IP Library Granted Patent US 10,838,258
Granted Patent B2
US 10,838,258 · App. 15/940,065 · Granted Nov 17, 2020

Liquid crystal alignment layers and method of fabrication

Inventors: Anita Trajkovska-Broach (Christiansburg, VA); David Boyd (Roanoke, VA); Dan Chambers (Roanoke, VA); Joseph O. Branham (Farmington, CT)
Assignee: E-VISION, LLC
G02F1/13378G02F1/133753G02F1/133788G02F2001/133796Y10T29/49147
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Quick Facts
Patent No.
US 10,838,258
App. No.
15/940,065
Granted
Nov 17, 2020
Kind
B2
Abstract

Methods are provided for making layers with nano- and micro-patterned topographies by laser action or inkjet printing on a first surface. These topographies have a periodicity of 5 nm to 500 μm in a first direction in the plane of the first surface. These layers can be used as anisotropically patterned alignment layers in electro-optical devices and generate an orientational order of at least 0.30.

Claims (35)

1. A method comprising:

providing a first surface;

depositing a solution over the first surface via inkjet printing to form a first anisotropic pattern; and

solidifying the solution to form a first anisotropically patterned alignment layer having features with a size of 5 nm to 500 μm,

wherein the first anisotropic pattern formed by the deposition has a first pitch of 5 nm to 500 μm in a first direction in the plane of the first surface.

2. The method of claim 1 , wherein the first anisotropic pattern formed by the deposition has a second pitch in a second direction in the plane of the surface, the first direction is different from the second direction, the first pitch is different from the second pitch, and the second pitch is 5 nm to 500 μm.

3. The method of claim 1 , wherein depositing the solution includes depositing drops of the solution and solidifying the solution includes partially coalescing the drops while retaining at least some structure of the first pitch.

4. The method of claim 1 , wherein the first surface is a first surface of a substrate.

5. The method of claim 1 , wherein the first surface is a first surface of an electrode.

6. The method of claim 1 , wherein the first surface is a first surface of a separate layer disposed on an electrode or a substrate.

7. The method of claim 1 , further comprising:

providing a first substrate;

providing a first electrode disposed over the first substrate;

disposing the first surface over the electrode;

providing a liquid crystal layer disposed over the first surface;

providing a second surface disposed over the liquid crystal layer;

providing a second electrode disposed over the second surface; and

providing a second substrate disposed over the second electrode.

8. The method of claim 7 , wherein:

providing the second surface comprises depositing the solution over the second surface via inkjet printing to form a second anisotropic pattern; and

solidifying the solution to form a second anisotropically patterned alignment layer having features with a size of 5 nm to 500 μm and a third pitch of 5 nm to 500 μm in a third direction in the plane of the second surface.

9. The method of claim 8 , wherein the second anisotropic pattern has a fourth pitch in a fourth direction in the plane of the second surface, the third direction is different from the fourth direction, the third pitch is different from the fourth pitch, and the fourth pitch is 5 nm to 500 μm.

10. The method of claim 1 , wherein the step of solidifying the solution comprises illuminating the solution with ultra-violet radiation.

11. The method of claim 1 , wherein the step of solidifying the solution comprises heating the solution with infra-red radiation.

12. The method of claim 1 , wherein the solution comprises at least one of a conjugated polymer, an acrylate, a urethane, an organosilane, or an epoxy.

13. The method of claim 1 , wherein the solution comprises at least one of a surfactant or a binder.

14. The method of claim 1 , wherein the solution comprises at least one of an alcohol, a ketone, an aldehyde, an alkane, an alkene, or a chlorinated solvent.

15. The method of claim 1 , wherein the solution comprises nanoparticles of at least one of a metal or a metal oxide.

16. The method of claim 1 , wherein the solution comprises carbon nanotubes.

17. The method of claim 1 , further comprising:

aligning at least one of a nematic, cholesteric, smectic, discotic, or blue-phase liquid crystal layer with the anisotropically patterned alignment layer.

18. The method of claim 1 , further comprising:

aligning, with the anisotropically patterned alignment layer, a nematic liquid crystal layer with an orientational order parameter of at least S=0.50.

19. The method of claim 1 , further comprising:

at least one of managing, scattering, or diffracting light with the anisotropically patterned alignment layer.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 20, 2023
From: E-VISION, LLC
To: E-VISION OPTICS, LLC
Reel/Frame 065629/0772 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 6, 2018
From: HPO ASSETS LLC
To: MITSUI CHEMICALS, INC.
Reel/Frame 045462/0147 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 6, 2018
From: TRAJKOVSKA-BROACH, ANITA; BOYD, DAVID; CHAMBERS, DAN; BRANHAM, JOSEPH O.
To: HPO ASSETS LLC
Reel/Frame 045462/0167 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 6, 2018
From: MITSUI CHEMICALS, INC.
To: E-VISION, LLC
Reel/Frame 045462/0189 →
Continuity (4)
Division 14178069 · Feb 11, 2014
Provisional Application 61769283 · Feb 26, 2013
Provisional Application 61765462 · Feb 15, 2013
Related Publication 20180321533A1 · Nov 8, 2018