GRAPHENE COMPOSITES WITH DISPERSED METAL OR METAL OXIDE
Metal-graphene nanocomposites, metal-oxide-graphene nanocomposites, and method for their preparation are described. According to some embodiments, a metal salt is combined with graphite oxide (GO) to form a metal salt-GO composite. The metal salt-GO composite is reduced to a metal-graphene or metal oxide-graphene nanocomposite material. The metals may be magnetic or non-magnetic. In some embodiments, the reduction is conducted via exposure to intensified electromagnetic radiation, such as focused solar radiation.
1 . A nanocomposite comprising:
a graphene sheet; and
a plurality of nanoparticles of at least one metal or metal oxide dispersed on the graphene sheet, wherein an oxygen content in the nanocomposite comprising the graphene sheet and the plurality of nanoparticles is less than about 15%.
2 . The nanocomposite of claim 1 , wherein the at least one metal or metal oxide is selected from Fe 2 O 3 , CuO, NiO, Au, Ag, Pt, Pd, Co, Ru, CoO, RuO 2 , SnO 2 , ZnO, CeO 2 , CrO 2 , and combinations thereof.
3 . The nanocomposite of claim 1 , wherein the graphene sheet defines two sides, and the nanoparticles of the at least one metal or metal oxide are dispersed substantially evenly on each of the two sides of the graphene sheet.
4 . The nanocomposite of claim 1 , wherein the nanocomposite comprises a plurality of graphene sheets, and wherein each graphene sheet comprises dispersed nanoparticles of the at least one metal or metal oxide.
5 . The nanocomposite of claim 1 , wherein the plurality of nanoparticles include one or more of non-magnetic nanoparticles or magnetic nanoparticles.
6 . The nanocomposite of claim 1 , wherein the plurality of nanoparticles are Ag nanoparticles that have a diameter in a range of about 10 nm to about 15 nm distributed in a face centered cubic structure of Ag, and wherein the graphene sheet is coated with the Ag nanoparticles.
7 . The nanocomposite of claim 1 , wherein the nanoparticles are Au nanoparticles that have a face centered cubic structure and a diameter in a range of about 12 nm to about 18 nm, and wherein the graphene sheet is coated with the Au nanoparticles.
8 . The nanocomposite of claim 1 , wherein the plurality of nanoparticles include CuO nanoparticles that have a diameter in a range of about 12 nm to about 20 nm, NiO nanoparticles that have a diameter in a range of about 9 nm to about 18 nm and magnetic Fe 2 O 3 nanoparticles that have a diameter in a range of about 34 nm to about 50 nm, and wherein the graphene sheet is coated with the CuO nanoparticles, the NiO nanoparticles, and the magnetic Fe 2 O 3 nanoparticles.
9 . The nanocomposite of claim 1 , wherein the nanocomposite comprises less than 2 atomic % chlorine.
10 . The nanocomposite of claim 1 , wherein the nanoparticles are metal nanoparticles, and oxygen content in the nanocomposite is less than about 7 atomic %.
11 . The nanocomposite of claim 1 , wherein each of the plurality of nanoparticles of at least one metal or metal oxide dispersed on the graphene sheet has a diameter in the range of about 5 nm to about 50 nm.
12 . The nanocomposite of claim 1 , wherein the graphene sheet comprises gold graphene, and wherein chlorine content in the graphene sheet is about 1 atomic % and the oxygen content in the graphene sheet is about 3 atomic %.
13 . A graphene nanocomposite material comprising:
a plurality of graphene sheets, wherein each of the plurality of graphene sheets has two sides; and
nanoparticles of at least one metal or metal oxide, wherein the nanoparticles are dispersed substantially evenly on each of the two sides of each of the plurality of graphene sheets, wherein the nanoparticles are dispersed as spacers, and wherein the nanoparticles prevent restacking of the plurality of graphene sheets.
14 . The graphene nanocomposite material of claim 13 , wherein the graphene nanocomposite material has a thickness in a range of about 1 nm to about 10 nm, and wherein an interlayer spacing between pairs of the plurality of graphene sheets is about 3 Å.
15 . The graphene nanocomposite material of claim 13 , further wherein the nanoparticles are gold nanoparticles, and wherein X-Ray Diffraction (XRD) of the graphene nanocomposite material displays a broad peak at about 26 degrees.
16 . The graphene nanocomposite material of claim 13 , wherein the plurality of graphene sheets comprise ferric oxide-graphene, and wherein oxygen content in the plurality of graphene sheets is about 10 atomic %.
17 . The graphene nanocomposite material of claim 13 , wherein the plurality of graphene sheets comprise nickel oxide-graphene, and wherein oxygen content in the plurality of graphene sheets is about 7 atomic % and chlorine content in the plurality of graphene sheets is about 1 atomic %.
18 . The graphene nanocomposite material of claim 17 , wherein each of the plurality of graphene sheets exhibits a weight loss of about 2 wt. % at about 300° C. and has an onset decomposition temperature of about 400° C.
19 . A nanocomposite comprising:
a graphene sheet, wherein the graphene sheet defines two sides, and nanoparticles of the at least one metal are dispersed substantially evenly on each of the two sides of the graphene sheet, wherein an oxygen content in the nanocomposite comprising the graphene sheet and the plurality of nanoparticles is less than about 7%, wherein the at least one metal is selected from Au, Ag, Pt, Pd, Co, Ru, and combinations thereof, and wherein each of the plurality of nanoparticles has a diameter in the range of about 5 nm to about 50 nm.
20 . The nanocomposite of claim 1 , wherein the nanocomposite comprises less than about 2 atomic % chlorine.