IP Library Granted Patent US 11,118,136
Granted Patent B2
US 11,118,136 · App. 16/001,316 · Granted Sep 14, 2021

Detergent compositions containing a surfactant system including a nonionic and an ionic surfactant

Inventor: Daniel T. Piorkowski (Fairfield, CT)
Assignee: Henkel IP & Holding GmbH
C11D1/831C11D1/146C11D1/22C11D1/722C11D3/001C11D3/0021C11D3/0036C11D3/386C11D3/3905C11D3/42C11D3/43C11D3/48C11D11/0017C11D17/04C11D17/08
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Quick Facts
Patent No.
US 11,118,136
App. No.
16/001,316
Granted
Sep 14, 2021
Kind
B2
Abstract

A wash composition includes a surfactant system, a solvent system, and one or more beneficial compositions. The surfactant system includes a) a linear alkylbenzenesulfonate (LAS), and b) a fatty acid methyl ester ethoxylate (MEE). Optionally, the surfactant system may further include c) an alkyl ether sulfate (AES), and d) a nonionic alcohol ethoxylate (AE). The wash composition may be embodied as a unit dose composition or a heavy-duty liquid. Methods for increasing the effectiveness of fabric cleaning that include using the wash composition are also provided.

Claims (49)

1. A unit dose pack comprising a wash composition and a container composed of a water-soluble film, wherein the wash composition is enclosed in the container, and wherein the wash composition comprises:

(1) a surfactant system, wherein the surfactant system comprises:

a) an alkyl ether sulfate (AES) comprising sodium lauryl ether sulfate (SLES), wherein the alkyl ether sulfate is present in an amount of about 13 wt % to about 14 wt % actives, based on the total weight of the wash composition,

b) a nonionic alcohol ethoxylate (AE) comprising a compound according to Formula (B):

R 2 —(—O—C 2 H 4 —) m —OH

(B) wherein R 2 is a hydrocarbyl group having 8 to 16 carbon atoms and m is from 1 to 20, wherein the nonionic alcohol ethoxylate is present in an amount of about 23 wt % actives, based on the total weight of the wash composition,

c) a linear alkylbenzenesulfonate (LAS) comprising an alkali metal salt of a C 10 -C 16 alkyl benzene sulfonic acid, wherein the linear alkylbenzenesulfonate is present in an amount of about 5 wt % to about 10 wt % actives, based on the total weight of the wash composition, and

d) a fatty acid methyl ester ethoxylate (MEE) that has an average unit number of repeating ethylene oxide (EO) units of from about 5 to 30 moles, and wherein the fatty acid methyl ester ethoxylate is derived from a fatty acid having from 10 to 22 carbons, and wherein the fatty acid methyl ester ethoxylate is present in an amount of about 5 wt % to about 10 wt % actives, based on the total weight of the wash composition,

(2) a solvent system, wherein the solvent system comprises a non-aqueous solvent present in an amount of from about 18 to about 25 weight percent based on a total weight of the wash composition and wherein the non-aqueous solvent is chosen from polyols, ionic liquids, glycol ethers, ethylene oxide/propylene oxide (EO/PO) block copolymers, polyethylene glycol, and combinations thereof;

water present in an amount of from about 14.5 to about 16 weight percent based on a total weight of the wash composition; and

one or more beneficial compositions.

2. The wash composition of claim 1 , wherein the one or more beneficial compositions are selected from the group consisting of: an enzyme, a peroxy compound, a bleach activator, an anti-redeposition agent, a neutralizer, an optical brightener, a foam inhibitor, a chelator, a bittering agent, a dye transfer inhibitor, a soil release agent, a water softener, an electrolyte, a pH regulator, a graying inhibitor, an anti-crease component, a bleach agent, a colorant, a scent, a processing aid, an antimicrobial agent, and a preservative.

3. The wash composition of claim 1 wherein the a) alkyl ether sulfate (AES) is the sodium lauryl ether sulfate (SLES).

4. The wash composition of claim 1 wherein the b) nonionic alcohol ethoxylate (AE) is the compound according to Formula (B).

5. The wash composition of claim 1 wherein the c) linear alkylbenzenesulfonate (LAS) is the alkali metal salt of the C 10 -C16 alkyl benzene sulfonic acid.

6. The wash composition of claim 1 wherein the solvent system is the non-aqueous solvent.

7. The wash composition of claim 2 wherein the a) alkyl ether sulfate (AES) is the sodium lauryl ether sulfate (SLES).

8. The wash composition of claim 7 wherein the b) nonionic alcohol ethoxylate (AE) is the compound according to Formula (B).

