IP Library Granted Patent US 10,684,377
Granted Patent B2
US 10,684,377 · App. 15/963,137 · Granted Jun 16, 2020

Scintillator, scintillator array, radiation detector, and radiation inspection device

Inventors: Kazumitsu Morimoto (Yokohama, JP); Yoshitaka Adachi (Yokohama, JP); Yukihiro Fukuta (Yokohama, JP)
Assignees: Kabushiki Kaisha Toshiba; Toshiba Materials Co., Ltd.
G01T1/2023A61B6/03C09K11/00C09K11/7771G01N23/04G01N23/046G01T1/20G01T1/2002G01T1/202G21K4/00
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Quick Facts
Patent No.
US 10,684,377
App. No.
15/963,137
Granted
Jun 16, 2020
Kind
B2
Abstract

A scintillator comprises a sintered body having a volume of 1 mm 3 or less. The sintered body includes a crystal region of a rare earth oxysulfide. The number of polycrystal bodies each having a different composition from that of the crystal region is 200 or less per a unit area of 100 μm×100 μm of a cross section of the sintered body.

Claims (22)

1. A scintillator, comprising;

a sintered body having a volume of 1 mm 3 or less, the sintered body including

crystal grains having a crystal region of a rare earth oxysulfide, wherein the rare earth oxysulfide is represented by a general formula (Gd 1-a-b Pr a M b ) 2 O 2 S, wherein M is at least one element selected from the group consisting of Ce, Yb, Eu, and Tb, a is a number satisfying 0.0001≤a≤0.01, and b is a number satisfying 0≤b≤0.005, wherein an average diameter of the crystal grains is 5 μm or more and 30 μm or less, and wherein a maximum diameter of the crystal grains is 50 μm or less, and

a grain boundary disposed between the crystal grains and having a polycrystal region of polycrystal bodies, wherein each polycrystal body has a different composition from a composition of the rare earth oxysulfide, and wherein each polycrystal body contains iron and phosphorous,

wherein the number of the polycrystal bodies is 200 or less per a unit area of 100 μm×100 μm of a cross section of the sintered body.

2. The scintillator according to claim 1 , wherein in an observation image of the cross section by a scanning electron microscope, a contrast of the polycrystal region is different from that of the crystal region, and a color of the polycrystal region is deeper and darker than that of the crystal region, and

wherein an area of the polycrystal region is 10000 μm 2 or less per a unit area of 500 μm×500 μm of the cross section.

3. The scintillator according to claim 1 , wherein each polycrystal body further contains at least one element selected from the group consisting of a carbonate, iron, aluminum, phosphorous, an alkali metal element, and an alkaline earth metal element.

4. A scintillator array comprising:

a first scintillator;

a second scintillator; and

a reflective layer between the first and second scintillators,

wherein each of the first and second scintillators is the scintillator according to claim 1 .

5. The scintillator array according to claim 4 , wherein the reflective layer contains a titanium oxide or an aluminum oxide.

6. The scintillator array according to claim 4 , wherein a width between the first and second scintillators in the reflective layer is 100 μm or less.

7. A radiation detector comprising the scintillator array according to claim 4 .

8. A radiation inspection device comprising the radiation detector according to claim 7 .

9. A scintillator, comprising:

a sintered body having a volume of 1 mm 3 or less, the sintered body including

crystal grains having a crystal region of a rare earth oxysulfide, wherein the rare earth oxysulfide is represented by a general formula ((Gd 1-α X α ) 1-a-b Pr a M b ) 2 O 2 S, wherein X is at least one element selected from the group consisting of Y, La, and Lu, M is at least one element selected from the group consisting of Ce, Yb, Eu, and Tb, α is a number satisfying 0<α<1, a is a number satisfying 0.0001≤a≤0.01, and b is a number satisfying 0≤b≤0.005, wherein an average diameter of the crystal grains is 5 μm or more and 30 μm or less, and wherein a maximum diameter of the crystal grains is 50 μm or less, and

a grain boundary disposed between the crystal grains and having a polycrystal region of polycrystal bodies, wherein each polycrystal body has a different composition from a composition of the rare earth oxysulfide, and wherein each polycrystal body contains iron and phosphorous,

wherein the number of the polycrystal bodies is 200 or less per a unit area of 100 μm×100 μm of a cross section of the sintered body.

Assignments (4)
NUNC PRO TUNC ASSIGNMENT Recorded Feb 19, 2026
From: KABUSHIKI KAISHA TOSHIBA
To: TOSHIBA MATERIALS CO. LTD.
Reel/Frame 074940/0511 →
CHANGE OF NAME Recorded Feb 19, 2026
From: TOSHIBA MATERIALS CO. LTD.
To: NITERRA MATERIALS CO., LTD.
Reel/Frame 074941/0803 →
CHANGE OF ADDRESS Recorded Feb 19, 2026
From: KABUSHIKI KAISHA TOSHIBA
To: KABUSHIKI KAISHA TOSHIBA
Reel/Frame 074941/0846 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 29, 2018
From: MORIMOTO, KAZUMITSU; ADACHI, YOSHITAKA; FUKUTA, YUKIHIRO
To: KABUSHIKI KAISHA TOSHIBA; TOSHIBA MATERIALS CO., LTD.
Reel/Frame 045920/0781 →
Priority Claims (1)
JP 2015-215683 · Nov 2, 2015 · national
Continuity (2)
Continuation PCTJP2016082542 · Nov 2, 2016
Related Publication 20180252824A1 · Sep 6, 2018