Pigment powders
Disclosed are pigment powders containing only coated BiOCl flakes, which flakes area) BiOCl flakes having a coating containing yellow iron oxide Fe 2 O 3 *xH 2 O, optionally a colorant, optionally an adjuvant, and optionally SiO 2 , b) BiOCl flakes having a coating containing SiO 2 , optionally a colorant, and optionally an adjuvant, c) BiOCl flakes having a coating containing a colorant, SiO 2 , optionally yellow iron oxide Fe 2 O 3 *xH 2 O, and optionally an adjuvant, or d) BiOCl flakes having a coating containing Fe 3 O 4 and optionally SiO 2 , to a process for the preparation of the pigment powders, and to the use thereof especially in cosmetic formulations.
1. A pigment powder consisting of coated BiOCl flakes, which flakes are selected from the group consisting of
a) BiOCl flakes having a coating consisting of yellow iron oxide Fe 2 O 3 *xH 2 O, and optionally a colorant, a surfactant, nano-particles of a metal or metal oxide or metal salt, or SiO 2 ,
b) BiOCl flakes having a coating consisting of
SiO 2 , and
optionally a colorant, a surfactant or nano-particles of a metal or metal oxide or metal salt,
wherein the coated BiOCl flakes consist of 90-95% by weight of BiOCl flakes and 5-10% by weight of the coating, where the % by weight are based on the total weight of the coated BiOCl flakes,
c) BiOCl flakes having a coating consisting of
a colorant,
SiO 2 , and
optionally yellow iron oxide Fe 2 O 3 *xH 2 O, a surfactant, or nano-particles of a metal or metal oxide or metal salt,
and
d) BiOCl flakes having a coating consisting of
Fe 3 O 4 , and
optionally SiO 2 ,
wherein the coated BiOCl flakes consist of 75-95% by weight of BiOCl flakes, 5-20% by weight of Fe 3 O 4 , and 0-5% by weight of SiO 2 , where the % by weight are based on the total weight of the coated BiOCl flakes;
and
wherein, in a), b), c) and d),
the BiOCl flakes without counting the coating have a thickness of <100 nm, the coatings are directly on the BiOCl flakes, and the coated BiOCl flakes optionally contain an organic after coating.
2. The pigment powder according to claim 1 , wherein the coated BiOCl flakes are selected from the group consisting of
a) coated BiOCl flakes, wherein the coating consist of a first layer and optionally a second layer, wherein the first layer consists of yellow iron oxide Fe 2 O 3 *xH 2 O, and optionally a colorant, a surfactant or nano-particles of a metal or metal oxide or metal salt, and the optional second layer consists of SiO 2 ,
b) coated BiOCl flakes having a layer consisting of SiO 2 , wherein the coated BiOCl flakes consist of 90-95% by weight of BiOCl flakes and 5-10% by weight of the SiO 2 , where the % by weight are based on the total weight of the coated BiOCl flakes,
c) coated BiOCl flakes, wherein the coating consist of a first layer and optionally a second layer, wherein the first layer consists of a colorant, SiO 2 , and optionally yellow iron oxide Fe 2 O 3 *xH 2 O, is a surfactant or nano-particles of a metal or metal oxide or metal salt, and the optional second layer consists of SiO 2 , and
d) coated BiOCl flakes, wherein the coating consist of a first layer and optionally a second layer, wherein the first layer consists of Fe 3 O 4 and the optional second layer consists of SiO 2 , wherein the coated BiOCl flakes consist of 75-95% by weight of BiOCl flakes, 5-20% by weight of Fe 3 O 4 , and 0-5% by weight of SiO 2 , where the % by weight are based on the total weight of the coated BiOCl flakes.
3. The pigment powder according to claim 1 , wherein the coated BiOCl flakes contain an organic after coating.
4. The pigment powder according claim 1 , wherein the coated BiOCl flakes consist of 70-92% by weight of BiOCl flakes and 8-30% by weight of yellow iron oxide Fe 2 O 3 *xH 2 O, where the % by weight are based on the total weight of the coated BiOCl flakes.
