Quantum dot encapsulation techniques
View Patent ↗Quantum dots and methods of making quantum dots are described. A method begins with forming quantum dots having a core-shell structure with a plurality of ligands on the shell structure. The method includes exchanging the plurality of ligands with a plurality of second ligands. The plurality of second ligands have a weaker binding affinity to the shell structure than the plurality of first ligands. The plurality of second ligands are then exchanged with hydrolyzed alkoxysilane to form a monolayer of hydrolyzed alkoxysilane on a surface of the shell structure. The method includes forming a barrier layer around the shell structure by using the hydrolyzed alkoxysilane as a nucleation center.
1. A display device comprising:
a quantum dot film comprising quantum dots, each of the quantum dots including:
a core-shell structure having a core comprising indium phosphide (InP) and a shell comprising zinc sulfide (ZnS) or zinc selenide (ZnSe) surrounding the core, and
an optically transparent hydrophobic barrier layer, disposed on the core-shell structure, wherein the optically transparent hydrophobic barrier layer surrounds only a single quantum dot; and
a matrix material configured to house the quantum dots and be in substantial contact with the optically transparent hydrophobic barrier layer;
disposed on an organic layer that emits a broadband radiation during operation; and
an optical element, disposed on the quantum dot film, configured to block wavelengths of the broadband radiation that are greater than the primary emission peak wavelength.
2. The display device of claim 1 , wherein the hydrophobic barrier layer is configured to provide a distance between the shell of one of the quantum dots with the shell of other quantum dots that are in contact with the one of the quantum dots to prevent aggregation.
3. The display device of claim 2 , wherein the distance is equal or greater than a Forster radius.
4. The display device of claim 1 , wherein the organic layer, the quantum dot film, and the optical element are part of a pixel unit of the display device.
5. The display device of claim 1 , wherein the optical element is a color filter.
6. The display device of claim 1 , wherein the optically transparent hydrophobic barrier layer comprises an oxide.
7. The display device of claim 1 , wherein the optically transparent hydrophobic barrier layer comprises silicon dioxide.
8. The display device of claim 1 , further comprising surfactants disposed on an outer surface of the optically transparent hydrophobic barrier layer.
9. The display device of claim 1 , wherein the matrix material comprises an extrudable material.
10. The display device of claim 1 , wherein the matrix material comprises a brightness enhancement film.
11. The display device of claim 1 , wherein the matrix material comprises a polymer plastic based substrate.
12. The display device of claim 1 , wherein the film has a thickness in a range from about 70 μm to about 40 μm.