Flowable brazing compositions and methods of brazing metal articles together using the same
Flowable brazing compositions and methods of brazing metal articles together using the same are provided herein. In an embodiment, a flowable brazing composition includes a non-polymeric carrier medium and flux-coated particles. The carrier medium includes at least one polar organic solvent and is liquid at ambient temperature. The flux-coated particles include a braze material core and a flux coating disposed on the core. The braze material core includes different material from the flux coating. The flowable brazing composition has less than or equal to about 1.5 weight % of polymeric binder components, based upon a total weight of the flowable brazing composition.
1. A flowable brazing composition comprising:
a non-polymeric carrier medium, wherein the carrier medium comprises at least one polar organic solvent and is liquid at ambient temperature;
flux-coated particles including a braze material core and a flux coating disposed on the core, wherein the braze material core includes different material from the flux coating;
wherein the flowable brazing composition has less than or equal to about 1.5 weight % of polymeric binder components, based upon a total weight of the flowable brazing composition.
2. The flowable brazing composition of claim 1 , wherein the composition is a stable suspension of the flux-coated particles in the carrier medium, and wherein the composition is free from visible solvent separation for a period of at least 25 weeks at a temperature of about 35° C.
3. The flowable brazing composition of claim 1 , wherein the at least one polar organic solvent includes a C2-C10 aliphatic glycol.
4. The flowable brazing composition of claim 3 , wherein the at least one polar organic solvent includes hexylene glycol.
5. The flowable brazing composition of claim 4 , wherein the at least one polar organic solvent further includes a C2-C4 glycol.
6. The flowable brazing composition of claim 1 , wherein the at least one polar organic solvent is present in an amount of at least 10 weight % based on the total weight of the flowable brazing composition.
7. The flowable brazing composition of claim 1 , further comprising flux particles separate from the flux-coated particles.
8. The flowable brazing composition of claim 7 , wherein the flux particles are present in an amount of at least 3 weight % based on the total weight of the flowable brazing composition.
9. The flowable brazing composition of claim 7 , wherein the flux particles comprise a metal halide or a salt thereof.
10. The flowable brazing composition of claim 7 , wherein the flux particles have a D50 particle size distribution of from about 5 to about 15 μm.
11. The flowable brazing composition of claim 7 , wherein at least some of the flux particles have a length to diameter (L/D) ratio from about 3 to about 10.
12. The flowable brazing composition of claim 1 , wherein the braze material core comprises a silicon-containing material.
13. The flowable brazing composition of claim 12 , wherein the braze material core comprises an alloy of silicon and a metal.
14. The flowable brazing composition of claim 13 , wherein the braze material core comprises an Al—Si alloy or precursor thereof.
15. The flowable brazing composition of claim 1 , wherein the flux coating comprises a metal halide or a salt thereof.
16. The flowable brazing composition of claim 1 , wherein the flux-coated particles have a D50 particle size diameter of from about 30 to about 60 μm.
17. The flowable brazing composition of claim 1 , further comprising a thickener.
18. The flowable brazing composition of claim 1 , free of detectable water.
19. A method of brazing metal articles together using a flowable brazing composition, wherein the method comprises:
providing a brazing composition comprising:
a non-polymeric carrier medium, wherein the carrier medium comprises at least one polar organic solvent and is liquid at ambient temperature;
flux-coated particles including a braze material core and a flux coating disposed on the core, wherein the flux coating comprises a metal halide and wherein the braze material core includes different material from the flux coating;
wherein the flowable brazing composition has less than or equal to about 1.5 weight % of polymeric binder components, based upon a total weight of the flowable brazing composition;
depositing the brazing composition on at least one of the metal articles at a location where the metal articles are to be joined;
heating the at least one metal article to substantially remove the solvent from the flowable brazing composition; and
brazing the metal articles together at a temperature and time sufficient to melt the core of the flux-coated particles.
20. A flowable brazing composition consisting of:
a non-polymeric carrier medium, wherein the carrier medium consists of one or more polar organic solvents and is liquid at ambient temperature;
flux-coated particles including a braze material core and a flux coating disposed on the core, wherein the flux coating comprises a metal halide and wherein the braze material core includes different material from the flux coating;
flux particles separate from the flux-coated particles; and
optionally, a non-polymeric thickener.