Dissociation of a 1,4-bis (4-phenoxybenzoyl)benzene-lewis acid complex in an aqueous solution
A method for manufacturing 1,4-bis(4-phenoxybenzoyl)benzene, including: reacting terephthaloyl chloride with diphenyl ether in a reaction solvent and in the presence of a Lewis acid, so as to obtain a product mixture including a 1,4-bis(4-phenoxybenzoyl)benzene-Lewis acid complex; contacting the product mixture with an aqueous solution, so as to obtain an aqueous phase containing the Lewis acid and an organic phase containing 1,4-bis(4-phenoxybenzoyl)benzene; heating at least the second phase up to a maximum temperature, followed by cooling the second phase down to a separation temperature; subjecting at least the second phase to a solid/liquid separation step at the separation temperature, so as to recover solid 1,4-bis(4-phenoxybenzoyl)benzene.
1. A method for manufacturing 1,4-bis(4-phenoxybenzoyl)benzene, comprising:
reacting terephthaloyl chloride with diphenyl ether in a reaction solvent and in the presence of a Lewis acid, so as to obtain a product mixture comprising a 1,4-bis(4-phenoxybenzoylbenzene)-Lewis acid complex, wherein the reaction solvent is ortho-dichlorobenzene and wherein the Lewis acid is aluminum trichloride; and
contacting the product mixture with an aqueous solution, so as to obtain an aqueous phase containing the Lewis acid and an organic phase containing 1,4-bis(4-phenoxybenzoyl)benzene,
wherein the concentration of Lewis acid in the product mixture is from 10 to 25%, and wherein the aqueous phase contains at least 90% of the Lewis acid from the product mixture, and wherein the relative weight ratio of product mixture and aqueous solution put in contact is from 3 to 0.5.
2. The method of claim 1 , wherein the aqueous solution has a pH of not more than 5.
3. The method of claim 1 , wherein the product mixture is poured into a vessel containing the aqueous solution.
4. The method of claim 1 , further comprising:
separating the aqueous phase from the organic phase; and/or
heating the organic phase up to a maximum temperature, followed by cooling the organic phase down to a separation temperature.
5. The method of claim 4 , wherein from 30 to 99.9 wt. % of the 1,4-bis(4-phenoxybenzoyl)benzene contained in the organic phase is dissolved in the organic phase at the maximum temperature.
6. The method of claim 4 , wherein the maximum temperature is from 90 to 150° C.
7. The method of claim 4 , wherein the separation temperature is at least 20° C.
8. The method of claim 4 , wherein the organic phase is cooled down at a rate of from 10 to 50° C./h.
9. The method of claim 1 , wherein at least the organic phase is subjected to a solid/liquid separation step so as to recover solid 1,4-bis(4-phenoxybenzoyl)benzene.
10. The method of claim 9 , wherein the solid/liquid separation step is performed at a temperature of at least 20° C.
11. The method of claim 9 , comprising one or more steps of washing the recovered solid 1,4-bis(4-phenoxybenzoyl)benzene in a protic solvent and subjecting it to a further solid/liquid separation.
12. The method of claim 11 , wherein at least one of the steps of washing the solid 1,4-bis(4-phenoxybenzoyl)benzene in a protic solvent is performed at a temperature of at least 20° C.
13. The method of claim 1 , wherein the organic phase comprises at least 50% of the 1,4-bis(4-phenoxybenzoyl)benzene in the product mixture.
14. A method of making a polyether ketone polymer, comprising:
manufacturing 1,4-bis(4-phenoxybenzoyl)benzene according to the method of claim 1 ; and
reacting said 1,4-bis(4-phenoxybenzoyl)benzene with at least one difunctional aromatic acyl chloride.