FABRICATION OF CORRELATED ELECTRON MATERIAL DEVICES
Subject matter disclosed herein may relate to fabrication of correlated electron materials used, for example, to perform a switching function. In embodiments, precursors, in a gaseous form, may be utilized in a chamber to build a film of correlated electron materials comprising various impedance characteristics. In embodiments, a film of correlated electron materials may be annealed after deposition and prior to depositing a conductive material over the film.
1 . A method comprising:
depositing, in a chamber, one or more layers of a film of correlated electron material (CEM) on a conductive substrate;
annealing the one or more layers of the film of CEM formed on the conductive substrate; and
forming, following the annealing of the one or more layers of the film of CEM, a conductive overlay on the one or more layers of the film of CEM.
2 . The method of claim 1 , wherein depositing comprises utilizing a chemical vapor deposition process or utilizing a physical vapor deposition process.
3 . The method of claim 1 , wherein annealing the one or more layers of the film of CEM comprises exposing the film to a temperature of between about 300.0° C. and about 400.0° C. for a duration of about 20.0 min.
4 . The method of claim 3 , wherein annealing the one or more layers of the film of CEM comprises exposing the one or more layers of the film of CEM to a pressure comprising a value of between 1.0 kPa and 80.0 kPa.
5 . The method of claim 3 , wherein annealing the one or more layers of the film is performed via exposure of the one or more layers of the film of CEM to a pressure of between about 50.0 kPa to about 105.0 kPa.
6 . The method of claim 3 , further comprising removing the film of CEM from the chamber prior to annealing.
7 . The method of claim 3 , wherein the annealing is performed in the chamber, the chamber being substantially filled with gaseous oxygen.
8 . The method of claim 3 , wherein the annealing is performed in the chamber, the chamber being substantially filled with gaseous nitrogen.
9 . The method of claim 1 , wherein depositing one or more layers of a film of CEM on the conductive substrate gives rise to an atomic concentration of a dopant within the film of CEM of between 0.1% and 25.0%.
10 . The method of claim 9 , wherein the dopant comprises a carbon-containing dopant.
11 . The method of claim 9 , wherein annealing the one or more layers of the film of CEM comprises reducing the atomic concentration of the dopant within the film of CEM to between about 0.1% and about 15.0%.
12 . A method comprising:
depositing, in a chamber, one or more layers of a film of correlated electron material (CEM) on a conductive substrate, the one or more layers of the film of CEM comprising an atomic concentration of a dopant of between about 0.1% and about 25.0%;
reducing the atomic concentration of the dopant of the film of CEM to between about 0.1% and about 15.0% via annealing the film of CEM; and
depositing, following the annealing of the one or more layers of the film of CEM, a conductive overlay on the one or more layers of the film of CEM.
13 . The method of claim 12 , wherein depositing comprises utilizing a chemical vapor deposition process or a physical vapor deposition process.
14 . The method of claim 12 , wherein annealing the one or more layers of the film of CEM comprises exposing the film to a temperature of between about 250.0° C. and about 500.0° C. for a duration of about 10.0 minutes to about 35.0 minutes.
15 . The method of claim 14 , wherein annealing the one or more layers of the film of CEM comprises exposing the one or more layers of the film of CEM to a pressure comprising a value of between 1.0 kPa and 80.0 kPa.
16 . The method of claim 14 , further comprising removing the film of CEM from the chamber prior to annealing.
17 . The method of claim 14 , wherein the annealing is performed in an environment substantially filled with gaseous oxygen.
18 . The method of claim 14 , wherein the annealing is performed in an environment substantially filled with gaseous nitrogen.
19 . The method of claim 12 , wherein the dopant comprises a carbon-containing dopant.
20 . The method of claim 19 , wherein the carbon-containing dopant comprises carbonyl.
21 . The method of claim 12 , further comprising forming the conductive substrate from a material comprising titanium nitride, platinum, titanium, copper, aluminum, cobalt, nickel, tungsten, tungsten nitride, cobalt silicide, ruthenium oxide, chromium, gold, palladium, indium tin oxide, tantalum, silver or iridium, or any combination thereof.