IP Library Granted Patent US 11,242,455
Granted Patent B2
US 11,242,455 · App. 16/031,157 · Granted Feb 8, 2022

Tube connectors based on a polyamide composition

Inventors: Yves Deyrail (Evreux, FR); Thibaut Montanari (Menneval, FR); Zhenzhong Li (Jiangsu, CN); Sylvain Benet (Bernay, FR)
Assignee: ARKEMA FRANCE
C08L77/06B29C45/0001B29D23/003C08K7/14C08L77/02B29K2077/00C08L2205/02C08L2205/025F16L47/02
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Quick Facts
Patent No.
US 11,242,455
App. No.
16/031,157
Granted
Feb 8, 2022
Kind
B2
Abstract

A tube connector made from a polyamide composition, the polyamide composition including at least one first polyamide A having an average number of carbon atoms per nitrogen atom C A and at least one second polyamide B having an average number of carbon atoms per nitrogen atom C B , wherein C A ≤8.5 and C B ≥7.5, and wherein C A <C B . The composition may include a third polyamide C having an average number of carbon atoms per nitrogen atom C C , wherein C B ≤C C .

Claims (43)

1. A method of connecting a tube connector part to a tube or a functional part, the method comprising welding a tube connector part to the tube or functional part, wherein the tube connector part is made from a composition, the composition comprising at least one first polyamide A having an average number of carbon atoms per nitrogen atom CA and at least one second polyamide B having an average number of carbon atoms per nitrogen atom CB, wherein CA=8 and CB≥9, and wherein CA<CB, wherein the difference CB−CA is from 1 to 6, and

wherein the tube connector is not a tube,

wherein the tube connector is incorporated into a fluidic circuit for conveying liquids, and

wherein polyamide A is PA 6.10.

2. The method of connecting a tube connector part of claim 1 , wherein the composition comprises from 1 to 70 wt. % of the at least one first polyamide A.

3. The method of connecting a tube connector part of claim 1 , wherein the second polyamide B is selected from PA 6.12, PA 6.14, PA 10.10, PA 11, PA 12, PA 10.12, PA 6.18, PA 12.T, PA 12/10.T, PA 10.10/10.T, PA B.12, PA B.10/10.10, PA IPD.10, PA B.I/12 and mixtures thereof.

4. The method of connecting a tube connector part of claim 1 , wherein the composition comprises from 1 to 70 wt. % of the at least second polyamide B.

5. The method of connecting a tube connector part of claim 1 , wherein the composition consists of one first polyamide A, one second polyamide B and, optionally, non-polyamide additives.

6. The method of connecting a tube connector part of claim 1 , wherein the composition comprises, in addition to the first polyamide A and the second polyamide B, at least one third polyamide C having an average number of carbon atoms per nitrogen atom CC, wherein CC≥9 and CC≥CB.

7. The method of connecting a tube connector part of claim 6 , wherein CC≥9 and CC>CB.

8. The method of connecting a tube connector part of claim 6 , wherein the difference CC−CB is from 1 to 4.

9. The method of connecting a tube connector part of claim 6 , wherein the second polyamide B is selected from PA 6.12 ; and the third polyamide C is selected from PA 6.14, PA 10.10, PA 11, PA 12, PA 10.12, PA 6.18, PA 12.T, PA 12/10.T, PA 10.10/10.T, PA B.12, PA B.10/10.10, PA IPD.10, PA B.I/12 and mixtures thereof.

10. The method of connecting a tube connector part of claim 6 , wherein the composition comprises from 1 to 80 wt. % of the at least one second polyamide B; and the composition comprises from 1 to 70 wt. % of the at least one third polyamide C.

11. The method of connecting a tube connector part of claim 6 , wherein the composition consists of one first polyamide A, one second polyamide B, one third polyamide C and, optionally, non-polyamide additives.

12. The method of connecting a tube connector part of claim 1 , wherein the amount of polyamides in the composition is from 30 to 100 wt. %.

13. The method of connecting a tube connector part of claim 1 , wherein the composition further comprises additives selected from impact modifiers, processing aids, fillers, stabilizers, nucleating agents, dyes, pigments, fireproofing agents, or mixtures thereof.

14. The method of connecting a tube connector part of claim 1 , wherein the fluidiccircuit conveys liquids in motor vehicles.

