Photoconductor having protective overcoat layer with a charge transport molecule with four radical polymerizable hydrophilic functional groups containing an oxygen atom and method of making the same
View Patent ↗An improved organic photoconductor drum used in an electrophotographic image forming device and method to make the same is provided. The organic photoconductor drum contains a protective overcoat. The protective overcoat is prepared from a curable composition including a charge transport molecule containing four radical polymerizable hydrophilic functional groups containing an oxygen atom of the general structure shown below: where R 1 and R 2 contain a spacer group and a radical polymerizable hydrophilic functional group containing an oxygen atom, R 3 and R 4 are a non-radical polymerizable functional group, and R 5 and R 6 contain a spacer group and a radical polymerizable hydrophilic functional group containing an oxygen atom. The curable composition may also contain at least one curing agent. This organic photoconductor drum has excellent wear resistance without negatively altering the electrophotographic properties, thus protecting the organic photoconductor drum from damage and extending its service life.
1. An organic photoconductor drum comprising:
a support element;
a charge generation layer disposed over the support element;
a charge transport layer disposed over the charge generation layer; and
an overcoat layer disposed over the charge transport layer, wherein the overcoat layer includes a cured composition including a charge transport molecule as shown below:
wherein R 1 and R 2 contain a spacer group and a radical polymerizable hydrophilic functional group containing an oxygen atom, R 3 and R 4 are a non-radical polymerizable functional group, and R 5 and R 6 contain a spacer group and a radical polymerizable hydrophilic functional group containing an oxygen atom, and wherein the radical polymerizable hydrophilic functional group containing an oxygen atom of R 1 and R 2 is selected from the group consisting of acrylate group, methacrylate group, glycidyl ether group and epoxy group.
2. The organic photoconductor drum of claim 1 , wherein the radical polymerizable functional group containing an oxygen atom of R 1 and R 2 is an acrylate group.
3. The organic photoconductor drum of claim 1 , wherein R 3 and R 4 are hydrogen atoms.
4. The organic photoconductor drum of claim 1 , wherein the spacer group of R 5 and R 6 is an unbranched alkyl group containing between 1 and about 6 carbon atoms.
5. The organic photoconductor drum of claim 4 , wherein the unbranched alkyl group containing between 1 and 6 carbon atoms is an ethyl group.
6. An organic photoconductor drum comprising:
a support element;
a charge generation layer disposed over the support element;
a charge transport layer disposed over the charge generation layer; and
an overcoat layer disposed over the charge transport layer, wherein the overcoat layer includes a cured composition including a charge transport molecule as shown below:
wherein R 1 and R 2 contain a spacer group and a radical polymerizable hydrophilic functional group containing an oxygen atom, R 3 and R 4 are a non-radical polymerizable functional group, and R 5 and R 6 contain a spacer group and a radical polymerizable hydrophilic functional group containing an oxygen atom, and wherein the radical polymerizable functional group containing an oxygen atom of R 5 and R 6 is selected from the group consisting of acrylate group, methacrylate group, glycidyl ether group and epoxy group.
7. The organic photoconductor drum of claim 6 , wherein the radical polymerizable functional group containing an oxygen atom of R 5 and R 6 is an acrylate group.