Pelletized road marking binders and related methods
A composition for use as a binder system for road marking formulations and methods for making thereof is disclosed. The binder system is provided as pellets. The method provides for making the pelletized binder system, and mixing the pelletized binder system with fillers and other components, heating the mixed ingredients forming into a molten mixture for applying on a road surface. The pelletized binder system comprises at least a resin and an elastomer in one embodiment; at least a resin and a plasticizer in a second embodiment; and at least a resin, an elastomer, and a plasticizer in a third embodiment.
1. A pelletized binder composition for use in road marking applications, based on total weight of the binder composition, consisting essentially of:
an alkyd resin selected from rosin resins, modified rosin resins, rosin esters, rosin ester derivatives, and combinations thereof in an amount of 20 to 96 wt. %;
an elastomer selected from styrene-isoprene-styrene rubber (SIS), styrene-butadiene-styrene rubber (SBS), styrene-ethylene/butylene-styrene (SEBS), and SEBS rubber having 1 to 3 wt. % maleic anhydride (MA) grafted onto the rubber midblock, in an amount of 1 to 40 wt. %;
an optional plasticizer selected from vegetable oils, mineral oils, process oils, phthalates and mixtures, in an amount up to 10 wt. %;
wherein the resin, the elastomer, and the optional plasticizer are combined together as pellets of a homogeneous composition prior to being combined with other components forming the pelletized binder composition for use in road marking compositions.
2. The pelletized binder composition of claim 1 , wherein the alkyd resin and the elastomer are immiscible, for the elastomer to form an insoluble dispersed phase in the resin as a continuous phase.
3. The pelletized binder composition of claim 2 , wherein the alkyd resin is selected from maleated rosin, fumarated rosin, acrylated rosin, amidated rosin, nitrated rosin, chlorinated rosin, brominated rosin, and mixtures thereof.
4. The pelletized binder composition of claim 1 , wherein the plasticizer is present in an amount of up to 15 wt. %, and wherein the alkyd resin and the optional plasticizer are combined together as pellets of a homogeneous composition prior to being combined with the elastomer.
5. The pelletized binder composition of claim 1 , wherein the plasticizer is present in an amount of up to 15 wt. %, and wherein the elastomer and the plasticizer are combined together as pellets prior to being combined with the alkyd resin.
6. The pelletized binder composition of claim 1 , wherein the pelletized binder composition is heated up to a temperature of less than 225° C. for blending into a road marking composition in an amount ranging from 5-75 wt. % based on the total weight of the road marking composition.
7. The pelletized binder composition of claim 1 , wherein the alkyd resin is a modified rosin resin comprising rosin acids, and wherein the rosin acids comprise one or more member selected from the group consisting of abietic acid, neoabietic acid, dehydroabietic acid, levopimaric acid, pimaric acid, palustric acid, isopimaric acid, and sandarocopimaric acid.
8. The pelletized binder composition of claim 1 , wherein the alkyd resin is a rosin ester derivative obtained by reacting one or more rosin acids with one or more alcohols selected from methanol, triethylene glycol, glycerol, and pentaerythritol.
9. A road marking composition comprising the pelletized binder composition of claim 1 , wherein the pelletized binder composition is present in an amount of 5-75 wt. % based on the total weight of the road marking composition.
10. A road marking composition comprising the pelletized binder composition of claim 2 , wherein the road marking composition further comprises a second resin that is miscible with the alkyd resin and the elastomer in the pelletized binder composition.
11. The road marking composition of claim 10 , wherein the second resin is selected from the group of: pentaerythritol ester of hydrogenated rosin, pentaerythritol ester of non-hydrogenated rosin, glycerol rosin esters, hydrocarbon resins, styreneated hydrocarbon resins, terpene phenolic resins, styreneated terpene resins, and polyterpene resins.
12. A method for forming a road marking composition comprises:
providing pellets of a homogeneous composition comprising at least an alkyd resin selected from, rosin resins, modified rosin resins, rosin esters, rosin ester derivatives and combinations thereof in an amount of 20 to 96 wt. %; an elastomer selected from styrene-isoprene-styrene rubber (SIS), styrene-butadiene-styrene rubber (SBS), styrene-ethylene/butylene-styrene (SEBS), and SEBS rubber having 1 to 3 wt. % maleic anhydride (MA) grafted onto the rubber midblock in an amount of 1 to 40 wt. %, and optionally a plasticizer selected from vegetable oils, process oils, phthalates and mixtures, in an amount of 0.1 to 10 wt. %; and
mixing the pellets with a composition comprising waxes, pigments, and fillers to form the road marking composition.
13. The method of forming a road marking composition of claim 12 ,
wherein the alkyd resin and the elastomer are immiscible; and
wherein the pellets are mixed with composition comprising waxes, pigments, fillers, and a second resin that is miscible with the alkyd resin and the elastomer in the pelletized binder composition to form the road marking composition.
14. The method of forming a road marking composition of claim 12 , further comprising applying the road marking composition to a road surface by extrusion or a hot spray.