Compound and organic light emitting display device

1. A compound, having a structure shown as formula (I):

wherein D represents an electron donor unit, A represents an electron acceptor unit, m and n are each independently selected from 1, 2 or 3, and m+n≤4;

wherein the A unit is selected from one or more of a triaryl boron substituent, a benzophenone substituent, an aromatic heterocyclic ketone substituent, and a sulfone substituent;

wherein the D unit is selected based on any one of following schemes:

scheme 1: the D unit is selected from any one or more of the following structures:

wherein X, X 1 and X 2 are each independently selected from, a nitrogen atom, an oxygen atom, or a sulfur atom;

# represents a position which can be linked to

x and y are each independently selected from 0, 1, 2 or 3;

R 1 , R 2 , R 3 , and R 4 are each independently selected from any one or more of a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 40 carbon atoms, a substituted or unsubstituted heteroaryl group having 4 to 40 carbon atoms, a substituted or unsubstituted carbazolyl group having 12 to 40 carbon atoms and its derivative groups, a substituted or unsubstituted diphenylamino group having 12 to 40 carbon atoms and its derivative groups, a substituted or unsubstituted acridinyl group having 12 to 40 carbon atoms and its derivative groups, and a substituted or unsubstituted azine group having 3 to 40 carbon atoms and its derivative groups;

when X is an oxygen atom or a sulfur atom, R 3 is not present; when X 1 is an oxygen atom or a sulfur atom, R 3 is not present; when X 2 is an oxygen atom or a sulfur atom, R 4 is not present;

or

scheme 2: the D unit is selected from any one or more of the following structures:

wherein X is selected from a carbon atom, a nitrogen atom, an oxygen atom, a sulfur atom or a silicon atom;

# represents a position which is linked to

r and s are each independently selected from 0, 1, 2 or 3, p and q are each independently selected from 0, 1 or 2;

R 1 , R 2 , R 3 , and R 4 are each independently selected from any one or more of a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 40 carbon atoms, a substituted or unsubstituted heteroaryl group having 4 to 40 carbon atoms, a substituted or unsubstituted carbazolyl group having 12 to 40 carbon atoms and its derivative groups, a substituted or unsubstituted diphenylamino group having 12 to 40 carbon atoms and its derivative groups, a substituted or unsubstituted acridinyl group having 12 to 40 carbon atoms and its derivative groups, and a substituted or unsubstituted azine group having 3 to 40 carbon atoms and its derivative groups;

when X represents an oxygen atom or a sulfur atom, p=0 and q=0; when X represents a nitrogen atom, p=1 and q=1; when X represents a carbon atom or a silicon atom, p=2 and q=2;

or,

scheme 3: the D unit is selected from any one or more of the following structures:

# represents a position which is linked to

u and v are each independently selected from 0, 1, 2 or 3;

R 1 and R 2 are each independently selected from any one or more of a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 40 carbon atoms, a substituted or unsubstituted heteroaryl group having 4 to 40 carbon atoms, a substituted or unsubstituted carbazolyl group having 12 to 40 carbon atoms and its derivative groups, a substituted or unsubstituted diphenylamino group having 12 to 40 carbon atoms and its derivative groups, a substituted or unsubstituted acridinyl group having 12 to 40 carbon atoms and its derivative groups, and a substituted or unsubstituted azine group having 3 to 40 carbon atoms and its derivative groups;

or,

scheme 4: the D unit is selected from any one or more of the following structures:

wherein # represents a position which can be linked to

2. The compound according to claim 1 , wherein in the compound, at least one D unit and at least one A unit are respectively linked to an adjacent —CH— on a

ring.

3. The compound according to claim 1 , wherein when the D unit is selected based on the scheme 1, the D unit is selected from any one or more of the following structures:

wherein # represents a position which is linked to

R in each structural formula independently represents an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an alkynyl group having 2 to 20 carbon atoms, an aromatic group having 6 to 40 carbon atoms, and a heteromatic group having 4 to 40 carbon atoms.

