Lithium composite anode, method of fabricating the same, and lithium secondary battery including the same
Provided is a lithium composite anode including a metal film, and lithium ion conductors and electron conductors dispersed on one surface of the metal film, wherein portions of the lithium ion conductors and electron conductors are impregnated into the metal film from the one surface of the metal film.
1. A lithium composite anode for lithium battery, comprising:
a metal film having a first portion and a second portion, the first portion including a first surface, the second portion including a second surface that is opposite to the first surface; and
a conductive film including lithium metal particles, lithium ion conductors, electron conductors, and a binder, wherein the lithium ion conductors and the electron conductors are cross-linked by the binder and disposed over the first surface of the metal film;
a combination of the first portion of the metal film and lithium ion conductors and electron conductors dispersed in the first portion of the metal film, the combination disposed between the conductive film and the metal film, each of the lithium ion conductors and the electron conductors having a solid structure; and
a collector on the second surface of the metal film,
wherein the metal film includes a lithium,
wherein some of the lithium ion conductors and the electron conductors are impregnated into the first portion of the metal film from the first surface of the metal film,
wherein none of the lithium ion conductors and the electron conductors are impregnated into the second portion of the metal film from the first surface of the metal film,
wherein a melting point of the conductive film is higher than that of the metal film,
wherein the lithium ion conductors have a one-dimensional linear structure, a two-dimensional planar structure, or a three-dimensional mass structure,
wherein the electron conductors have a one-dimensional linear structure, a two-dimensional planar structure, or a three-dimensional mass structure.
2. The lithium composite anode of claim 1 , wherein the lithium ion conductors and the electron conductors comprise nanowires, nanotubes, or nanoplates.
3. The lithium composite anode of claim 1 , wherein the lithium ion conductors and the electron conductors do not react with lithium at a driving voltage.
4. The lithium composite anode of claim 1 , wherein the lithium ion conductors comprise Li 2 O—SiO 2 —TiO 2 —P 2 O 5 (LSTP), Li 3 PS 4 - glass-ceramic, Li 7 P 3 S 11 glass-ceramic, Li 4 SnS 4 .
5. The lithium composite anode of claim 1 , wherein the electron conductors comprise stainless steel (SUS), nickel (Ni), or copper (Cu).
6. The lithium composite anode of claim 1 , wherein each of the lithium ion conductors has an aspect ratio that is equal to or greater than 1.1.
7. The lithium composite anode of claim 1 , wherein a length of each of the lithium ion conductors is in a range from 1 nm to 500 nm.
8. The lithium composite anode of claim 1 , wherein mass of the lithium ion conductors is in a range from 20 wt % to 80 wt % with respect to total mass of the lithium composite anode.
9. The lithium composite anode of claim 1 , wherein the combination comprises a binder.
10. A lithium secondary battery comprising:
a first electrode;
a second electrode; and
an electrolyte between the first electrode and the second electrode,
wherein the first electrode includes:
a metal film having a first portion and a second portion, the first portion including a first surface, the second portion including a second surface that is opposite to the first surface;
a conductive film including lithium metal particles, lithium ion conductors, electron conductors, and a binder, wherein the lithium ion conductors and the electron conductors are cross-linked by the binder and disposed over the first surface of the metal film;
a combination of the first portion of the metal film and lithium ion conductors and electron conductors dispersed in the first portion of the metal film, the combination disposed between the conductive film and the metal film, each of the lithium ion conductors and the electron conductors having a solid structure; and
a collector on the second surface of the metal film,
wherein the metal film includes lithium,
wherein some of the lithium ion conductors and the electron conductors are impregnated into the first portion of the metal film from the first surface of the metal film,
wherein none of the lithium ion conductors and the electron conductors are impregnated into the second portion of the metal film from the first surface of the metal film,
wherein a melting point of the conductive film is higher than that of the metal film,
wherein the lithium ion conductors have a one-dimensional linear structure, two-dimensional planar structure, or three-dimensional mass structure,
wherein the electron conductors have a one-dimensional linear structure, a two-dimensional planar structure, or a three-dimensional mass structure.
11. The lithium secondary battery of claim 10 , wherein the electron conductors comprise stainless steel (SUS), nickel (Ni), or copper (Cu).
12. The lithium secondary battery of claim 10 , wherein the combination comprises a binder.