15. The method of connecting a tube connector part of claim 1 , wherein the tube connector part is formed by an injection molding process.

16. The method of connecting a tube connector part of claim 15 , wherein the tube connector part is welded to one or more tubes.

17. A method of connecting a tube connector part to at least one tube or a functional part, the method comprising welding a tube connector part to the tube or functional part, wherein the tube connector part is made from a composition, the composition comprising at least one first polyamide A having an average number of carbon atoms per nitrogen atom CA and at least one second polyamide B having an average number of carbon atoms per nitrogen atom CB, wherein CA=8 and CB≥9, and wherein CA<CB, wherein the difference CB−CA is from 1 to 6,

wherein the tube connector part is formed by an injection molding process,

wherein the tube connector part is not a tube,

wherein the tube connector is incorporated into a fluidic circuit for conveying liquids, and wherein polyamide A is PA 6.10.

18. The method of connecting a tube connector part of claim 16 , wherein the tube is a polyamide tube.

19. The method of connecting a tube connector part of claim 18 , wherein the polyamide tube is a multilayer tube containing different polyamide components in the inner and outer layers.

20. The method of connecting a tube connector part of claim 19 , wherein the multilayer tube has a PA 12-based outer layer and a PA 6-based inner layer.

21. The method of connecting a tube connector part of claim 1 , wherein the welding is spin welding.

22. The method of connecting a tube connector part of claim 14 , wherein the circuit is in a motor vehicle.

23. The method of connecting a tube connector part of claim 22 , wherein the fluid is a refrigerant.

24. The method of connecting a tube connector part of claim 22 , wherein the fluid is a fuel.

25. The method of connecting a tube connector part of claim 1 , wherein the tube connector part is welded to the functional part.

26. The method of connecting a tube connector part of claim 25 , wherein the functional part is a filter.

27. The method of connecting a tube connector part of claim 1 , wherein the second polyamide B is selected from PA 10.10, PA 11, PA 12, PA 10.12, PA 12.T, PA 12/10.T, PA 10.10/10.T, PA B.12, PA B.10/10.10, PA IPD.10, PA B.I/12 and mixtures thereof.

28. The method of connecting a tube connector part of claim 1 , wherein the composition further comprises carbon fibers in an amount that contributes 5% to the total weight of said composition.

29. The method of connecting a tube connector part of claim 1 , wherein the composition comprises, in addition to the first polyamide A and the second polyamide B, at least one third polyamide C having an average number of carbon atoms per nitrogen atom CC, wherein CC≥9 and CC≥CB, and wherein the composition comprises, either:

from 1 to 80 wt. % of the at least one second polyamide B; or

from 1 to 70 wt. % of the at least one third polyamide C.

30. A weldable tube connector part made from a composition, the composition comprising at least one first polyamide A having an average number of carbon atoms per nitrogen atom CA and at least one second polyamide B having an average number of carbon atoms per nitrogen atom CB, wherein CA=8 and CB>8, and wherein CA<CB, wherein the composition further comprises, in addition to the first polyamide A and the second polyamide B, at least one third polyamide C having an average number of carbon atoms per nitrogen atom CC, wherein CC>8 and CC≥CB, and wherein the composition comprises, either:

from 1 to 80 wt. % of the at least one second polyamide B; or

from 1 to 70 wt. % of the at least one third polyamide C,

wherein the tube connector part is nota tube,

wherein the tube connector is incorporated into a fluidiccircuit for conveying liquids, and wherein polyamide A is PA 6.10.

31. The method of connecting a tube connector part of claim 1 , wherein the tube connector part is made of a single layer of the composition.

Assignments (2)
CHANGE OF ADDRESS Recorded Jul 4, 2025
From: ARKEMA FRANCE
To: ARKEMA FRANCE
Reel/Frame 071814/0739 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 10, 2018
From: DEYRAIL, YVES; MONTANARI, THIBAUT; LI, ZHENZHONG; BENET, SYLVAIN
To: ARKEMA FRANCE
Reel/Frame 046304/0802 →
Priority Claims (1)
FR 13.58494 · Sep 5, 2013 · national
Continuity (2)
Continuation 14477043 · Sep 4, 2014
Related Publication 20190077956A1 · Mar 14, 2019