Resin composition and method for producing same
The purpose of the present invention is to establish a more precise method for evaluating long-run moldability and, based on this method, improve long-run moldability of a resin composition containing an EVOH-based resin and a nylon 6-based polyamide. Provided is a resin composition having improved long-run moldability and containing an EVOH-based resin and a nylon 6-based polyamide, wherein the amount of ε-caprolactam is 200 ppm or less. When the resin composition comprises an EVOH-based resin and a nylon 6-based polyamide, contacting the resin composition with water can reduce the amount of ε-caprolactam.
1. A method for producing a melt-molded article comprising a resin composition comprising a saponified ethylene-vinyl ester-based copolymer and nylon 6-based polyamide, the method comprising
a process of contacting the nylon 6-based polyamide with water having a temperature of 20 to 60° C. for 10 minutes to 24 hours;
wherein ε-caprolactam is contained in the resin composition at a concentration of 10 to 200 ppm;
wherein a ratio of the amounts in weight of the saponified ethylene-vinyl ester-based copolymer to the nylon 6-based polyamide (saponified ethylene-vinyl ester-based copolymer:nylon 6-based polyamide) in the resin composition is from 50:50 to 90:10;
mixing the saponified ethylene-vinyl ester-based copolymer and nylon 6-based polyamide;
to form a resin composition having a water content of greater than 0.15% by weight to 1% by weight; and
melt-molding the resin composition having a water content of greater than 0.15% by weight to 1% by weight to form the melt-molded article.
2. The method for producing a melt-molded article according to claim 1 , wherein the contact process is carried out at any one of i)-iv) shown below:
i) prior to mixing the saponified ethylene-vinyl ester-based copolymer with the nylon 6-based polyamide;
ii) when mixing the saponified ethylene-vinyl ester-based copolymer with the nylon 6-based polyamide;
iii) after mixing the saponified ethylene-vinyl ester-based copolymer with the nylon 6-based polyamide;
or iv) a combination of two or more of i) to iii).
3. The method for producing a melt-molded article according to claim 2 , wherein the amount of ε-caprolactam contained in the resin composition is reduced to 10 to 200 ppm by the contact process.
4. The method for producing a melt-molded article according to claim 1 , wherein the amount of ε-caprolactam contained in the resin composition is reduced to 10 to 200 ppm by the contact process.
5. The method for producing a melt-molded article according to claim 1 , wherein the process of contacting is carried out for 10 minutes to 12 hours.