4. The compound according to claim 1 , wherein when the D unit is selected based on the scheme 2, the D unit is selected from any one or more of the following structures:

wherein # represents a position which is linked to

5. The compound according to claim 1 , wherein when the D unit is selected based on the scheme 3, the D unit is selected from any one or more of the following structures:

wherein # indicates a position which is linked to

6. The compound according to claim 1 , wherein the triaryl boron substituent is selected from one or more of the following structures:

wherein # represents a position which can be linked to

7. The compound according to claim 1 , wherein the aromatic heterocyclic ketone substituent is selected from one or more of the following structures:

and the benzophenone substituent selected from one or more of the following structures:

wherein # represents a position which can be linked to

R in each structural formula independently represents an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an alkynyl group having 2 to 20 carbon atoms, a naphthenic group having 4 to 8 carbon atoms, an aromatic group having 6 to 40 carbon atoms, or a heteromatic group having 4 to 40 carbon atoms.

8. The compound according to claim 1 , wherein the sulfone substituent is selected from one or more of the following structures:

wherein # represents a position which can be linked to

9. The compound according to claim 1 , wherein the compound is selected from one of following compounds:

10. The compound according to claim 1 , wherein the difference between the singlet energy and the triplet energy of the compound is less than 0.3 eV.

11. An organic light emitting display device, comprising an organic electroluminescent device, the organic electroluminescent device comprising:

an organic functional layer comprising one or more organic film layers, and at least one of the organic film layers is a light emitting layer;

the light emitting layer comprises a light emitting material, and the light emitting material comprises the compound of claim 1 .

12. The organic light emitting display device according to claim 11 , wherein the compound functions as a host material or a guest material of the light emitting layer, or the compound constitutes the light emitting layer alone to prepare a non-doping organic light emitting display device.

13. The organic light emitting display device according to claim 11 , wherein the compound functions as a red light emitting material of the light emitting layer, and the singlet energy of the red light emitting material is located between 1.61 eV and 1.99 eV.

14. The organic light emitting display device according to claim 11 , wherein the compound functions as a green light emitting material of the light emitting layer, and the singlet energy of the green light emitting material is located between 2.15 eV and 2.52 eV.

15. The organic light emitting display device according to claim 11 , wherein the compound functions as a blue light emitting material of the light emitting layer, and the singlet energy of the blue light emitting material is located between 2.52 eV and 2.73 eV.

16. The organic light emitting display device according to claim 11 , wherein the compound functions as a guest material of a light emitting material, and a host material is any one or more of 2,8-bis(diphenylphosphinyloxy)dibenzothiophene,

4,4′-di(9-carbazolyl) biphenyl, 3,3′-bis(N-carbazolyl)-1,1′-biphenyl,

2,8-bis(diphenylphosphinyloxy)bis benzofuran,

bis(4-(9H-carbazolyl-9-yl)phenyl)diphenylsilane,

9-(4-t-butylphenyl)-3,6-bis(triphenylsilyl)-9h-carbazole, bis(2-diphenylphosphine

oxide)diphenyl ether, 1,3-bis[3,5-bis(pyridin-3-yl)phenyl]benzene,

4,6-bis(3,5-bis(3-pyridyl)phenyl)-2-methylpyrimidine,

9-(3-(9H-carbazolyl)-9-yl)phenyl)-9H-carbazole-3-cyano,

9-phenyl-9-[4-(triphenylsilyl)phenyl]-9H-fluorene,

1,3,5-tris(1-phenyl-1H-benzimidazol-2-yl)benzene,

diphenyl[4-(triphenylsilyl)phenyl]phosphine oxide,

4,4′,4″-tris(carbazolyl-9-yl)triphenylamine, 2,6-dicarbazole-1,5-pyridine, polyvinylcarbazole and polyfluorene; the difference between the Highest Occupied Molecular Orbital (HOMO) of the host material and the HOMO of the guest material is less than 0.6 eV, or the difference between the Lowest Unoccupied Molecular Orbital (LUMO) of the host material and the LUMO of the guest material is less than 0.6 eV.

