Electrolyte and electrochemical energy storage device
The present disclosure provides an electrolyte and an electrochemical energy storage device, the electrolyte comprises an electrolyte salt and an additive. The additive comprises a sulfonic ester cyclic quaternary ammonium salt and a multinitrile compound. The sulfonic ester cyclic quaternary ammonium salt and the multinitrile compound can form a dense and uniform passive film with high ionic conductivity on a surface of each of the positive electrode film and the negative electrode film, so as to prevent continuous oxidation and reduction reaction from occurring between the electrolyte and the positive electrode film and the negative electrode film and make the electrochemical energy storage device has excellent high temperature cycle performance and high temperature storage performance.
1. An electrolyte, comprising:
an electrolyte salt; and
an additive;
wherein the additive comprises a sulfonic ester cyclic quaternary ammonium salt and a multinitrile compound;
wherein the sulfonic ester cyclic quaternary ammonium salt is
the multinitrile compound is ethylene glycol bis(propionitrile) ether;
a content of the sulfonic ester cyclic quaternary ammonium salt is 0.05%˜10% of a total mass of the electrolyte; and
a content of the multinitrile compound is 0.05%˜7% of the total mass of the electrolyte.
2. The electrolyte according to claim 1 , wherein
the content of the sulfonic ester cyclic quaternary ammonium salt is 0.1%˜5% of the total mass of the electrolyte; and
the content of the multinitrile compound is 0.1%˜4% of the total mass of the electrolyte.
3. The electrolyte according to claim 1 , wherein the electrolyte is a liquid electrolyte, a solid polymer electrolyte or a gel polymer electrolyte.
4. An electrochemical energy storage device, comprising an electrolyte;
the electrolyte comprising an electrolyte salt and an additive;
wherein the additive comprises a sulfonic ester cyclic quaternary ammonium salt and a multinitrile compound;
wherein the sulfonic ester cyclic quaternary ammonium salt is
the multinitrile compound is ethylene glycol bis(propionitrile) ether;
a content of the sulfonic ester cyclic quaternary ammonium salt is 0.05%˜10% of a total mass of the electrolyte; and
a content of the multinitrile compound is 0.05%˜7% of the total mass of the electrolyte.
5. The electrochemical energy storage device according to claim 4 , wherein
the content of the sulfonic ester cyclic quaternary ammonium salt is 0.1%˜5% of the total mass of the electrolyte; and
the content of the multinitrile compound is 0.1%˜4% of the total mass of the electrolyte.
6. The electrochemical energy storage device according to claim 4 , wherein the electrolyte is a liquid electrolyte, a solid polymer electrolyte or a gel polymer electrolyte.