell of claim 1 , wherein the lithium salt is present in an amount in a range of about 0.8 moles per liter to about 1.2 moles per liter based on a total volume of the solvent in the electrolyte.

17. An implantable device comprising:

the electrochemical cell of claim 1 , wherein

a ratio of an amount of electrolyte to an amount of cathode active material is about 0.93.

18. The electrochemical cell of claim 1 , wherein the electrolyte volume is in the range of about 40 percent to about 44 percent of the internal volume.

19. The electrochemical cell of claim 1 , wherein the electrolyte volume is in the range of about 41 percent to about 43 percent of the internal volume.

20. The electrochemical cell of claim 1 , wherein the electrolyte volume is about 42 percent of the internal volume.

21. The electrochemical cell of claim 1 , wherein the void volume is in the range of about 3 percent to about 9 percent of the internal volume.

22. The electrochemical cell of claim 1 , wherein the void volume is in the range of about 4 percent to about 8 percent of the internal volume.

23. The electrochemical cell of claim 1 , wherein the void volume is in the range of about 5 percent to about 7 percent of the internal volume.

24. The electrochemical cell of claim 1 , wherein the void volume is about 6 percent of the internal volume.

25. The electrochemical cell of claim 1 , wherein the length of the first step is less than a length of the header, and a length of the second step is less than a length of the first step.

26. The electrochemical cell of claim 1 , wherein the entire upper surface of the first step is disposed directly on the lower surface of the header and the entire upper surface of the second step is disposed directly on a lower surface of the first step.

Assignments (3)
CHANGE OF NAME Recorded Oct 12, 2023
From: EAGLEPICHER ENERGY PRODUCTS ULC
To: RESONETICS MEDICAL POWER CANADA ULC
Reel/Frame 065220/0159 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 21, 2022
From: EAGLEPICHER TECHNOLOGIES, LLC
To: EAGLEPICHER ENERGY PRODUCTS, ULC
Reel/Frame 059666/0367 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 15, 2018
From: ZHANG, DONG; MUDGE, JASON A; DARCH, DAVID TIMOTHY ANDREW; DESTEPHEN, MARIO; NDZEBET, ERNEST; JANAKIRAMAN, UMAMAHESWARI
To: EAGLEPICHER TECHNOLOGIES, LLC
Reel/Frame 046374/0845 →
Continuity (2)
Provisional Application 62472522 · Mar 16, 2017
Related Publication 20180269437A1 · Sep 20, 2018