Cutting elements and earth-boring tools comprising polycrystalline diamond
View Patent ↗A method of forming polycrystalline diamond includes encapsulating diamond particles, carbon monoxide, and carbon dioxide in a container. The encapsulated diamond particles, carbon monoxide, and carbon dioxide are subjected to a pressure of at least 4.5 GPa and a temperature of at least 1,400° C. to form inter-granular bonds between the diamond particles. A cutting element includes polycrystalline diamond material comprising inter-bonded grains of diamond. The polycrystalline diamond material is substantially free of graphitic carbon and metallic compounds. The polycrystalline diamond material exhibits a density of at least about 3.49 g/cm 3 and a modulus of at least about 1,000 GPa. An earth-boring tool may include such a cutting element secured to a body.
1. A cutting element comprising polycrystalline diamond material comprising inter-bonded diamond grains bonded directly together by diamond-to-diamond bonds, wherein the polycrystalline diamond material is substantially free of graphitic carbon and metallic compounds immediately after diamond particles, carbon monoxide, and carbon dioxide are subjected to a high-pressure/high-temperature (HPHT) sintering process, and wherein the polycrystalline diamond material exhibits a density of at least about 3.49 g/cm 3 and an elastic modulus of at least about 1000 GPa.
2. The cutting element of claim 1 , further comprising a substrate secured to the polycrystalline diamond material.
3. The cutting element of claim 2 , wherein the substrate comprises a material having a chemical composition different from a chemical composition of the polycrystalline diamond material.
4. The cutting element of claim 3 , wherein the substrate comprises a cobalt-cemented tungsten carbide material.
5. The cutting element of claim 1 , wherein the polycrystalline diamond material exhibits a density of at least 99% of the theoretical maximum density of diamond.
6. The cutting element of claim 5 , wherein the polycrystalline diamond material exhibits a density of at least 99.9% of the theoretical maximum density of diamond.
7. The cutting element of claim 1 , wherein the polycrystalline diamond material exhibits a multimodal grain size distribution.
8. The cutting element of claim 1 , wherein the polycrystalline diamond material defines a plurality of interstitial spaces, wherein the plurality of interstitial spaces are substantially free of solids and liquids.
9. The cutting element of claim 1 , wherein the polycrystalline diamond material exhibits a modulus of at least about 1100 GPa.
10. An earth-boring tool, comprising:
a body; and
a cutting element secured to the body, the cutting element comprising polycrystalline diamond material comprising inter-bonded diamond grains bonded directly together by diamond-to-diamond bonds, wherein the polycrystalline diamond material is substantially free of graphitic carbon and metallic compounds immediately after diamond particles, carbon monoxide, and carbon dioxide are subjected to a high-pressure/high-temperature (HPHT) sintering process, and wherein the polycrystalline diamond material exhibits a density of at least about 3.49 g/cm 3 and an elastic modulus of at least about 1000 GPa.
11. The earth-boring tool of claim 10 , wherein the body comprises an earth-boring rotary drill bit.
12. The earth-boring tool of claim 10 , wherein the polycrystalline diamond material is unleached.
13. The earth-boring tool of claim 10 , wherein the cutting element is secured within a pocket defined by the body.
14. The earth-boring tool of claim 10 , wherein the body comprises a body of a tool selected from the group consisting of roller cone bits, percussion bits, hybrid bits, and reamers.
15. The earth-boring tool of claim 10 , wherein the cutting element further comprises a substrate secured to the polycrystalline diamond material.
16. The earth-boring tool of claim 15 , wherein the substrate comprises a cobalt-cemented tungsten carbide material.
17. The earth-boring tool of claim 10 , wherein the polycrystalline diamond material exhibits a multimodal grain size distribution.
18. The earth-boring tool of claim 10 , wherein the polycrystalline diamond material defines a plurality of interstitial spaces, wherein the plurality of interstitial spaces are substantially free of solids and liquids.
19. The earth-boring tool of claim 10 , wherein the polycrystalline diamond material exhibits a density of at least 99% of the theoretical maximum density of diamond.
20. The earth-boring tool of claim 19 , wherein the polycrystalline diamond material exhibits a density of at least 99.9% of the theoretical maximum density of diamond.