5. The pigment powder according claim 1 , wherein the coated BiOCl flakes consist of 55-94.99% by weight of BiOCl flakes, 5-40% by weight of yellow iron oxide Fe 2 O 3 *xH 2 O, and 0.01-5% by weight of SiO 2 , where the % by weight are based on the total weight of the coated BiOCl flakes.
6. The pigment powder according to claim 1 , wherein the coated BiOCl flakes consist of 57 to 89.98% by weight of BiOCl flakes, 0.01-3% by weight of yellow iron oxide Fe 2 O 3 *xH 2 O, 5 to 20% by weight of a colorant, 5-15% by weight of SiO 2 , and 0.01-5% by weight of a surfactant or nano-particles of a metal or metal oxide or metal salt, where the % by weight are based on the total weight of the coated BiOCl flakes.
7. The pigment powder according to claim 1 , wherein the coated BiOCl flakes consist of 94-95% by weight of BiOCl flakes and 5-6% by weight of SiO 2 , where the % by weight are based on the total weight of the coated BiOCl flakes.
8. The pigment powder according to claim 1 , wherein the coated BiOCl flakes consist of 75-95% by weight of BiOCl flakes, 5-20% by weight of Fe 3 O 4 , and 3-5% by weight of SiO 2 , where the % by weight are based on the total weight of the coated BiOCl flakes.
9. The pigment powder according to claim 1 , wherein the colorant is an FD&C colorant or an D&C colorant or the lake form of a colorant, or phthalocyanine blue or green.
10. The pigment powder according to claim 1 , wherein BiOCl flakes have a particle size<25 μm.
11. A process for the production of the pigment powder according to claim 1 , comprising coating uncoated BiOCl flakes by a wet-chemical method and the resultant coated BiOCl flakes are worked up, subsequently spray-dried or oven dried, and optionally baked at 200 to 400° C. under an inert atmosphere.
12. A composition, comprising a pigment powder according to claim 1 .
13. The composition according to claim 12 , additionally comprising at least one constituent selected from the group consisting of absorbents, astringents, antimicrobial substances, antioxidants, antiperspirants, antifoaming agents, antidandruff active ingredients, antistatics, binders, biological additives, bleaching agents, chelating agents, deodorants, emollients, emulsifiers, emulsion stabilisers, dyes, humectants, film formers, fillers, odour substances, flavour substances, insect repellents, preservatives, anticorrosion agents, cosmetic oils, solvents, oxidants, vegetable constituents, buffer substances, reducing agents, surfactants, propellant gases, opacifiers, UV filters, UV absorbers, denaturing agents, viscosity regulators, perfume and vitamins.
14. A product selected from the group consisting of cosmetics, paints, coatings, inks, plastics, and films, comprising a pigment powder according to claim 1 .
15. The pigment powder according to claim 1 , which is a dry liquid free powder.
16. The pigment powder according to claim 1 , wherein, in the yellow iron oxide Fe 2 O 3 *xH 2 O, x is 0.5 to 1.0.
17. The pigment powder according to claim 1 , which is
a) BiOCl flakes having a coating consisting of yellow iron oxide Fe 2 O 3 *xH 2 O, and optionally a colorant, a surfactant, nano-particles of a metal or metal oxide or metal salt, or SiO 2 .
18. The pigment powder according to claim 1 , which is
b) BiOCl flakes having a coating consisting of SiO 2 , optionally a colorant, a surfactant or nano-particles of a metal or metal oxide or metal salt, wherein the coated BiOCl flakes consist of 90-95% by weight of BiOCl flakes and 5-10% by weight of the coating, where the % by weight are based on the total weight of the coated BiOCl flakes, or
c) BiOCl flakes having a coating consisting of a colorant, SiO 2 , optionally yellow iron oxide Fe 2 O 3 *xH 2 O, a surfactant or nano-particles of a metal or metal oxide or metal salt.
19. The pigment powder according to claim 1 , which is
d) BiOCl flakes having a coating consisting of Fe 3 O 4 and optionally SiO 2 , wherein the coated BiOCl flakes consist of 75-95% by weight of BiOCl flakes, 5-20% by weight of Fe 3 O 4 , and 0-5% by weight of SiO 2 , where the % by weight are based on the total weight of the coated BiOCl flakes.