17. The organic light emitting display device according to claim 16 , wherein the singlet energy of the host material is higher than the singlet energy of the guest material, and the difference between the singlet energy of the host material and the singlet energy of the guest material is less than 1.0 eV.

18. The organic light emitting display device according to claim 11 , wherein the compound functions as a host material of a light emitting material, and a guest material is selected from a fluorescent material, a thermally activated delayed fluorescence (TADF) material, or a phosphorescent light emitting material, and the difference between the HOMO of the host material and the HOMO of the guest material is less than 0.6 eV, or the difference between the LUMO of the host material and the LUMO of the guest material is less than 0.6 eV.

19. The organic light emitting display device according to claim 18 , wherein the compound functions as a host material of a light emitting material, and a guest material is selected from a fluorescent material or a TADF material; the singlet energy of the guest material is less than the singlet energy of the host material, and the difference between the singlet energy of the host material and the singlet energy of the guest material is less than 1.0 eV.

20. The organic light emitting display device according to claim 18 , wherein the compound functions as a host material of a light emitting material, and a guest material is selected from a fluorescent material; the triplet energy of the guest material is less than the triplet energy of the host material, and the difference between the triplet energy of the host material and the triplet energy of the guest material is less than 1.0 eV.

21. The organic light emitting display device according to claim 11 , wherein the light emitting material is a TADF material.

22. A compound, having a structure shown as formula (I):

wherein D represents an electron donor unit, A represents an electron acceptor unit, m and n are each independently selected from 1, 2 or 3, and m+n≤4;

wherein the D unit is selected from any one or more of the following structures:

wherein X, X 1 and X 2 are each independently selected from, a nitrogen atom, an oxygen atom, or a sulfur atom;

# represents a position which can be linked to

R 1 , R 2 , R 3 , and R 4 are each independently selected from any one or more of a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 40 carbon atoms, a substituted or unsubstituted heteroaryl group having 4 to 40 carbon atoms, a substituted or unsubstituted carbazolyl group having 12 to 40 carbon atoms and its derivative groups, a substituted or unsubstituted diphenylamino group having 12 to 40 carbon atoms and its derivative groups, a substituted or unsubstituted acridinyl group having 12 to 40 carbon atoms and its derivative groups, and a substituted or unsubstituted azine group having 3 to 40 carbon atoms and its derivative groups;

when X is an oxygen atom or a sulfur atom, R 3 is not present; when X 1 is an oxygen atom or a sulfur atom, R 3 is not present; when X 2 is an oxygen atom or a sulfur atom, R 4 is not present;

or

wherein the D unit is selected from any one or more of the following structures:

wherein X is selected from a carbon atom, a nitrogen atom, an oxygen atom, a sulfur atom or a silicon atom;

# represents a position which is linked to

r is selected from 0, 1, 2 or 3, p and q are each independently selected from 0, 1 or 2;

R 1 , R 2 , R 3 , and R 4 are each independently selected from any one or more of a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 40 carbon atoms, a substituted or unsubstituted heteroaryl group having 4 to 40 carbon atoms, a substituted or unsubstituted carbazolyl group having 12 to 40 carbon atoms and its derivative groups, a substituted or unsubstituted diphenylamino group having 12 to 40 carbon atoms and its derivative groups, a substituted or unsubstituted acridinyl group having 12 to 40 carbon atoms and its derivative groups, and a substituted or unsubstituted azine group having 3 to 40 carbon atoms and its derivative groups;

when X represents an oxygen atom or a sulfur atom, p=0 and q=0; when X represents a nitrogen atom, p=1 and q=1; when X represents a carbon atom or a silicon atom, p=2 and q=2;

or

wherein the D unit is selected from any one or more of the following structures:

wherein # represents a position which can be linked to