IP Library Granted Patent US 11,527,667
Granted Patent B2
US 11,527,667 · App. 15/964,852 · Granted Dec 13, 2022

Tunnel junctions for multijunction solar cells

Inventors: Nikhil Jain (Sunnyvale, CA); Myles Aaron Steiner (Denver, CO); John Franz Geisz (Wheat Ridge, CO); Emmett Edward Perl (Boulder, CO); Ryan Matthew France (Golden, CO)
Assignees: Alliance for Sustainable Energy, LLC; The Regents of the University of California, A California Corporation
H01L31/0725H01L31/036H01L31/035209H01L31/0687H01L31/0693H01L31/0735Y02E10/544
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Quick Facts
Patent No.
US 11,527,667
App. No.
15/964,852
Granted
Dec 13, 2022
Kind
B2
Abstract

Tunnel junctions for multijunction solar cells are provided. According to an aspect of the invention, a tunnel junction includes a first layer including p-type AlGaAs, a second layer including n-type GaAs, wherein the second layer is a quantum well, and a third layer including n-type AlGaAs or n-type lattice matched AlGaInP. The quantum well can be GaAs or AlxGaAs with x being more than about 40%, and lattice matched GaInAsNSb in the Eg range of from about 0.8 to about 1.4 eV.

Claims (10)

1. A tunnel junction in a multijunction solar cell comprising, in order:

a first layer comprising p-type AlGaAs;

a second layer comprising n-type GaAs, wherein the second layer is a quantum well; and

a third layer comprising n-type AlGaAs, wherein the concentration of Al in the third layer is at least 50%; and

wherein the second layer and the third layer are doped with Se, Si, Te or any combination thereof at a concentration of from about 1×10 18 cm −3 to about 1×10 20 cm −3 .

2. The tunnel junction of claim 1 , wherein a concentration of Al in the first layer is selected from the group consisting of at least 40%, at least 50%, and at least 60%.

3. The tunnel junction of claim 1 , further comprising additional adjacent layers selected from the group consisting of AlInGaP, AlGaAs, GaAs, GaInP, GaInAsP, InGaAsSb, InGaAsNSb, InP, InGaAs, InAlAs, GaAsSb, AlAsSb, GaInAsSb, and GaInAsP.

4. The tunnel junction of claim 1 , wherein the second layer quantum well is selected from the group consisting of Al x GaAs, or GaInAsNSb wherein x is at less than 40%.

5. The tunnel junction of claim 1 , wherein the thickness of the second layer is from about 1 nm to about 20 nm.

6. The tunnel junction of claim 1 that is operable up to about 1000× sun.

Assignments (6)
CHANGE OF NAME Recorded Dec 16, 2025
From: ALLIANCE FOR SUSTAINABLE ENERGY, LLC
To: ALLIANCE FOR ENERGY INNOVATION, LLC
Reel/Frame 073993/0276 →
CONFIRMATORY LICENSE Recorded Apr 16, 2019
From: NATIONAL RENEWABLE ENERGY LABORATORY
To: UNITED STATES DEPARTMENT OF ENERGY
Reel/Frame 048918/0594 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 7, 2018
From: PERL, EMMETT E
To: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA, A CALIFORNIA CORPORATION
Reel/Frame 046327/0464 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 4, 2018
From: PERL, EMMETT E.
To: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA, A CALIFORNIA CORPORATION
Reel/Frame 046100/0975 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 27, 2018
From: JAIN, NIKHIL; STEINER, MYLES AARON; GEISZ, JOHN FRANZ; FRANCE, RYAN MATTHEW
To: ALLIANCE FOR SUSTAINABLE ENERGY, LLC
Reel/Frame 045656/0840 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 27, 2018
From: PERL, EMMETT E.
To: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
Reel/Frame 046035/0144 →