High temperature titanium alloys
A non-limiting embodiment of a titanium alloy comprises, in percent by weight based on total alloy weight: 5.1 to 6.5 aluminum; 1.9 to 3.2 tin; 1.8 to 3.1 zirconium; 3.3 to 5.5 molybdenum; 3.3 to 5.2 chromium; 0.08 to 0.15 oxygen; 0.03 to 0.20 silicon; 0 to 0.30 iron; titanium; and impurities. A non-limiting embodiment of the titanium alloy comprises an intentional addition of silicon in conjunction with certain other alloying additions to achieve an aluminum equivalent value of at least 6.9 and a molybdenum equivalent value of 7.4 to 12.8, which was observed to improve tensile strength at high temperatures.
1. A titanium alloy comprising, in percent by weight based on total alloy weight:
5.5 to 6.5 aluminum;
1.9 to 2.9 tin;
1.8 to 3.0 zirconium;
4.5 to 5.5 molybdenum;
4.2 to 5.2 chromium;
0.08 to 0.15 oxygen;
0.03 to 0.20 silicon;
greater than 0 to 0.30 iron;
titanium; and
impurities,
wherein the titanium alloy comprises an aluminum equivalent value of 8.0 to 9.5.
2. The titanium alloy of claim 1 comprising, in weight percentages based on total alloy weight:
5.5 to 6.5 aluminum;
2.2 to 2.6 tin;
2.0 to 2.8 zirconium;
4.8 to 5.2 molybdenum;
4.5 to 4.9 chromium;
0.08 to 0.13 oxygen;
0.03 to 0.11 silicon;
greater than 0 to 0.25 iron;
titanium; and
impurities.
3. The titanium alloy of claim 1 comprising, in weight percentages based on total alloy weight:
5.9 to 6.0 aluminum;
2.3 to 2.5 tin;
2.3 to 2.6 zirconium;
4.9 to 5.1 molybdenum;
4.5 to 4.8 chromium;
0.08 to 0.13 oxygen;
0.03 to 0.10 silicon;
greater than 0 to 0.07 iron;
titanium; and
impurities.
4. The titanium alloy of claim 1 further comprising, in weight percentages based on total alloy weight:
0 to 0.05 nitrogen;
0 to 0.05 carbon;
0 to 0.015 hydrogen; and
0 up to 0.1 each of niobium, tungsten, hafnium, nickel, gallium, antimony, vanadium, tantalum, manganese, cobalt, and copper.
5. The titanium ahoy of claim 1 , wherein the titanium alloy comprises a molybdenum equivalent value of 7.4 to 12.8, and exhibits an ultimate tensile strength of at least 160 ksi at 316° C.
6. The titanium alloy of claim 1 , wherein the titanium alloy comprises a molybdenum equivalent value of 7.4 to 12.8, and exhibits a yield strength of at least 140 ksi at 316° C.
7. The titanium alloy of claim 1 , wherein the titanium alloy comprises a molybdenum equivalent value of 7.4 to 12.8, and exhibits a time to 0.2% creep strain of at least 20 hours at 427° C. under a load of 60 ksi.
8. The titanium alloy of claim 1 , wherein the titanium alloy comprises an aluminum equivalent value of 8.0 to 9.5 and a molybdenum equivalent value of 7.4 to 12.8, and exhibits an ultimate tensile strength of at least 160 ksi at 316° C.
9. The titanium alloy of claim 1 , wherein the titanium alloy comprises an aluminum equivalent value of 8.0 to 9.5 and a molybdenum equivalent value of 7.4 to 12.8, and exhibits a yield strength of at least 140 ksi at 316° C.
10. The titanium alloy of claim 1 , wherein the titanium alloy comprises an aluminum equivalent value of 8.0 to 9.5 and a molybdenum equivalent value of 7.4 to 12.8, and exhibits a time to 0.2% creep strain of at least 20 hours at 427° C. under a load of 60 ksi.
11. The titanium alloy of claim 1 prepared by a process comprising:
solution treating the titanium alloy at 800° C. to 860° C. for 4 hours;
cooling the titanium alloy to ambient temperature at a rate depending on a cross-sectional thickness of the titanium alloy;
aging the titanium alloy at 620° C. to 650° C. for 8 hours; and
air cooling the titanium alloy.
12. A method for making an alloy, comprising:
solution treating a titanium alloy at 800° C. to 860° C. for 4 hours, wherein the titanium alloy comprises, in percent by weight based on total alloy weight, 5.5 to 6.5 aluminum, 1.9 to 2.9 tin, 1.8 to 3.0 zirconium, 4.5 to 5.5 molybdenum, 4.2 to 5.2 chromium, 0.08 to 0.15 oxygen, 0.03 to 0.20 silicon, greater than 0 to 0.30 iron, titanium, and impurities, wherein the titanium alloy comprises an aluminum equivalent value of 8.0 to 9.5;
cooling the titanium alloy to ambient temperature at a rate depending on a cross-sectional thickness of the titanium alloy;
aging the titanium alloy at 620° C. to 650° C. for 8 hours; and
air cooling the titanium alloy.
13. The method of claim 12 , wherein the titanium alloy further comprises, in weight percentages based on total alloy weight, 0 to 0.05 nitrogen, 0 to 0.05 carbon, 0 to 0.015 hydrogen, and 0 up to 0.1 each of niobium, tungsten, hafnium, nickel, gallium, antimony, vanadium, tantalum, manganese, cobalt, and copper.