Nylon based filaments, yarns and fabrics
View Patent ↗Nylon based filaments, yarns, and fabrics having improved properties are provided. A filament contains a composite material formed from a (i) a main structural component containing a mixture of one or more base nylons and one or more secondary nylons, and optionally (ii) an additive component mixed with the main structural component. The one or more base nylons may include one or more aliphatic nylons and the one or more secondary nylons may include one or more semiaromatic nylons.
1. A multifilament comprising:
one or more filaments that comprise a composite material comprising (i) a main structural component consisting of a mixture of one or more base nylons and one or more secondary nylons, and optionally (ii) an additive component mixed with the main structure component,
wherein the one or more base nylons and the one or more secondary nylons are present in amounts such that the filament has a greater tenacity than an otherwise equivalent filament having a main structural component consisting of the one or more base nylons,
wherein the one or more filaments have a tenacity which is from about 30% to about 60% greater than that of an otherwise equivalent filament having a main structural component consisting of the one or more base nylons,
wherein the one or more filaments have an elongation at break which is at least about 10% lower than that of the otherwise equivalent filament, and
wherein the one or more secondary nylons have a glass transition temperature from 130° C. to 150° C. and the one or more base nylons has a glass transition temperature from 15° C. to 75° C.
2. The multifilament of claim 1 , wherein the one or more base nylons consist of one or more aliphatic nylons and the one or more secondary nylons consist of one or more semiaromatic nylons.
3. The multifilament of claim 2 , wherein:
the one or more aliphatic nylons are selected from nylon 6,6, nylon 6, nylon 6,69, nylon 6,66, nylon 66,6, nylon 6,12, nylon 6,10, nylon 11, nylon 12, and mixtures thereof, and
the one or more semiaromatic nylons are selected from MXD6, 6I/6T, 6T/6I, DT/DI, DI/DT, 6I/6T/DI/DT, 6I/DI, 6T/DT, Dicycan-I, Dimetyldicycan-I, Dimethyldicycan-T, and Dicycan-T.
4. The multifilament of claim 1 , wherein the one or more secondary nylons are present in the composite material in an amount of from about 2 percent, by weight, to about 10 percent, by weight.
5. The multifilament of claim 1 , wherein the one or more secondary nylons are present in the composite material in an amount of from about 2 percent, by weight, to about 6 percent, by weight.
6. The multifilament of claim 1 , wherein the additive component is present in the composite material in an amount of from about 0.1 percent, by weight, to about 3 percent, by weight.
7. The multifilament of claim 1 , wherein the multifilament has a tenacity of from about 3 to about 11 grams per denier.
8. The multifilament of claim 1 , wherein the one or more base nylons and the one or more secondary nylons are present in the filaments in amounts such that each filament has a tenacity that is from about 40% greater to about 60% greater than an otherwise equivalent filament having a main structural component consisting of the one or more base nylons.
9. A fabric comprising:
a multifilament comprising a plurality of filaments formed from a composite material comprising (i) a main structural component consisting of a mixture of one or more base nylons and one or more secondary nylons, and optionally (ii) an additive component mixed with the main structural component,
wherein the one or more base nylons and the one or more secondary nylons are present in the filaments in amounts such that each filament has a tenacity that is from about 30% to about 60% greater than an otherwise equivalent filament having a main structural component consisting of the one or more base nylons, and such that each filament has an elongation at break that is at least about 10% lower than the otherwise equivalent filament, and
wherein the one or more secondary nylons have a glass transition temperature from 130° C. to 150° C. and the one or more base nylons has a glass transition temperature from 15° C. to 75° C.
10. The fabric of claim 9 , wherein the one or more base nylons consist of one or more aliphatic nylons and the one or more secondary nylons consist of one or more semiaromatic nylons.
11. The fabric of claim 10 , wherein:
the one or more aliphatic nylons are selected from nylon 6,6, nylon 6, nylon 6,69, nylon 6,66, nylon 66,6, nylon 6,12, nylon 6,10, nylon 11, nylon 12, and mixtures thereof, and
the one or more semiaromatic nylons are selected from MXD6, 6I/6T, 6T/6I, DT/DI, DI/DT, 6I/6T/DI/DT, 6I/DI, 6T/DT, Dicycan-I, Dimetyldicycan-I, Dimethyldicycan-T, and Dicycan-T.
12. The fabric of claim 9 , wherein the filaments each have a denier per fiber of from about 0.1 dpf to about 3.5 dpf.
13. The fabric of claim 9 , wherein the one or more secondary nylons are present in the composite material in an amount of from about 2 percent, by weight, to about 10 percent, by weight.