Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and tembotrione and/or topramezone
Provided herein are herbicidal compositions and methods of controlling undesirable vegetation utilizing (a) a compound of formula (I): or an agriculturally acceptable salt or ester thereof, and (b) tembotrione and/or topramezone. The compositions and methods provided herein provide control of undesirable vegetation, e.g., in corn crops such as field corn, field corn grown for seed, and popcorn, sweet corn, sorghum, and any other crops that are naturally tolerant to or contain herbicide tolerant traits to these active ingredients.
1. A herbicidal composition comprising a herbicidally effective amount of (a) a compound of the formula (I)
or an agriculturally acceptable salt or ester thereof, and (b) tembotrione and/or topramezone, and the weight ratio of (a) to (b) tembotrione on a gram active ingredient (g ai) basis is from about 1:200 to about 200:1, and the weight ratio of (a) to (b) topramezone on a gram active ingredient (g ai) basis is from about 1:5 to about 5:1.
2. The composition of claim 1 , wherein (a) is a benzyl ester of the compound of formula (I).
3. The composition of claim 2 , wherein (b) is tembotrione and the weight ratio of (a) to (b) on a gram active ingredient (g ai) basis is from about 1:20 to about 20:1.
4. The composition of claim 2 , wherein (b) is tembotrione and the weight ratio of (a) to (b) on a gram active ingredient (g ai) basis is from about 1:20 to about 3:1.
5. The composition of claim 2 , wherein (b) is topramezone.
6. The composition of claim 1 , further comprising a herbicide safener.
7. The composition of claim 1 , wherein (b) is tembotrione.
8. The composition of claim 1 , wherein (b) is tembotrione and the weight ratio (a) to (b) on a gram active ingredient per hectare (g ai) basis is from about 1:20 to about 3:1.
9. The composition of claim 1 , further comprising an agriculturally acceptable adjuvant or carrier.
10. A method of controlling undesirable vegetation which comprises contacting the vegetation or the locus thereof with or applying to the soil or water to control the emergence or growth of vegetation a herbicidally effective amount of (a) a compound of the formula (I)
or an agriculturally acceptable salt or ester thereof, and (b) tembotrione and/or topramezone, and the weight ratio of (a) to (b) tembotrione on a gram active ingredient per hectare (g ai/ha) basis is from about 1:200 to about 200:1, and the weight ratio of (a) to (b) topramezone on a gram active ingredient per hectare (g ai/ha) basis is from about 1:5 to about 5:1.
11. The method of claim 10 , wherein (a) is a benzyl ester of the compound of formula (I).
12. The method of claim 10 , wherein the herbicidal composition further comprises a safener.
13. The method of claim 10 , wherein (b) is tembotrione.
14. The method of claim 10 , wherein (b) is tembotrione and the weight ratio of (a) to (b) on a gram active ingredient per hectare (g ai/ha) basis is from about 1:20 to about 3:1.
15. The method of claim 10 , wherein the herbicidal composition further comprises an agriculturally acceptable adjuvant or carrier.
16. The method of claim 10 , wherein the undesirable vegetation is controlled in corn, maize, sorghum, direct-seeded, water-seeded and transplanted rice, cereals, wheat, barley, oats, rye, sugarcane, sunflower, oilseed rape, canola, sugar beet, soybean, cotton, pineapple, pastures, grasslands, rangelands, fallowland, turf, tree and vine orchards, aquatics, plantation crops, vegetables, industrial vegetation management (IVM) or rights-of-way (ROW).
17. The method of claim 10 , wherein the undesirable vegetation is controlled in corn crops such as field corn, field corn grown for seed, popcorn, and sweet corn, and sorghum.
18. The method of claim 10 , wherein the (a) and (b) are applied pre-emergently to the weed or the crop.
19. The method of claim 10 , wherein the undesirable vegetation is controlled in glyphosate-, 5-enolpyruvylshikimate-3-phosphate (EPSP) synthase inhibitor-, glufosinate-, glutamine synthetase inhibitor-, dicamba-, phenoxy auxin-, pyridyloxy auxin-, synthetic auxin-, auxin transport inhibitor-, aryloxyphenoxypropionate-, cyclohexanedione-, phenylpyrazoline-, acetyl CoA carboxylase (ACCase) inhibitor-, imidazolinone-, sulfonylurea-, pyrimidinylthiobenzoate-, triazolopyrimidine-, sulfonylaminocarbonyltriazolinone-, acetolactate synthase (ALS) or acetohydroxy acid synthase (AHAS) inhibitor-, 4-hydroxyphenyl-pyruvate dioxygenase (HPPD) inhibitor-, phytoene desaturase inhibitor-, carotenoid biosynthesis inhibitor-, protoporphyrinogen oxidase (PPO) inhibitor-, cellulose biosynthesis inhibitor-, mitosis inhibitor-, microtubule inhibitor-, very long chain fatty acid inhibitor-, fatty acid and lipid biosynthesis inhibitor-, photosystem I inhibitor-, photosystem II inhibitor-, triazine-, or bromoxynil-tolerant crops.
20. The method of claim 10 , wherein the undesirable vegetation comprises a herbicide resistant or tolerant weed.
21. The method of claim 20 , wherein the resistant or tolerant weed is a biotype resistant or tolerant to acetolactate synthase (ALS) or acetohydroxy acid synthase (AHAS) inhibitors, photosystem II inhibitors, acetyl CoA carboxylase (ACCase) inhibitors, synthetic auxins, auxin transport inhibitors, photosystem I inhibitors, 5-enolpyruvylshikimate-3-phosphate (EPSP) synthase inhibitors, microtubule assembly inhibitors, fatty acid and lipid synthesis inhibitors, protoporphyrinogen oxidase (PPO) inhibitors, carotenoid biosynthesis inhibitors, very long chain fatty acid (VLCFA) inhibitors, phytoene desaturase (PDS) inhibitors, glutamine synthetase inhibitors, 4-hydroxyphenyl-pyruvate-dioxygenase (HPPD) inhibitors, mitosis inhibitors, cellulose biosynthesis inhibitors, herbicides with multiple modes-of-action, quinclorac, arylaminopropionic acids, difenzoquat, endothall, or organoarsenicals.