9. The wash composition of claim 8 wherein the c) linear alkylbenzenesulfonate (LAS) is the alkali metal salt of the C 10 -C 16 alkyl benzene sulfonic acid.

10. The wash composition of claim 9 wherein the solvent system is the non-aqueous solvent.

11. The wash composition of claim 1 wherein R 2 is from 12-15.

12. The wash composition of claim 11 wherein m is 7.

13. The wash composition of claim 12 wherein the sodium lauryl ether sulfate is ethoxylated with 3 moles of ethylene oxide.

14. The wash composition of claim 13 wherein the fatty acid methyl ester ethoxylate is a C18 methyl ester ethoxylated with 10 moles of ethylene oxide.

15. The wash composition of claim 1 wherein the sodium lauryl ether sulfate is ethoxylated with 3 moles of ethylene oxide.

16. The wash composition of claim 1 wherein the fatty acid methyl ester ethoxylate is a C18 methyl ester ethoxylated with 10 moles of ethylene oxide.

17. The wash composition of claim 1 wherein

the a) alkyl ether sulfate (AES) is the sodium lauryl ether sulfate (SLES),

the b) nonionic alcohol ethoxylate (AE) is the compound according to Formula (B),

the c) linear alkylbenzenesulfonate (LAS) is the alkali metal salt of the C 10 -C 16 alkyl benzene sulfonic acid,

wherein R 2 is from 12-15, and

m is 7.

18. The wash composition of claim 17 wherein

the sodium lauryl ether sulfate is ethoxylated with 3 moles of ethylene oxide, and

the fatty acid methyl ester ethoxylate is a C18 methyl ester ethoxylated with 10 moles of ethylene oxide.

19. A unit dose pack comprising a wash composition and a container composed of a water-soluble film, wherein the wash composition is enclosed in the container, and wherein the wash composition comprises:

(1) a surfactant system, wherein the surfactant system comprises:

a) sodium lauryl ether sulfate (SLES) present in an amount of about 13 wt % to about 14 wt % actives, based on the total weight of the wash composition,

b) a compound according to Formula (B):

R 2 —(—O—C 2 H 4 —) m —OH (B)

wherein R 2 is a hydrocarbyl group having 12 to 15 carbon atoms and m is 7, and is present in an amount of about 23 wt % actives, based on the total weight of the wash composition,

c) an alkali metal salt of a C 10 -C 16 alkyl benzene sulfonic acid present in an amount of about 5 wt % to about 10 wt % actives, based on the total weight of the wash composition, and

d) a fatty acid methyl ester ethoxylate (MEE) that has an average unit number of repeating ethylene oxide (EO) units of from about 5 to 30 moles, wherein the fatty acid methyl ester ethoxylate is derived from a fatty acid having from 10 to 22 carbons, and wherein the fatty acid methyl ester ethoxylate is present in an amount of about 5 wt % to about 10 wt % actives, based on the total weight of the wash composition,

(2) a solvent system, wherein the solvent system comprises a non-aqueous solvent present in an amount of from about 18 to about 25 weight percent based on a total weight of the wash composition and wherein the non-aqueous solvent is chosen from polyols, ionic liquids, glycol ethers, ethylene oxide/propylene oxide (EO/PO) block copolymers, polyethylene glycol, and combinations thereof;

water present in an amount of from about 14.5 to about 16 weight percent based on a total weight of the wash composition; and

one or more beneficial compositions,

wherein the sodium lauryl ether sulfate is ethoxylated with 3 moles of ethylene oxide,

wherein the fatty acid methyl ester ethoxylate is a C18 methyl ester ethoxylated with 10 moles of ethylene oxide, and

wherein the one or more beneficial compositions are selected from the group consisting of: an enzyme, a peroxy compound, a bleach activator, an anti-redeposition agent, a neutralizer, an optical brightener, a foam inhibitor, a chelator, a bittering agent, a dye transfer inhibitor, a soil release agent, a water softener, an electrolyte, a pH regulator, a graying inhibitor, an anti-crease component, a bleach agent, a colorant, a scent, a processing aid, an antimicrobial agent, and a preservative.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 9, 2022
From: HENKEL IP & HOLDING GMBH
To: HENKEL AG & CO. KGAA
Reel/Frame 059357/0267 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 11, 2018
From: PIORKOWSKI, DANIEL
To: HENKEL IP & HOLDING GMBH
Reel/Frame 046315/0844 →
Continuity (1)
Related Publication 20190376005A1 · Dec 12, 2019