Heat shrinkable film and preparation method thereof
Embodiments relate to a heat shrinkable film, which has a heat shrinkage rate in the direction perpendicular to the main shrinkage direction that is not high even at a high temperature and which is printable thereon. The heat shrinkable film comprises a polyester resin, wherein the heat shrinkage characteristics in the direction perpendicular to the main shrinkage direction satisfy the following Relationships 1 and 2: −15≤Δ T 70−65 ≤0 [Relationship 1] 0≤Δ T 100−95 ≤5 [Relationship 2] wherein ΔT X−Y is a value obtained by subtracting a heat shrinkage rate of the heat shrinkable film in the direction perpendicular to the main shrinkage direction after the heat shrinkable film is immersed in a water bath for 10 seconds at Y° C. from a heat shrinkage rate of the heat shrinkable film in the direction perpendicular to the main shrinkage direction after the heat shrinkable film is immersed in a water bath for 10 seconds at X° C.
1. A heat shrinkable film, which comprises a polyester resin,
wherein a maximum expansion rate in direction perpendicular to main shrinking direction of the heat shrinkable film is 5 to 12%;
wherein the polyester resin comprises a dicarboxylic acid component and a diol component, and the diol component comprises diethylene glycol and neopentyl glycol;
wherein content of diethylene glycol is 5 to 15% by mole based on the total number of moles of the diol component, and content of neopentyl glycol is 22 to 30% by mole based on the total number of moles of the diol component; and
wherein heat shrinkage characteristics of the heat shrinkable film in the direction perpendicular to the main shrinkage direction satisfy the following Relationships 1b and 2b:
Relationship 1b −8%≤ΔT X−Y ≤−1%, wherein X is 70 and Y is 65,
Relationship 2b 0.2%≤ΔT X−Y ≤1%, wherein X is 100 and Y is 95,
wherein ΔT X−Y is a value obtained by subtracting a heat shrinkage rate of the heat shrinkable film in the direction perpendicular to the main shrinkage direction after the heat shrinkable film is immersed in a water bath for 10 seconds at Y° C. from a heat shrinkage rate of the heat shrinkable film in the direction perpendicular to the main shrinkage direction after the heat shrinkable film is immersed in a water bath for 10 seconds at X° C.
2. The heat shrinkable film of claim 1 , wherein the maximum expansion rate of the heat shrinkable film is present between 70° C. and 90° C. when the heat shrinkage of the heat shrinkable film in the direction perpendicular to the main shrinkage direction is measured at an interval of 5° C. between 50° C. and 100° C.
3. The heat shrinkable film of claim 1 , whose heat of crystallization (ΔHc) as measured by differential scanning calorimetry (DSC) is 0 to 30 J/g.
4. The heat shrinkable film of claim 1 , which satisfies that T 75 is −12 to 0%, that T 80 is −15 to 0%, that T 85 is −10 to 0%, wherein T 75 , T 80 , and T 85 each refer to a heat shrinkage rate in the direction perpendicular to the main shrinkage direction after the heat shrinkable film is immersed in a water bath for 10 seconds at 75° C., 80° C., and 85° C., respectively.
5. A process for preparing a heat shrinkable film according to claim 1 , which comprises:
(a) preparing a polyester resin composition, wherein the polyester resin comprises a dicarboxylic acid component and a diol component, and the diol component comprises diethylene glycol and neopentyl glycol, and wherein the content of diethylene glycol is 5 to 15% by mole based on the total number of moles of the diol component, and the content of neopentyl glycol is 22 to 30% by mole based on the total number of moles of the diol component;
(b) extruding the composition to obtain an unstretched sheet;
(c) preheating the unstretched sheet at a preheating temperature (T1) of 100 to 110° C.;
(d) stretching the preheated unstretched sheet in one direction to obtain a stretched sheet;
(e) thermally treating the stretched sheet at a thermal treatment temperature (T2) of 70 to 98° C.; and
(f) cooling the thermally treated and stretched sheet to prepare the heat shrinkable film,
wherein a maximum expansion rate in direction perpendicular to main shrinking direction of the heat shrinkable film is 5 to 12%;
wherein heat shrinkage characteristics of the heat shrinkable film in the direction perpendicular to the main shrinkage direction satisfy the following Relationships 1b and 2b:
Relationship 1b −8≤ΔT X−Y ≤−1%, wherein X is 70 and Y is 65,
Relationship 2b 0.2≤ΔT X−Y ≤1%, wherein X is 100 and Y is 95
wherein ΔT X−Y is a value obtained by subtracting a heat shrinkage rate of the heat shrinkable film in the direction perpendicular to the main shrinkage direction after the heat shrinkable film is immersed in a water bath for 10 seconds at Y° C. from a heat shrinkage rate of the heat shrinkable film in the direction perpendicular to the main shrinkage direction after the heat shrinkable film is immersed in a water bath for 10 seconds at X° C.
6. The process for preparing a heat shrinkable film of claim 5 , wherein the extrusion (b) is carried out at 260 to 300° C.
7. The process for preparing a heat shrinkable film of claim 5 , wherein T1-T2 is 10 to 40° C.
8. The process for preparing a heat shrinkable film of claim 5 , wherein the preheating (c) is carried out for 0.01 to 1 minute.
9. The process for preparing a heat shrinkable film of claim 5 , wherein the stretching (d) is carried out at a stretching ratio of 3 to 5 times in one direction.
10. The process for preparing a heat shrinkable film of claim 5 , which further comprises printing on the heat shrinkable film.