IP Library Granted Patent US 10,513,665
Granted Patent B2
US 10,513,665 · App. 15/987,532 · Granted Dec 24, 2019

Vanadium corrosion inhibitors in gas turbine applications

Inventor: Ki-Hyouk Choi (Dhahran, SA)
Assignee: Saudi Arabian Oil Company
C10L10/04B82Y30/00C08K3/04C08K3/22C09C1/565C10L1/12C10L1/1208C10L1/1233C10L1/322C23F11/187F02C3/30F02C7/30C01P2002/72C01P2002/88C01P2004/64C01P2006/12C08K2003/222C10L2200/0213C10L2200/0438C10L2230/08C10L2250/06C10L2270/04C10L2290/24F05D2260/95
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Quick Facts
Patent No.
US 10,513,665
App. No.
15/987,532
Granted
Dec 24, 2019
Kind
B2
Abstract

The present embodiments describe a method to reduce vanadium corrosion in a gas turbine by adding an oleophilic corrosion inhibitor into a combustion fuel, in which the oleophilic corrosion inhibitor comprises carbon black support particles and magnesium bonded to the carbon black support particles. The carbon black support particles comprise a particle size less than 40 nanometer (nm), and oxygen content less than 1 weight percent (wt %), and a surface area of at least 50 square meters per gram (m 2 /gram).

Claims (21)

1. A method of reducing vanadium corrosion in a gas turbine comprising:

adding an oleophilic corrosion inhibitor into a combustion fuel, in which the oleophilic corrosion inhibitor comprises magnesium chemically bonded to carbon black support particles;

allowing the combustion fuel to combust in the gas turbine; and

reducing vanadium corrosion in the gas turbine.

2. The method of claim 1 , further comprising mixing the oleophilic corrosion inhibitor and the combustion fuel.

3. The method of claim 1 , further comprising mixing the oleophilic corrosion inhibitor with liquid fuel solvent.

4. The method of claim 1 , in which:

the magnesium comprises magnesium oxide; and

the oleophilic corrosion inhibitor is added in an amount such that an amount of magnesium oxide is greater than an amount of vanadium in the gas turbine.

5. The method of claim 1 , in which the combustion fuel comprises liquid oil.

6. The method of claim 1 , in which the magnesium comprises at least one of magnesium oxide and elemental magnesium.

7. The method of claim 1 , in which the magnesium comprises from 0.05 to 20 weight percent magnesium oxide.

8. The method of claim 1 , in which the carbon black support particles comprise acetylene black.

9. The method of claim 1 , in which the carbon black support particles comprise a particle size of less than 20 nm.

10. The method of claim 1 , in which the carbon black support particles comprise an ash content of less than 0.5 weight percent.

11. The method of claim 1 , in which the carbon black support particles comprise a surface area of from 50 m 2 /gram to 100 m 2 /gram.

12. The method of claim 1 , in which the magnesium is attached to the carbon black support particles.

13. The method of claim 1 , in which the carbon black support particles comprise:

a particle size of less than 40 nm;

an oxygen content of less than 1 weight percent; and

a surface area of at least 50 m 2 /gram.

Assignments (3)
NOTICE OF SUCCESSOR AGENT AND ASSIGNMENT OF SECURITY INTERESTSAT REEL/FRAME 048478/0528 AND 059860/0325 Recorded Feb 10, 2025
From: BANK OF AMERICA, N.A., AS THE RESIGNING AGENT
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS SUCCESSOR AGENT
Reel/Frame 070161/0763 →
NOTICE OF GRANT OF SECURITY INTEREST IN PATENTS Recorded Mar 1, 2019
From: AMSTED RAIL COMPANY, INC.
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 048478/0528 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 24, 2018
From: CHOI, KI-HYOUK
To: SAUDI ARABIAN OIL COMPANY
Reel/Frame 045890/0205 →
Continuity (3)
Division 15482218 · Apr 7, 2017
Provisional Application 62324387 · Apr 19, 2016
Related Publication 20180265797A1 · Sep 20, 2018